• Title/Summary/Keyword: sieve method

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Microwave Synthesis of Titanium Silicalite-1 Using Solid Phase Precursors

  • Kim, K.Y.;Ahn, W.S.;Park, D.W.;Oh, J.H.;Lee, C.M.;Tai, W.P.
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.634-638
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    • 2004
  • Titanium silicalite-1 (TS-1) molecular sieve was produced by microwave heating of amorphous titanium-containing solid precursors after impregnation with aqueous TPAOH solution. $SiO_2-TiO_2$ xerogel, sub-micron sized $SiO_2-TiO_2$ prepared by thermal plasma process, and Ti-containing mesoporous silica, Ti-HMS, were tested as the solid phase substrates. Highly crystalline product was obtained within 30 min. after microwave irradiation with yields over 90% using $SiO_2-TiO_2$ xerogel, which showed essentially identical physicochemical properties to TS-1 prepared by conventional hydrothermal method. Excellent catalytic activity was also obtained for 1-hexene epoxidation using $H_2O_2.\;SiO_2-TiO_2$ particles prepared by thermal plasma and Ti-HMS were found inferior as a substrate for TS-1, probably due to difficulties in wetting the surface uniformly with TPAOH.

Tensile Strength Characteristics of Compacted Granite Soils with Variation of the Molding Moisture Contents (함수비 변화에 따른 다짐 화강토의 인장강도 특성)

  • Kim, Chan-Kee
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.4
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    • pp.63-70
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    • 2007
  • The soil samples used in this study were prepared with the residual granite soils passed through the #4 sieve and obtained from Pocheon in Gyeonggi-Ki do. Specifically, five types of samples were prepared. Sample A which is a natural state soil was classified as SM according to the uses. Samples of B, C, D, and E were prepared by mixing Sample A with bentonite and were classified as SC according to the uses. The plasticity indexes of samples B, C, D, and E were 15, 25, 30, and 40, respectively. The specimens, whose dimensions are 100mm by 127.5mm, were prepared by A method of ASTM D 698 with the Proctor mold. In experiments, the loading with the 1%/min was applied. Four different disk diameters, 13mm, 26mm, 38mm, and 52mm were used in the Improved Unconfined Penetration (IUP) tests. To compare the tensile strengths, the split tensile tests were also conducted on the same specimens used for the IUP tests. To find out the effects of moisture contents, plasticity Index of specimens on the tensile strength, six different water contents were used for making a specimen.

Novel Convenient Method to Determine Wettability and Dispersibility of Dairy Powders

  • Lee, Jeae;Chai, Changhoon;Park, Dong June;Lim, Kwangsei;Imm, Jee-Young
    • Food Science of Animal Resources
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    • v.34 no.6
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    • pp.852-857
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    • 2014
  • This study was carried out to develop a simple, convenient, and reproducible testing device to determine wettability and dispersibility of dairy powders. The testing device consists of a sieve ($150{\mu}m$) attached to a sample chamber, sensors mounted on a supporting body and a main control unit containing a display panel. The sensors detect the difference in electrical resistance between air and water. A timer is automatically triggered by the sensor when the bottom of sample-loaded chamber contacts water in the petri dish. Wettability and dispersibility of commercial skim milk powders (SMPs) produced at different heating strengths (low-, medium-, and high-heat SMP) are compared using the new testing device. Wettability of the SMPs were correlated with particle size and are found to increase in the order of medium-, low-, and high-heat SMP regardless of the amount of sample tested. Dispersibility of SMPs showed the same trend and high heat-SMP which has the smallest particle size resulted in the lowest dispersibility. Unlike existing methods, the new testing device can determine both wettability and dispersibility of powders and successfully detected differences among the samples.

