• Computers and Concrete
• /
• v.32 no.4
• /
• pp.373-381
• /
• 2023

Fly ash, granulated blast furnace slag, marble waste powder, etc. are just some of the by-products of other sectors that the construction industry is looking to include into the many types of concrete they produce. This research seeks to use surrogate machine learning methods to forecast the compressive strength of self-compacting concrete. The surrogate models were developed using Gradient Boosting Machine (GBM), Support Vector Machine (SVM), Random Forest (RF), and Gaussian Process Regression (GPR) techniques. Compressive strength is used as the output variable, with nano silica content, cement content, coarse aggregate content, fine aggregate content, superplasticizer, curing duration, and water-binder ratio as input variables. Of the four models, GBM had the highest accuracy in determining the compressive strength of SCC. The concrete's compressive strength is worst predicted by GPR. Compressive strength of SCC with nano silica is found to be most affected by curing time and least by fine aggregate.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.5
• /
• pp.1219-1222
• /
• 2010

A simple and efficient method has been developed for conversion of arenecarbaldehyde-3-methylquinoxalin-2-ylhydrazones to 3-(2-methylquinoxalin-3-yl)-2-(substitutedphenyl)thiazolidin-4-ones in good yields using microwave irradiation technique on silica as solid support under solvent free conditions. The synthesized compounds were characterized by elemental microanalysis, infrared spectroscopy, $^1H$ NMR, and mass spectroscopy. All the synthesized thiazolidinones were investigated for their antimicrobial and antifungal activities. The results of the biological activities revealed that the compounds 3b, 3d, 3f and 3h exhibited excellent antibacterial activities while 3d and 3h exhibited good antifungal activity.

• Bulletin of the Korean Chemical Society
• /
• v.26 no.9
• /
• pp.1381-1384
• /
• 2005

Surface modification of tridimensional cubic mesoporous silica, SBA-16, was investigated with pendant arm functionalized cobalt diaminosarcophagine (diAMsar) cage complex which covalently grafted onto the silica surface through the silication with sylanol group. The spectroscopic results showed that the mesoporous structure was preserved under the $[Co(diAMsar)]^{3+}$ grafting reaction condition. Successful grafting prevented the cobalt diAMsar cage from leaching out from the SBA-16 support.

• Proceedings of the KIEE Conference
• /
• 2006.10c
• /
• pp.211-213
• /
• 2006

In this study, plasma etching process was modeled by using support vector machine (SVM). The data used in modeling were collected from the etching of silica thin films in inductively coupled plasma. For training and testing neural network, 9 and 6 experiments were used respectively. The performance of SVM was evaluated as a function of kernel type and function type. For the kernel type, Epsilon-SVR and Nu-SVR were included. For the function type, linear, polynomial, and radial basis function (RBF) were included. The performance of SVM was optimized first in terms of kernel type, then as a function of function type. Five film characteristics were modeled by using SVM and the optimized models were compared to statistical regression models. The comparison revealed that statistical regression models yielded better predictions than SVM.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.05b
• /
• pp.41-44
• /
• 2006

Recently, single shell lining method of construction is studied by economical method of construction to make use of high-performance shotcrete of permanent shotcrete lining concept in the UStA, Europe, Japan etc. High-performance shotcrete use is essential as permanent support that single shell lining method of construction has two functions of lining and support to shotcrete. In this research, optimum accelerator amount was decided after setting time test using alkai-free and cement mineral accelerator. Also replacement ratio of silica fume and fly-ash was determined.

