• Title/Summary/Keyword: shift system change

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Hyperfine Interaction Integrals for NMR Chemical Shifts in 5f Paramagnetic Systems

  • 이기학;이지영;김동희
    • Bulletin of the Korean Chemical Society
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    • v.18 no.4
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    • pp.424-427
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    • 1997
  • To study the NMR chemical shift arising from the 5f-electron orbital angular momentum and the 5f-electron spin dipolar-nuclear spin angular momentum interactions, the evaluation of the hyperfine integrals has been extended to any pairs of SCF type 5f orbitals adopting a general method which is applicable to a general vector R, pointing in any direction in space. From the electronic wavefunctions for 5f orbitals expressed in common coordinate system, the radial part of the hyperfine interaction integrals are derived by translating the exponential part, r2 exp(-2βr), in terms of R, rN and the modified Bessel functions. The radial integals for 5f orbitals are tabulated in analytical forms. When two of the hyperfine integrals along the (100), (010), (001), (110), and (111) axes are calculated using the derived radial integrals, the calculated values for the 5f system change sign for R-values larger than R 0.35 nm. But the calculated values for the 4f systems change sign for R-values larger than R 0.20 nm.

Interfacial Features of Colloidal Particles in Aqueous Environment and Change in Its Stability According to Influential Conditions (수중 콜로이드성 고형물의 계면화학적 특성 및 영향 인자 조건에 따른 안정성의 변화)

  • Shin, Sung-Hye;Kim, Dong-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2227-2238
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    • 2000
  • The interfacial features of suspension system made of $CaCO_3$ particles have been investigated for the purpose of designing its effective treatment process. For the examination of variation of electrokinetic potential as a function of pH. the value of potential was observed to shift in the negative direction, which was thought to be due to the adsorption of hydroxide ion on the particle surface. Adsorption of surfactant on suspended particles resulted in the change of surface charge and shift in electrokinetic potential, which was dependent upon the sign of head charge and concentration of surfactant. Addition of inorganic salts affected stability of suspension greatly and sedimentation rate of suspension was influenced by the electric valence and amount of ions produced by dissolution of inorganic coagulants. DLVO theory made it possible to construct a energy profile diagram and a close correlation was found between experimental result and theoretically derived consequences. Non-specific adsorption of indifferent electrolyte resulted in the compression of electrical double layer and specific adsorption induced the shift of IEP and PZC in the opposite direction.

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Nursing Activities on Continuous Renal Replacement Therapy in the Intensive Care Units (중환자실 내 지속적 신대체 요법과 관련된 간호업무 분석)

  • Yun, Seonyoung;Lee, Young Ock;Kang, Jiyeon;Yun, Mi-Jeong;Won, Youn-Hui;Lee, Mi-Young
    • Journal of Korean Critical Care Nursing
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    • v.6 no.2
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    • pp.65-77
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    • 2013
  • Purpose: The purpose of the study was to analyze the nursing activities related to continuous renal replacement therapy (CRRT) in the intensive care units (ICU). Methods: We developed a list of 31 CRRT related nursing activities based on literature review and reviewed by expert group. A total of 109 direct time measurement records by 43 ICU nurses were collected and analyzed in terms of total time per shift, frequency, standard time, difficulty and performance levels of each CRRT nursing activity. Results: The mean time for CRRT nursing activity was 85.60 minutes per 8 hour shift. Nurses have spent average $9.46{\pm}6.98$ minutes in a shift for "waste fluid bag change" activity. In addition, "check catheter location" was the most time consuming single activity. The most difficult activity was "counseling-answer" and the most competent one was "dialysis solutions change". Conclusion: The CRRT nursing activities accounted for a significant portion of total nursing workload. Practical allocation of nursing staff for CRRT patient along with development of a new nursing cost system need to be considered. Continuous nursing educational and training programs on CRRT should be developed.

