• Title/Summary/Keyword: silica powder

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Physical and Chemical Properties of Nano-slag Mixed Mortar

  • Her, Jae-Won;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.6
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    • pp.145-154
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    • 2010
  • As buildings have become higher and larger, the use of high performance concrete has increased. With this increase, interest in and use of ultra fine powder admixture is also on the rise. The silica fume and BSF are the admixtures currently being used in Korea. However, silica fume is exclusively import dependent because it is not produced in Korea. In the case of BFS, it greatly improves concrete fluidity and long-term strength. But a problem exists in securing early strength. Furthermore, air-cooled slag is being discarded, buried in landfills, or used as road bed materials because of its low activation energy. Therefore, we investigated in this study the usability of nano-slag (both rapidly-chilled and air-cooled) as an alternative material to the silica fume. We conducted a physic-chemical analysis for the nano-slag powder and performed a mortar test to propose quality standards. The analysis and testing were done to find out the industrial usefulness of the BFS that has been grinded to the nano-level.

SiC aggregates synthesized from carbonized rice husks, paper sludge, coffee grounds, and silica powder (탄화왕겨, 제지슬러지, 커피찌거기 및 실리카 혼합물로부터 탄화규소 결정체 합성)

  • Park, Kyoung-Wook;Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.2
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    • pp.45-49
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    • 2019
  • Relatively fine silicon carbide (SiC) crystalline aggregates have been synthesized with the carbonized rice husks, paper sludge, coffee grounds as the carbon sources and the silica powder. The main reaction source to obtain silicon carbide (SiC) aggregates from the mixture of carbon sources and silica was inferred as the gaseous silicon monoxide (SiO) phase, being created from this mixture through the carbothermal reduction reaction. The silicon carbide (SiC) crystalline aggregates, fabricated from the carbonized rice husks and paper sludge, coffee grounds and silica ($SiO_2$) powder, were investigated by XRD patterns, FE-SEM and FE-TEM images. In these specimens, obtained from the carbonized rice husks, paper sludge and silica, XRD patterns showed rather high strong peak of (111) plane near $35^{\circ}$. The FE-TEM images and patterns of specimens, synthesized from carbonized rice husks, paper sludge, coffee grounds and silica under Ar atmosphere, showed relatively fine particles under $1{\mu}m$ and crystalline peak (110) of silicon carbide (SiC) diffraction pattern.

Graphitic Mesostructured Carbon from an Aliphatic Hydrocarbon Precursor

  • Kim, Chy-Hyung;Oh, Teresa
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.1978-1980
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    • 2009
  • A mesostructured form of carbon was fabricated from a template of mesostructured silica by using pentane, an aliphatic hydrocarbon precursor. To synthesize the mesostructured silica, a buffered (pH of 6.5) mixture of nonionic Pluronic P123 surfactant, sodium silicate, and acetic acid were used. The impregnated silica with Fe$(CO)_5$ (wt 5%) and pentane was placed in a quartz tube, treated with pentane vapor at 800 ${^{\circ}C}$ for two hours to synthesize the mesostructured carbon. The XRD patterns of the carbon replica in the low/wide angle regions, its TEM images, and nitrogen adsorption-desorption isotherm revealed that the long-range framework order of mesostructure with the pore size centered on 2.8 nm was maintained to some extent mainly due to some portions of mesophase carbon that work as a support to fix the hexagonal frameworks by anchoring on the pore surface with an improved graphitic character. The dc conductivity of the mesostructured carbon in pressed powder form at 6.0 MPa was 2.08 S/cm.

A Hydration Model for Blended Concrete utilizing Secondary Cementitious Powders (혼화재를 사용한 콘크리트의 수화모델)

  • Noh Jea Myoung;Byun Keun Joo;Song Ha-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.140-143
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    • 2004
  • Heat of hydration of concrete under different curing temperatures can be characterized with knowledge of the thermal activity, the heat rate at the reference temperature, and the total heat of hydration of the mixture. The so-called multi-component hydration model incorporates the effect of following variables: cement chemical composition, cement fineness, secondary cementitious powders, mixture proportions, and concrete properties. However, the model does not consider the use of silica fume as a secondary cementitious powder. Therefore, the model that quantifies the heat of hydration due to the use of silica fume is needed. In this thesis, the effects of silica fume on heat of hydration are evaluated and the influence on the heat of hydration are also quantified to be included in the model, so that the analysis using modified multi-component hydration model for silica fume concrete provides more accurate results than normal concrete.

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The propertise of the compressive strength of ultra-high strength Steel Fiber Reinforced Cementitious Composites with mineral admixtures (광물질 혼화재를 사용한 초고강도 SFRCC의 특성)

  • Park, Jung-Jun;Go, Gyung-Taek;Kang, Su-Tae;Ryu, Gum-Sung;Kim, Sung-Wook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.473-476
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    • 2005
  • Silica fume has merits of filling the voids, enhancement of reheological chracteristics, prduction of secondary hydrates by pozzolanic reaction in reactive powder concretes. However silica fume has been imported in high-cost in domestic industry, we need to investigate replaceable material in stead of silica fume in a view of economy Therefore, in this paper, in order to investigation replacement of silica fume in ultra-high strength SFRCC we used another mineral admixtures like that fly-ash, blast slag.

