• 한국분말재료학회지
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• 제19권6호
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• pp.412-415
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• 2012

The quartz glasses were prepared by sintering of fumed silica powders and the effect of OH concentration on their surface on sintering was studied. Through the firing process, the fumed silica was crystallized from 1180 to $1260^{\circ}C$ region. The amount of hydroxyl group decreased with increase in calcination temperature and consequently the crystallization was prevented. A transparent quartz glass was obtained from fumed silica, previously calcined at $1000^{\circ}C$, by the sintering at $1250^{\circ}C$ for 1 h.

• 한국산업보건학회지
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• 제29권3호
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• pp.271-277
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• 2019

Objectives: A 46-year-old woman who had worked on cleaning stainless steel containers with Initially unknown powders died from acute silicosis. To determine whether the acute silicosis was related to his work environment, we conducted exposure assessment the level of exposure to respirable crystalline silica(RCS) during cleaning stainless steel containers with unknown powders. Methods: The exposure assessment of RCS were undertaken according to the National Institute for Occupational Safety and Health(NIOSH) method 7500. The components of the unknown powder were analyzed using X-ray Diffraction. Results: The unknown powder was found to be natural diatomaceous earth, which contained 12% and 9% quartz and cristobalite, respectively, crystalline silica. In the case of cleaning stainless steel containers with diatomaceous earth powder, the primary measurement resulted in 1.3 times higher occupational exposure limit of MOEL(in sum of quartz and cristobalite concentration) and 3.9 times higher in secondary measurement. The workbench was equipped with a local exhaust system, but because there was no hood at the end of the duct, the wind speed at the opening of the duct was 12 m/sec, whereas the controlled wind speed at the working position was only 0.3 m/sec below the legal standard. Conclusions: There is an urgent need to install the hood, conduct safety and health education for employers and workers, and periodically monitoring and manage the working environment.

• 한국결정성장학회지
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• 제32권4호
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• pp.128-135
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• 2022

반도체 공정용 석영유리 도가니의 내측에 위치하는 투명층은 합성 실리카 분말을 원료로 사용하여 제조한다. 도가니의 투명층에는 다양한 원인에 기인하여 버블이 발생하는데, 버블은 도가니의 품질뿐만 아니라 실리콘 잉곳의 수율을 저하시키는 악영향을 미친다. 따라서 투명층의 원료인 합성 실리카 분말 역시 버블 생성 인자를 최소화하는 것이 주요 목표이다. 이에 따라 합성 실리카 분말의 경우, 실라놀 그룹, 탄소계 불순물, 그리고 기공이 충분히 제거되어야만 한다. 본 연구에서는 졸-겔법을 이용하여 합성 실리카 겔을 제조하고, 2단 하소공정에서 하소온도와 유지시간에 따른 탄소 함량과 비표면적의 변화를 살펴보았다. 1단계 하소온도는 500℃~600℃, 2단계 하소온도는 1000℃~1100℃에서 수행하였으며, 유지시간은 10분에서 최대 12시간까지 실시하였다. 1000℃에서 1시간 동안 하소한 분말의 탄소함량은 0.0031 wt.%를 나타내었으며, 1100℃에서 12시간 동안 하소한 분말의 비표면적은 16.6 m²/g을 나타내었다.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1991년도 춘계연구발표회 논문개요집
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• pp.29-30
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• 1991

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 추계 학술논문 발표대회
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• pp.121-125
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• 2009

The recycling of waste concrete is increasing for the environment protection and the shortage of aggregate according to the large scale construction project in Korea. The more manufacturing high quality recycled aggregate is produced, the more waste concrete powder generated from the manufacture process of recycled aggregate, and the consideration about the recycling of waste concrete powder is need. Waste concrete powder was used for the partial replacement of silica powder, which is a main raw material for the manufacture of autoclave foamed concrete. According to the results of research, the slurry density, flow, compressive strength mainly depend on the replacement ratio of particle size and waste concrete powder. At the SEM analysis, the more high-waste concrete powder was the less there are generated tobermorite. But we conclude that it is possible to replace WCP as silica source in the manufacture of the lightweight foamed concrete.

• 한국세라믹학회지
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• 제26권1호
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• pp.81-90
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• 1989

High purity alumina and amorphous silica were prepared from Ha-dong kaolin by means of appliance of sulfuric acid. The effect of sulfuric acid concentration, reaction temperature and reaction time on the formation of aluminum sulfate was investigated. The precipitation conditions ofaluminum sulfate from the sulfuric acid solution with ethanol and ammonium hydroxide were deteremined. In the optimum condition, the conversion of aluminum oxide in kaolin to aluminum oxide powder was 85.0 percent. Alumina powder was prepared by calcination of the precipitates, and its purity was 99.0 percent.