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An Analysis and Improvement of the Experiment about the Effect of Pressure on the Equilibrium of the NO2 - N2O4 System (NO2 - N2O4 사이의 평형에서 압력의 영향에 관한 실험의 문제점 분석 및 개선)

  • Eung-Gyu Kang;Seong-Joo Kang
    • Journal of the Korean Chemical Society
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    • v.47 no.3
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    • pp.283-291
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    • 2003
  • The purpose of this research was to analyze and improve the experiment, observing the color change under compression on the equilibrium of $2NO_2\;{\rightleftarrow}\;N_2O_4$ system, described in high school and general chemistry textbooks. Chemistry textbooks described that the reddish brown color got lighter on the compression of $2NO_2\;{\rightleftarrow}\;N_2O_4$ system. This misinterpretation was due to no consideration of $NO_2$ concentration increase by the volume decrease. In order to propose a correct interpretation, the changes of color and temperature on compression were quantitatively measured and compared with theoretical studies. In addition, an improved experiment, excluding the effect of $NO_2$ concentration increase, was proposed to observe only the color change of the net equilibrium shift.

A Study on Factors Influencing on Continuous Usage Intention of Open Course Ware (오픈코스웨어의 지속적 사용의도에 영향을 미치는 요인에 관한 연구)

  • Lee, Jaemo;Gim, Gwangyong
    • Journal of Information Technology Services
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    • v.15 no.2
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    • pp.93-106
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    • 2016
  • Recently, Open Course Ware service area which offers free lecture materials has been steadily growing. This change comes from a paradigm shift of education service caused by the progress of ICT and a role change of consumers. Knowledge creation from higher educational institutions is slow compared to change of society. Therefore, consumers escape from one-sided education, and perform a new role of knowledge generation. Nevertheless, there is not much of academic research of Open Course Ware. Consequently, the paper is dedicated to empirical study on effect of perceived value, information system quality and brand trust on intention to continuous use. As implications for the research, as a practical point of view, the results-an economic side that offers contents for free of charge, a contents side that is fresh, various and substantial, a systematic side that makes customers to use the system easily, a service side which takes charge of customers support and brand trust affect satisfaction and intention to continuous use - can be used for establishment of executive strategies.

Surface acoustic wave gas sensors by assembling gas chromatography column (가스 크로마토그래피를 부착한 표면탄성파 가스 센서)

  • Yoo, Beom-Keun;Park, Yong-Wook;Kang, Chong-Yun;Yoon, Seok-Jin;Choi, Doo-Jin;Kim, Jin-Sang
    • Journal of Sensor Science and Technology
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    • v.16 no.1
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    • pp.39-43
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    • 2007
  • This paper presents characteristics of surface acoustic wave (SAW) gas sensor for detecting volatile gases such as acetone, methanol, and ethanol by measuring phase shift of output signal. A delay-line by combining with a center frequency of 200 MHz was fabricated on S-T Quartz substrates. Using gas chromatography column, the selectivity of the SAW gas sensor were introduced. Experimental results, which show the phase change of output signal under the absorption of volatile gas on sensor surface, were presented. This SAW gas sensor system may be well suited for a high performance electronic nose system.

Improved sensitivity of surface acoustic wave gas sensors by using polyurethane absorption layer (폴리우레탄 감지막에 의한 표면탄성파 가스 센서의 감지능 향상)

  • Yoo, Beom-Keun;Park, Yong-Wook;Choi, Doo-Jin;Kim, Jin-Sang;Yoon, Seok-Jin;Kim, Hyun-Jai
    • Journal of Sensor Science and Technology
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    • v.16 no.5
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    • pp.349-354
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    • 2007
  • This paper presents characteristics of surface acoustic wave (SAW) gas sensor for detecting volatile gases such as ethanol gas by measuring the phase shift of output signal. A delay-line with a center frequency of 400 MHz was fabricated on $128^{\circ}$ Y-Z $LiNbO_{3}$ substrates. Experimental results, which showed the phase change of the output signal under the absorption of volatile gas on sensor surface, were presented. The sensitivities of SAW delay lines coated with polyurethane films were greatly increased compared to those for uncoated devices. This SAW gas sensor system may be well suited for a high sensitivity electronic nose system.