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Preparation of the silica composite membranes for CO removal from PEMFC anode feed gas

  • Lee, Dong-Wook;Lee, Yoon-Gyu;Nam, Seung-Eun;Bongkuk Sea;Ihm, Son-Ki;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.129-132
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    • 2003
  • Silica/SUS composite membranes were prepared for CO removal from products of methanol steam reforming. A support was prepared by coating Ni powder of sub-micron and SiO$_2$ sols of particle size of 500nm and 150nm in turns on a porous stainless steel (SUS) substrate. Silica top layer was coated on the modified support using colloidal sol with nanoparticle. As a result of mixture gas permeation test of silica composite membrane using H$_2$(99%)/CO(1%), CO concentration of 10000 ppm was reduced to under 81 ppm, which is acceptable in PEMFC anode gas specification. Permeation mechanism through the membrane was mainly molecular sieving.

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A Study on Production and Physical Properties of High-Strength Concrete with Blending Additives (혼합재를 사용한 고강도 콘크리트의 제조와 물성에 관한 연구)

  • Jeong, Yong;Shim, Yong-Soo;Kim, Won-Ki;Jaung, Jae-Dong
    • Proceedings of the Korea Concrete Institute Conference
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    • 1991.10a
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    • pp.15-20
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    • 1991
  • High-strength concrete were produced with super-plasticizer, silica fume, fly ash and blast furnace slag powder. Topics investigated inclued mix proportion, and effects of unit weight of binder, W/C ratio, additive type on the physical properties of high-strength concrete. As the result, at 20% of silica fume, unit weight of binder 700kg/$\textrm{m}^3$ and W/C=0.24, 28days compressive strength of concrete was over 1,000kgf/$\textrm{cm}^2$. And in cases of blending with silica fume 10% and fly ash or slag 10%, it was able to produce economical high-strength concrete with 28 days strength similar to silica fume 20% only, and higher strength after 90days.

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Methodological Study for Recycle of Chemical Mechanical Polishing Slurry (슬러리 Modification 에 대한 연구)

  • Park, Sung-Woo;Seo, Yong-Jin;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.567-568
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    • 2006
  • To investigate the recycle possibility of slurry for the oxide-chemical mechanical polishing (oxide-CMP) application, three kinds of retreated methods were introduced as follows: First, the effects on the addition of silica abrasives and the diluted silica slurry (DSS) on CMP performances were investigated. Second, the characteristics of mixed abrasive slurry (MAS) using non-annealed and annealed alumina ($Al_2O_3$) powder as an abrasive added within DSS were evaluated to achieve the improvement of removal rates (RRs) and within-wafer non-uniformity (WIWNU%). Third, the oxide-CMP wastewater was examined in order to evaluate the possible ways of reusing it. And then, we have discussed the CMP characteristics of silica slurry retreated by mixing of original slurry and used slurry (MOS).

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The effect of material factors on the compressive strength of ultra-high strength Steel Fiber Reinforced Cementitious Composites (재료요인이 초고강도 강섬유 보강 시멘트 복합체의 압축강도에 미치는 영향)

  • Park Jung Jun;Go Gyung Taek;Kang Su Tae;Ryu Gum Sung;Kim Sung Wook;Lee Jang Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.288-291
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    • 2004
  • In this paper, to make ultra-high strength SFRCC with the range of compressive strength 180MPa, it was investigated the constitute factors of ultra-high strength SFRCC influenced on the compressive strength. The experimental variables were water-cementitious ratio, replacement of silica fume, size and proportion of sand, type and replacement of filling powder, and using of steel fiber in ultra-high strength SFRCC. As a result, in water-binder ratio 0.18, we could make ultra-high strength SFRCC with compressive strength 180MPa through using of silica fume, quartz sand with below 0.5mm, filling powder and steel fiber.

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Mullitization of Kyanite-Al Mixture (Kyanite-Al 혼합물의 Mullite화 반응)

  • 박정현;배원태
    • Journal of the Korean Ceramic Society
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    • v.23 no.2
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    • pp.7-12
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    • 1986
  • As the other silicate minerals such as kaolinite and pyrophyllite kyanite ($Al_2O_3$.$SiO_2$) is transformed to mullite and free silica or glassy phase at high temperature. Therefore $Al_2O_3$ is commonly added to kyanite in order to increase the mullite-yield. In case of $Al_2O_3$-addition mullite-yield depends on the reactivity of added $Al_2O_3$ with free silica which occurs from transformation of kyanite or exists as accessory minerals. It is well known that addition of activated $Al_2O_3$Al powder is added to kyanite to utilize the aluminothermal reac-tion of Al powder in reaction of mullite-formation.

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