Breakage Index and Changes in Permeability of Bottom Ash for Use as Fill Material (성토재로의 활용을 위한 Bottom Ash의 파쇄지수 산정 및 투수계수 변화)

  • Kim, Donggeun;Son, Younghwan;Park, Jaesung;Bong, Taeho
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.6
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    • pp.107-115
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    • 2015
  • The objective of the this study is to find the breakage index and changes in permeability of Bottom ash from thermoelectric power plants in Korea. Bottom ash was crushed by compaction according to compaction energy from 0 to $1661.4\;kN/m^2$. The particle size distribution was estimated by sieve analysis. The various breakage indexes were used for analyzing the change in particle size distribution and effect of compaction energy. In the result, breakage indexes were increased as compaction energy and initial upper 4.75 mm diameter ratio, but values and tendencies of breakage indexes appeared in different as calculation method of breakage indexes. The coefficient of permeability was decreased with particle breakage, but decreasing ratio of permeability was very small. Bottom ash has a higher permeability than the weathered soil and it is considered high usability as a permeable materials.

Manufacture of AlSi10Mg Alloy Powder for Powder Bed Fusion(PBF) Process using Gas Atomization Method (가스 분무법을 이용한 Powder Bed Fusion(PBF) 공정용 AlSi10Mg 합금 분말 제조)

  • Im, Weon Bin;Park, Seung Joon;Yun, Yeo Chun;Kim, Byeong Cheol
    • Journal of Powder Materials
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    • v.28 no.2
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    • pp.120-126
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    • 2021
  • In this study, AlSi10Mg alloy powders are synthesized using gas atomization and sieving processes for powder bed fusion (PBF) additive manufacturing. The effect of nozzle diameter (ø = 4.0, 4.5, 5.0 and 8.0 mm) on the gas atomization and sieving size on the properties of the prepared powder are investigated. As the nozzle diameter decreases, the size of the manufactured powder decreases, and the uniformity of the particle size distribution improves. Therefore, the ø 4.0 mm nozzle diameter yields powder with superior properties. Spherically shaped powders can be prepared at a scale suitable for the PBF process with a particle size distribution of 10-45 ㎛. The Hausner ratio value of the powder is measured to be 1.24. In addition, the yield fraction of the powder prepared in this study is 26.6%, which is higher than the previously reported value of 10-15%. These results indicate that the nozzle diameter and the post-sieve process simultaneously influence the shape of the prepared powder as well as the satellite powder on its surface.

A critical review of fluoride removal from water by using different types of adsorbents

  • Prashant S. Lingayat;Rampravesh K. Rai
    • Advances in environmental research
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    • v.12 no.2
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    • pp.77-93
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    • 2023
  • The water can be contaminated by natural sources or by industrial effluents. One such contaminant is fluoride. Fluoride contamination in the water environment due to natural and artificial activities has been recognized as one of the major problems worldwide. Among the commonly used treatment technologies applied for fluoride removal, the adsorption technique has been explored widely and offers a highly efficient simple and low-cost process for fluoride removal from water. This review paper the recent developments in fluoride removal from surface water by adsorption methods. Studies on fluoride removal from aqueous solutions using various carbon materials are reviewed. Various adsorbents with high fluoride removal capacity have been developed, however, there is still an urgent need to transfer the removal process to an industrial scale. Regeneration studies need to be performed to more extent to recover the adsorbent in field conditions, enhancing the economic feasibility of the process. Based on the review, technical strategies of the adsorption method including the Nano-surface effect, structural memory effect, anti-competitive adsorption and ionic sieve effect can be proposed. The design of adsorbents through these strategies can greatly improve the removal efficiency of fluoride in water and guide the development of new efficient methods for fluoride removal in the future. This paper describes brief discussions on various low-cost adsorbents used for the effective removal of fluoride from water.

Synthesis of Silica/Alumina Composite Membrane Using Sol-Gel and CVD Method for Hydrogen Purification at High Temperature (Sol-gel 및 CVD법을 이용한 고온 수소 분리용 silica/alumina 복합막의 합성)

  • 서봉국;이동욱;이규호
    • Membrane Journal
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    • v.11 no.3
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    • pp.124-132
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    • 2001
  • Silica membranes were prepared on a porous ${\alpha}$-alumina tube with pore size of 150nm by sol-gel and chemical vapor deposition(CVD) method for hydrogen separation at high temperatures. Silica and ${\gamma}$-lumina membranes formed by the sol-gel method possessed a large amount of mesopores of a Knudsen diffusion regime. In order to improve the $H_2$ selectivity, silica was deposited in the sol-gel derived silica/${\gamma}$-alumina layer by thermal decomposition of tetraethyl orthosilicate(TEOS) at $600^{\circ}C$. The CVD with forced cross flow through the porous wall of the support was very effective in plugging mesopores that were left unplugged in the membranes. The CVD modified silica/alumina composite membrane completely rejected nitrogen permeation and thus showed a high $H_2$ selectivity by molecular sieve effect. the permeation of hydrogen was explained by activated diffusion and the activation energy was 9.52kJ/mol.