AN INTEGRATED PROCESS CONTROL PROCEDURE WITH REPEATED ADJUSTMENTS AND EWMA MONITORING UNDER AN IMA(1,1) DISTURBANCE WITH A STEP SHIFT

  • Park, Chang-Soon
    • Journal of the Korean Statistical Society
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    • v.33 no.4
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    • pp.381-399
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    • 2004
  • Statistical process control (SPC) and engineering process control (EPC) are based on different strategies for process quality improvement. SPC re-duces process variability by detecting and eliminating special causes of process variation, while EPC reduces process variability by adjusting compensatory variables to keep the quality variable close to target. Recently there has been need for an integrated process control (IPC) procedure which combines the two strategies. This paper considers a scheme that simultaneously applies SPC and EPC techniques to reduce the variation of a process. The process model under consideration is an IMA(1,1) model with a step shift. The EPC part of the scheme adjusts the process, while the SPC part of the scheme detects the occurrence of a special cause. For adjusting the process repeated adjustment is applied according to the predicted deviation from target. For detecting special causes the exponentially weighted moving average control chart is applied to the observed deviations. It was assumed that the adjustment under the presence of a special cause may increase the process variability or change the system gain. Reasonable choices of parameters for the IPC procedure are considered in the context of the mean squared deviation as well as the average run length.

Improved sensitivity of surface acoustic wave gas sensor by using polyurethane absorption layer (폴리우레탄 감지막에 의한 표면탄성파 가스 센서의 감지능 향상)

  • Yoo, Beom-Keun;Park, Yong-Wook;Choi, Doo-Jin;Kim, Hyun-Jai;Kim, Jin-Sang;Yoon, Seok-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.364-364
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    • 2007
  • This paper presents characteristics of surface acoustic wave (SAW) gas sensor for detecting volatile gases such as ethanol gas by measuring phase shift of output signal. A delay-line with a center frequency of 400MHz was fabricated on 128o Y-Z $LiNbO_3$ substrates. Experimental results, which show the phase change of output signal under the absorption of volatile gas on sensor surface, were presented. The sensitivities of SAW delay lines coated with polyurethane films are greatly increased compared to those for uncoated devices. This SAW gas sensor system may be well suited for a high sensitivity electronic nose system.

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Identifuication of College Student's And Teacher's Conceptions for Chemical Equilibrium and Equilibrium Shift (화학평형과 평형이동에 대한 대학생과 교사들의 개념조사)

  • Park, Jong Yun;Park, Hyeon Ju
    • Journal of the Korean Chemical Society
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    • v.46 no.3
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    • pp.265-278
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    • 2002
  • A concept test was administered to college students and teachers to identify their understanding of chemical equilibrium and equilibrium shift. The subjects were 53 freshmen in the General Chemistry class, 28 juniors in the Physical Chemistry class and 26 seniors from a university and 10 high school teachers in Seoul. Test items include the calculations of partial pressure and concentration of the gas in the mixture, the equilibrium constant cal-culation and the prediction of equilibrium shift when an inert gas is added to the gaseous reaction system, and the equilibrium concentration calculation and the prediction of equilibrium shift when water or common ion is added to the weak acid solution. The test was focused to identify whether the subjects can predict equilibrium shift using the reaction quotient change for the situations in which Le Chatelier principle is difficult to apply. The results showed that the achievements of teachers and juniors were significantly higher than those of freshmen and seniors. Many stu-dents had difficulties in predicting equilibrium shift using the reaction quotient while they could calculate partial pres-sure and concentration for the same situation. It means they are lack of conceptual understanding of chemical equilibrium shift.