• Journal of the Korean Ceramic Society
• /
• v.29 no.6
• /
• pp.496-504
• /
• 1992

Alumina tubes suitable for the support of gas separation membranes have been prepared by the slipcasting technique. These supports have the average pore size of 0.1 ${\mu}{\textrm}{m}$ within the narrow distribution. The sol-gel dipcoating process of nanoparticulate sols is very sensitive to microstructure of the support, and the coating on the inside surface of the tube is found to be more successful than on the outside surface. Nanoparticulate silica sols (0.82 mol/ι) have been synthesized by an interfacial hydrolysis reaction between TEOS and high alkaline water. When coating an alumina tube with these sols, the minimum limits of the particle size and the aging time required for forming the coated gel layer at the given pH are provided. It is optimum to coat the support with less concentrated sols stabilized through aging for the appropriate time (more than 22 days) at the lower pH (pH 2.0) for producing a reproducible crack free thin film coating in composite membranes.

• Journal of the Korea Concrete Institute
• /
• v.19 no.6
• /
• pp.701-706
• /
• 2007

This study evaluated the durability of high-performance shotcrete mixed in the proper proportions using alkali-free and cement mineral accelerators as a permanent support that maintains its strength for the long term. Durability tests were performed the chloride permeability, repeated freezing and thawing, accelerated carbonation, and the effects of salt environments. Test results showed that all the shotcrete mixes included silica fume had low permeability. In addition, after 300 freeze/thaw cycles, the shotcrete mix had excellent freeze/thaw resistance more than the 85% relative dynamic modulus of elasticity. The accelerated carbonation test results were no effect of accelerator type but, the depth of carbonation was greater in the shotcrete mix containing silica fume. No damage was seen in a salt environments. Therefore, the high performance shotcrete mix proportions used in this study showed excellent durability.

• Journal of the Korean Chemical Society
• /
• v.55 no.1
• /
• pp.81-85
• /
• 2011

$V_{0.9}Sb_{0.1}O_x$ systems, bulk and deposited on different supports (five types of $\gamma$-aluminas, $\alpha$-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. Catalytic performance of VSb oxides has shown to be highly dependent on the support and the nature of the support decreasing in a series: $\gamma$-$Al_2O_3$ > $\alpha$-$Al_2O_3$ > Si-Al-O > $SiO_2$ $\approx$ MgO $\gg$ unsupported. Variation of the V-Sb-O-loading in the studied range of coverage (0.5-2 theoretical monolayer) only slightly influences the catalysts' activity and selectivity. The best catalytic performance of $\gamma$-alumina-supported $V_{0.9}Sb_{0.1}O_x$ systems can be explained by the optimal surface interaction between support and supported components resulting in the formation of well-spread amorphous active $VO_x$-component with vanadium in a high oxidation state.

• Applied Chemistry for Engineering
• /
• v.17 no.2
• /
• pp.223-228
• /
• 2006

Pore-size controlled porous carbons for the catalyst supports of the direct methanol fuel cell were prepared from the mesophase pitch by using the silica spheres with different sizes. Pitch solution in THF and spheres were mixed, carbonized and etched by 5 M NaOH to make porous carbon. Specific surface area of the porous carbons was $14.7{\sim}87.7m^2/g$ and average pore diameter was 50~550 nm which were dependent on the size of silica spheres. Aqueous reduction method was used to load 60 wt% PtRu on the prepared porous carbon supports. The electro-oxidation activity of the supported 60 wt% Pt-Ru catalysts was measured by cyclic voltammetry and unit cell test. For the 60 wt% Pt-Ru/porous carbon synthesized by 50 nm silica, current density value in the cyclic voltammetry test was $123mA/cm^2$ at 0.4 V and peak power density in the unit cell test were 105 and $162mW/cm^2$ under oxygen at 60 and $80^{\circ}C$, respectively.

• Bulletin of the Korean Chemical Society
• /
• v.10 no.6
• /
• pp.578-581
• /
• 1989

Two enantiomers of various 2-hydroxy acid esters have been resolved as the 3,5-dinitrophenyl carbamates on chiral stationary phases (CSPs) derived from ${\alpha}-arylalkylamines.$ Two CSPs, each of which contains the same type of chiral moiety, but shows different mode of connection to a silica support, have been found to show the contrasting resolution behaviors. From the contrasting resolution behaviours of two CSPs used in this study, two competing chiral recognition mechanisms are proposed.