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Effects of HCl and EDTA on Soil Washing to Remediate Lead-contaminated Soil in a Firing Range (사격장 납 오염토양 복원을 위한 토양세척시 HCl과 EDTA의 영향 연구)

  • Kim, Hyo-Sik;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.13 no.1
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    • pp.60-66
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    • 2008
  • Laboratory soil washing experiments with HCl or EDTA were conducted to remediate lead-contaminated soil in a firing range. After lead bullets were removed by standard sieve #18 (1.0 mM), Pb concentrations were measured by EPA Method 3050B (9,443 mg/kg) and Korea Standard Test (4,803.5 mg/kg). The results of the batch test showed that the removal efficiency curve was logarithmic and approximately 90% of lead in soil was removed, when HCl was used. In case of EDTA, the removal efficiency increased proportionally to the concentration of EDTA, up to 98% lead removal with 0.1M EDTA. High mixing strength resulted in increase of removal efficiency and kinetics showed that the most lead was extracted in 10 min.

A Study on Operating Method to Save Energy from the Adsorption Dryer in the Process of Purifying Compressed Air (고순도 압축공기 제조시스템의 흡착식 Dryer에서 에너지절감을 위한 운전방법에 관한 연구)

  • Kang, Seok-Wan;Chang, Sung-Ho;Kim, Hyeon-Joon;Kim, Sung-Soo;Lee, Yeong-Wook
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.39 no.3
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    • pp.180-191
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    • 2016
  • Optimizing energy usage for maximum efficiency is an essential goal for manufacturing plants in every industrial manufacturing sector. The generation and distribution of purifying compressed air is a large expense incurred in practically all manufacturing processes. Not only is the generation and treatment expensive equipment of compressed air, but frequent maintenance and effective operation is also required. As a plant's compressed air system is often an integral part of the production process, it needs to be reliable, efficient, and easy to be maintain. In this paper, we study to find operating method to save energy from the adsorption dryer in the process of purifying compressed air, which is required for a clean room production site in "A" company. The compressed air passes through a pressure vessel with two "towers" filled with a material such as activated alumina, silica gel, molecular sieve or other desiccant material. This desiccant material attracts the water from the compressed air via adsorption. As the water clings to the desiccant, the desiccant particle becomes saturated. Therefore, Adsorption dryer is an extremely significant facility which removes the moisture in the air $70^{\circ}C$ below the dew point temperature while using a lot of energy. Also, the energy consumption of the adsorption dryer can be varied by various operating conditions (time, pressure, temperature, etc). Therefore, based on existing operating experiments, we have searched operating condition to maximize energy saving by changing operating conditions of the facility. However, due to a short experiment period (from September to October), further research will be focused on considering seasonality.

Physicochemical Properties and Formulation of Citrus Juice Extracted with Different Methods (유자의 착즙방법별 착즙액의 특성 및 관능검사)

  • 김민정;이경애;박갑주;강현민;김강성
    • Korean Journal of Environmental Biology
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    • v.21 no.1
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    • pp.31-35
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    • 2003
  • The effects of different extraction methods on quality of citron juices were investigated in terms of chemical composition and sensory evaluation. Extraction methods employed were press-filtration with 400 mesh sieve, centrifugation, and enzyme pretreatment using pectinase. Enzyme pretreatment method showed the highest yield of juice with 68%, while press-filtration method, the lowest yield of juice with 26.3%. The pH of the juices was relatively similar at 3.29~3.34. Filter-pressed juice showed the highest concentration of soluble solid at 6.0$^{\circ}$Brix, while the juice produced using centrifugation showed the lowest concentration at 4.5$^{\circ}$Brix. In all the juices, fructose was the main soluble sugar. Concentration of organic acid was the highest with the juice produced with centrifugation so that supplementation with higher amount with sugar was needed for overall acceptability.