• Corrosion Science and Technology
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• v.8 no.5
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• pp.171-176
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• 2009

The chloride threshold level (CTL) in mixed concrete containing, ordinary Portland cement (OPC), pulverized fuel ash (PFA) ground granulated blast furnace slag (GGBS), and silica fume (SF) is important for study on corrosion of reinforced concrete structures. The CTL is defined as a critical content of chloride at the steel depth of the steel which causes the breakdown of the passive film. The criterion of the CTL represented by total chloride content has been used due to convenience and practicality. In order to demonstrate a relationship between the CTL by total chloride content and the CTL by free chloride content, corrosion test and chloride binding capacity test were carried out. In corrosion test, Mortar specimens were cast using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.0, 0.2, 0.4, 0.8, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binder. All specimens were cured 28 days, and then the corrosion rate was measured by the Tafel's extrapolation method. In chloride binding capacity, paste specimens were casting using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.1, 0.2, 0.3, 0.5, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binders. At 28days, solution mixed with the powder of ground specimens was used to measure binding capacity. All specimens of both experiments were wrapped in polythene film to avoid leaching out of chloride and hydroxyl ions. As a result, the CTL by total chloride content ranged from 0.36-1.44% by weight of binders and the CTL by free chloride content ranged from 0.14-0.96%. Accordingly, the difference was ranging, from 0.22 to 0.48% by weight of binder. The order of difference for binder is OPC > 10% SF > 30% PFA > 60% GGBS.

• International Journal of Concrete Structures and Materials
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• v.8 no.4
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• pp.289-299
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• 2014

Alkali-activated slag concretes are being extensively researched because of its potential sustainability-related benefits. For such concretes to be implemented in large scale concrete applications such as infrastructural and building elements, it is essential to understand its early and long-term performance characteristics vis-a'-vis conventional ordinary portland cement (OPC) based concretes. This paper presents a comprehensive study of the property and performance features including early-age isothermal calorimetric response, compressive strength development with time, microstructural features such as the pore volume and representative pore size, and accelerated chloride transport resistance of OPC and alkali-activated binder systems. Slag mixtures activated using sodium silicate solution ($SiO_2$-to-$Na_2O$ ratio or $M_s$ of 1-2) to provide a total alkalinity of 0.05 ($Na_2O$-to-binder ratio) are compared with OPC mixtures with and without partial cement replacement with Class F fly ash (20 % by mass) or silica fume (6 % by mass). Major similarities are noted between these binder systems for: (1) calorimetric response with respect to the presence of features even though the locations and peaks vary based on $M_s$, (2) compressive strength and its development, (3) total porosity and pore size, and (4) rapid chloride permeability and non-steady state migration coefficients. Moreover, electrical impedance based circuit models are used to bring out the microstructural features (resistance of the connected pores, and capacitances of the solid phase and pore-solid interface) that are similar in conventional OPC and alkali-activated slag concretes. This study thus demonstrates that performance-equivalent alkali-activated slag systems that are more sustainable from energy and environmental standpoints can be proportioned.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.1
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• pp.19-29
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• 2023

An ultra-high strength prestressed prismatic beam of 100 MPa in compressive strength was developed by increasing the watertightness of concrete by utilizing centrifugal molding processes without adding expensive admixtures such as silica fume. The ultra-high strength centrifugal shaped square beam installed on the wall is composited with the upper slab concrete and then subjected to a service load. Horizontal shear stress is generated by bending between the centrifugal molding beam and the floor plate, which causes the beam and floor plate to perform composite behavior through shear connections such as studs and rebars. In this study, a flexural load test was performed on a mock-up specimen that was synthesized by fabricating an RC slab on top of a 100 MPa-class centrifugal shaped beam produced at the factory. proven reliability.

• Magazine of the Korea Concrete Institute
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• v.8 no.3
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• pp.219-229
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• 1996

Recent construction activity of infrastructures has been booming and accelerating to incur shortage of river sand for concrete works. Thus, sea sand has been excessively used instead of river sa.nd, that directly causes to decrease the quality and the durability of concrete, and then might lead to the collapse of concrete structures. The purpose of this experimental research is not only to develop high-strength concrete using sea sand, but also to investigate mechanical properties of high-strength concrete, such as elastic moduli, compressive strength and etc, which could be used for important design data of concrete structures. Rational analytic formula for elastic moduli have been proposed together with those for the splitting tensile strength and the flexural strength, which are to be predicted from compressive strength of concrete cylinder. Optimum water-cement and water-binder ratio have been experimentally obtained so as to develop high compressive strength with and without using silica fume as a admixture for concrete. It is noted that experimental elastic moduli for high strength concrete above aCk=330kgf /cm2 are less than those by the Code. Appropriate amount of concrete mixture has been experimentally investigated so as to develop maximum compressive, flexural and splitting tensile strength.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.57-61
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• 2005

Cement paste is originally the basic material and crucial factor consisting concrete. This study investigates the relationship between flow apparatuses, which are ring flow(R-F), flow cone(F-C) and mini slump(M-S), in order to estimate the fluidity of cement Paste. For quantitatively evaluating the measured data this study also investigated the calibration of the rheology consistent, such as yield value and plastic viscosity, of cement paste using viscometer For this purpose the present work discussed the influence of 3 type of ordinary portland cement with different companies, affecting the fluidity of cement paste. and it also demonstrated the influence of the various kinds of mineral admixtures, such as fly ash(FA), blast furnace slag(BS) and silica fume(SF) and that of incorporating ratio. The author concluded that using R-F apparatus is the most effective flow test method of cement paste and it is exactly proportional to other apparatus' rheological properties.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.1
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• pp.39-43
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• 2015

The cement mixtures such as flyash, iron-slag and silica fume have been actively studied in order to increase the quality of concrete. In this study, the grinded copper-slag with different proportion was added to portland cement. The physical properties of the cement mortars, (i.e.) flowability, absorption, compressive strength and flexural strength, were investigated for the potential application to the cement. Also, the influence of the acid on the chemical resistance of the cement mortars with copper-slag was evaluated by monitoring the weight variation of the cement mortars under 5 % sulfuric acid for 28 days.