• 한국구조물진단유지관리공학회 논문집
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• 제16권5호
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• pp.59-67
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• 2012

시멘트를 생산할 때 발생하는 이산화탄소로 인하여 콘크리트를 활용하는 건설산업의 친환경성이 문제시 되어가고 있는 실정이다. 이에 본 연구에서는 석회석미분말로 시멘트를 대체하는 기술의 기초연구로서 석회석미분말을 함유한 콘크리트의 내구특성에 관하여 특성을 파악하고자 하였다. 실험변수는 석회석미분말의 시멘트 치환률을 0%에서 25%까지 5%씩 중가하였으며 동결융해 저항성, 제설염 저항성 및 알칼리-실리카반응 저항성 등의 내구특성과 기초적인 경화특성 등을 분석하였다. 석회석미분말의 사용으로 인한 동결융해저항성, 제설제염 저항성 등의 영향은 거의 없는 것으로 나타났으며 또한 알카리-실리카반응성의 억제를 위하여도 긍정적으로 검토될 수 있을 것으로 판단된다.

• 공업화학
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• 제27권3호
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• pp.299-306
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• 2016

본 연구는 광노화의 원인으로 알려진 자외선을 차단하는 새로운 복합 분체에 관한 것이다. Hydroxyapatite (HAp)는 자체 생체 친화적이고, 피부에 도포 시 백탁 현상 없이 자외선을 차단하는 효과가 우수하다. 그러나 HAp 구조가 단단한 육방정계이어서 피부 도포 시 피부손상과 분체의 재응집 현상이 발생되어 화장 후 뭉치는 현상, 자체 사용감이 매끄럽지 못하는 단점을 가지고 있다. 이러한 문제점을 개선하고자 HAp의 표면 개질을 통한 자외선 차단 증진 및 사용감을 개선한 새로운 복합 분체를 개발하고자 하였다. 본 연구에서 HAp의 표면 개질을 위해 코팅제로 dimethicone, lauroyl lysine, triethoxycaprylylsilane 및 silica를 사용하였다. Dimethicone, lauroyl lysine 및 triethoxycaprylylsilane은 건식 방법으로 각각 표면 복합화 처리하였고, silica는 수열 합성법으로 표면 처리하여 표면 복합체를 제조하였다. 제조된 HAp 복합체의 자외선 차단 효과를 측정하여 실리카가 코팅된 HAp-silica를 최적의 HAp 복합체로 선정하였다. SEM, 입자크기와 분포, 표면 측정, EDS 분석을 통해 HAp-silica의 표면 복합 분체 특성을 조사하였다. 또한 제형 내에서 안정성, BB cream에서 자외선 차단 효과 측정 및 안전성 시험을 실시하였다. 연구 결과, HAp 분체의 표면 개질을 통해 제조한 HAp-silica는 사용감이 우수하였고, 백탁 현상을 개선함으로써 자외선 차단 효과를 증진시키는 복합 분체로서 자외선 차단 화장품의 새로운 기능성 소재로서 응용 가능성이 있음을 확인하였다.

• 한국분말재료학회지
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• 제25권5호
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• pp.379-383
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• 2018

Silica is used in shell materials to minimize oxidation and aggregation of nanoparticles. Particularly, porous silica has gained attention because of its performance in adsorption, catalysis, and medical applications. In this study, to investigate the effect of the density of the silica coating layer on the color of the pigment, we arbitrarily change the structure of a silica layer using an etchant. We use NaOH or $NH_4OH$ to etch the silica coating layer. First, we synthesize ${\alpha}-FeOOH$ for a length of 400 nm and coat it with TEOS to fabricate particles with a 50 nm coating layer. The coating thickness is then adjusted to 30-40 nm by etching the silica layer for 5 h. Four different shapes of ${\alpha}-FeOOH$ with different colors are measured using UV-vis light. From the color changes of the four different shapes of ${\alpha}-FeOOH$ features during coating or etching, the $L^*$ value is observed to increase and brighten the overall color, and the $b^*$ value increases to impart a clear yellow color to the pigment. The brightest yellow color was that coated with silica; if the sample is etched with NaOH or $NH_4OH$, the $b^*$ value can be controlled to study the yellow colors.

• Advances in concrete construction
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• 제1권4호
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• pp.273-288
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• 2013

The main objective of this research was to evaluate the potentials of self-compacting concrete (SCC) mixes to develop bond strength. The investigated mixes incorporated relatively high contents of dolomite powder replacing Portland cement. Either silica fume or fly ash was used along with the dolomite powder in some mixes. Seven mixes were proportioned and cast without vibration in long beams with 10 mm and 16 mm steel dowels fixed vertically along the flowing path. The beams were then broken into discrete test specimens. A push-put configuration was adopted for conducting the bond test. The variation of the ultimate bond strength along the flowing path for the different mixes was evaluated. The steel-concrete bond adequacy was evaluated based on normalized bond strength. The results showed that the bond strength was reduced due to Portland cement replacement with dolomite powder. The addition of either silica fume or fly ash positively hindered further degradation as the dolomite powder content increased. However, all SCC mixes containing up to 30% dolomite powder still yielded bond strengths that were adequate for design purpose. The test results demonstrated inconsistent normalized bond strength in the case of the larger diameter compared to the smaller one.