• Title/Summary/Keyword: silane coupling agent.

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Improvements of Impact strength in Glass Fiber/Polypropylene Composite by Silane Coupling Agents (실란커플링제에 의한 유리섬유/폴리프로필렌 복합재료의 충격강도 증가에 관한 연구)

  • 정광보
    • Journal of the Korean Society of Safety
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    • v.16 no.1
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    • pp.43-47
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    • 2001
  • Effect of coupling agent on the mechanical properties of PP/GF blend was investigated. The flexural modulus, Izod impact strength, elongation at yield and tensile strength were improved with using coupling agent. Mopological studies revealed that PP and GF were incompatible and addition of coupling agent was very effective to enhance the compatibility, result in mechanical properties.

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Preparations and Interfacial Phenomena of Hybrid Composites (Hycom) Containing Wasted Stone Powders and Tire Chips (폐석분과 폐타이어 칩을 충진제로 한 혼성복합재(Hycom)의 제조 및 계면현상 연구)

  • Hwang, Teak-Sung;Cha, Ki-Sik
    • Journal of Adhesion and Interface
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    • v.2 no.1
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    • pp.1-8
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    • 2001
  • In this study, wasted stone powders (WSP) obtained from sludge and Wasted Tire Chips (WTC) as fillers have been used to formulate polymer hybrid composites based on Unsaturated Polyester (UPE) resin. To further enhance not only the interfacial bond between the inorganic filler and the polymer matrix, but also the filler dispersion by wetting the particulate surfaces to uniformly spread the resin during the mixing, silane coupling agent[${\gamma}$-methacryloxy propyl trimethoxy silane (${\gamma}$-MPS)] was used. The influences of organic recycled fillers contents and the concentrations of coupling agent in polymer hybrid composite formulations have been investigated from a mechanical and microstructural point o view through Mercury Porosimeter and SEM.

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A Study on the Preparation ana Mechanical Properties of Composites Reinforced FRP Waste and Rock-Crush Sludge (폐 FRP/석분슬러지 충전 복합재의 제조 및 기계적 물성에 관한 연구)

  • 황택성;박진원;이철호
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.829-836
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    • 2000
  • In order to recyle the FRP waste from SMC bathtubs and rock-crush sludge obtained as a byproduct of stones, the composite consisting of the FRP and rock-crush sludge and the unsaturated polyester matrix resin were prepared. To enhance the interfacial bonding force between the reinforcements and the matrix resin, the rock-crush sludge was treated with silane coupling agent, ${\gamma}$-methacryloxypropyltrimethoxysilane (${\gamma}$-MPS) and their mechanical properties and interface phenomena were examined. The flexural modulus of the composite containing 10 wt% rock-crush powder treated with 3 wt% silane coupling agent showed the maximum value. And also the initial thermal degradation temperature of composites were in the range of 352~359$^{\circ}C$. From these results, we observed that the weight loss of composites was almost constant regardless of the concentration of silane coupling agent. It is confirmed that the interface of the composites containing filler treated with ${\gamma}$-MPS was improved in that there were no pull-out phenomena between the reinforcement and matrix resin.

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Effect of Silane Coupling Agent on Thermal Stability and Adhesion Properties of DGEBF Epoxy Resin (실란 커플링제에 따른 DGEBF 계열 에폭시의 열안정성 및 접착특성 평가)

  • Lee, Dong Su;Lee, Seul-Yi;Min, Byung-Gak;Seo, Young Soo;Lee, Bong Han;Park, Soo-Jin
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.787-790
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    • 2014
  • In this work, the epoxy specimens were prepared from diglycidyl ether of bisphenol F (DGEBF) with silane coupling agents (3-glycidoxypropyl trimethoxysilane (GPTMS)) in different ratios. Thermal stability was studied in terms of polymer decomposition temperature (PDT), temperature of maximum rate of weight loss ($T_{max}$), integral procedural decomposition temperature (IPDT), and decomposition activation energy ($E_a$) using TGA analysis. Adhesion properties of epoxy composite specimens were measured by UTM (universal testing machine) at atmosphere temperature. In this result, the adhesion properties of DGEBF were improved by addition of silane coupling agents compared to non-treated epoxy resin. However, when the content of GPTMS agent is more than 10 phr, adhesion properties decreased with increasing GPTMS agent.

Effect of fiber-matrix adhesion on the fracture behavior of a carbon fiber reinforced thermoplastic-modified epoxy matrix

  • Carrillo-Escalante, H.J.;Alvarez-Castillo, A.;Valadez-Gonzalez, A.;Herrera-Franco, P. J.
    • Carbon letters
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    • v.19
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    • pp.47-56
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    • 2016
  • In this study, the fracture behavior of a thermoplastic-modified epoxy resin reinforced with continuous carbon fibers for two levels of fiber-matrix adhesion was performed. A carbon fiber with commercial sizing was used and also treated with a known silane, (3-glycidoxy propyl trimethoxysilane) coupling agent. Toughness was determined using the double cantilever test, together with surface analysis after failure using scanning electron microscope. The presence of polysulfone particles improved the fracture behavior of the composite, but fiber-matrix adhesion seemed to play a very important role in the performance of the composite material. There appeared to be a synergy between the matrix modifier and the fiber-matrix adhesion coupling agent.

Effect of silane coupling agent on the Dielectric Properties of Glass Cloth / Epoxy Composite (Glass Cloth / Epoxy 복합재료의 유전특성에 미치는 계면 결합제의 효과)

  • Kwak, Young-Soon;Hong, Young-Ki;Sin, Joong-Hong;Park, Chung-Hoo
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.353-355
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    • 1989
  • Composite insulating materials have the defect of interface. To minimize the defect of interface of GFRP (glass cloth reinforced plastics), coupling agent is treated. In this paper, the method of coupling agent treatment has been studied. The result shows that the optimum electric and mechanical properties is obtained for the sample treated on the glass fiber with 0.3% amino silane water solution.

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