• Computers and Concrete
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• v.19 no.2
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• pp.121-126
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• 2017

This paper presents the effect of aggregate type on high temperature resistance of self-compacting mortars (SCM) produced with normal and lightweight aggregates like expanded perlite and pumice. Silica fume (SF) and fly ash (FA) were used as mineral additives. Totally 13 different mixtures were designed according to the aggregate rates. Mini slump flow, mini V-funnel and viscometer tests were carried out on the fresh mortar. On the other hand, bulk density, porosity, water absorption and high temperature tests were made on the hardened SCM. After being heated to temperatures of 300, 600 and $900^{\circ}C$, respectively, the tensile strength in bending and compressive strength of mortars determined. As a result of the experiments, the increase in the use of lightweight aggregate increased total water absorption and porosity of mortars. It is observed that, the increment in the usage of lightweight aggregate decreased tensile strength in bending and compressive strengths of mortar specimens exposed to high temperatures but the usage of up to 10% expanded perlite in mortar increased the compressive strength of specimens exposed to $300^{\circ}C$.

• Computers and Concrete
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• v.20 no.4
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• pp.449-459
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• 2017

Fresh and hardened behaviors of a new hybrid fiber (steel fiber, polyvinyl alcohol fiber and calcium carbonate whisker) reinforced cementitious composites (HyFRCC) with admixtures (fly ash, silica fume and water reducer) have been studied. Within the limitations of the equipment and testing program, it is illustrated that the rheological properties of the new HyFRCC conform to the modified Bingham model. The relations between flow spread and yield stress as well as flow rate and plastic viscosity both conform well with negative exponent correlation, justifying that slump flow and flow rate test can be applied to replace the other two as simple rheology measurement and control method in jobsite. In addition, for the new HyFRCC with fly ash and water reducer, the mathematical model between the rheological and mechanical properties conform well with the quadratic function, and these quadratic function curves are always concave upward. Based on mathematical analysis, an optimal range of rheology/ flowability can be identified to achieve ideal mechanical properties. In addition, this optimization method can be extended to PVA fiber reinforced cement-based composites.

• Economic and Environmental Geology
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• v.30 no.2
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• pp.175-183
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• 1997

The concrete structure can be easily damaged due to alkali-aggregates reaction. There are several methods to identify alkali reactivity of aggregates. The most reliable method is mortar-bar test, but it takes 3 to 12 months for whole test. The authors applied "rapid method" which takes only 7 days for this test. The result of this rapid method follows; expansion ratio of mortar bar for natural aggregates taken at the Youngsan River ranges from 0.197 to 0.489%, but that from Changseong Lake has low expansion ratio of 0.147%, which is below the limit of allowance, 0.168%. Those from the Seomjin River range from 0.173 to 0.22%, and those from the Keum River range from 0.078% to 0.111%. In the case of higher expansion ratio than 0.168%, aggregates must be used with cement containing low alkali content or adding material consuming the alkali content of cement, for example, fly ash and silica fume, etc.. Most of natural aggregates in Cheolla area have no problem in physical properties, particularly the abrasion ratio is below 40%, the limit of allowance. The natural aggregate from Cheolla area consists mostly of gneiss, granite and volcanic rocks. The major alkali reactive materials are quartz mineral with undulatory extinction in gneiss and granite, and amorphous silica in volcanic rocks. Even if a certain aggregate consists of the same kind of rocks and has similar rock composition each other, content of alkali reactivity material can be various, because rock formation is locally different according to temperature and pressure. Therefore every rock type must be physically and chemically identified before using for aggregates.

• Tunnel and Underground Space
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• v.17 no.4
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• pp.266-284
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• 2007

Recently, many efforts have been made to construct the first unlined tunnel, without in-situ concrete lining, in Korea. However, the lack of reliability in the performance of shotcrete as permanent tunnel support prevented from its realization. Shotcrete has been regarded to have significant problems in field application and long term performance because of unsatisfactory strength level and durability compared to those of European countries. In this study, the high strength shotcrete satisfying compressive strength over 40 MPa and flexural strength over 4.5 MPa was developed from optimized mix design. The type of accelerators and the amount of silica fume were selected as the main factors in mixing process and the analyses were carried out up to the elapsed time of 2 years. In order to evaluate the short term durability of shotcrete, an array of laboratory test consisting of freeze-thaw, carbonation chloride penetration and permeability test was performed. For long-term durability tests, specimens have been put in an operated highway tunnel to expose them to the similar environment when they are actually used as an unlined tunnel support. From the strength and durability tests, it was found that only alkali-free based accelerator satisfied the target strength of this study and also, the developed shotcrete showed very high performance in its durability.