• 폴리머
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• 제34권3호
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• pp.261-268
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• 2010

본 연구에서는 상전이 온도가 36 $^{\circ}C$인 n-eicosnae을 열가소성 폴리올레핀 고분자인 폴리프로필렌과 블렌드하였으며, 또한 최근의 형태안정성 PCM(SSPCM)의 연구검토를 통하여 폴리프로필렌과 n-eicosnae의 특성과 잠열저장체로서의 적용 가능성을 확인하였다. 상전이 온도가 36 $^{\circ}C$인 n-eicosane과 폴리프로필렌을 멜팅방법과 흡수방법을 이용하여 시료를 제조하였다. 제조된 형태안정성 PCM(SSPCM)을 DSC, WAXD, FTIR spectroscopy, ARES로 분석결과 형태안정성, 열용량의 향상을 확인하였다.

• 폴리머
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• 제39권1호
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• pp.23-32
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• 2015

상 전이 물질인 파라핀 왁스를 초고분자량 폴리에틸렌(UHMWPE)과의 absorption method를 통해 파우더를 제조 후 hot press를 사용하여 형태안정성 상 전이 물질(SSPCM) composite를 제조하였다. SSPCM composite의 화학, 미세구조, 형태, 열적, 결정구조, 유변학적 특성을 조사하기 위하여 FTIR, SEM, DSC, XRD, ARES 측정을 하였다. FTIR 분석결과 파라핀 및 UHMWPE의 고유 피크들이 나타나고 있는 것을 확인하였고, SEM 분석결과 파라핀의 농도가 40 wt%까지는 표면이 상당히 팽윤되며 거친 특성을 나타냄을 확인할 수 있었고, DSC 분석결과 SSPCM에서 파라핀 및 UHMWPE의 고유 융점들이 나타났고, XRD 분석에서는 파라핀과 UHMWPE의 $2{\theta}$ 값들이 SSPCM에서도 나타남을 확인할 수 있었고, ARES 분석에서는 파라핀 농도에 따른 G', G", $tan{\delta}$ 값의 변화를 확인할 수 있었다. 종합적인 분석 결과를 통해, 파라핀의 농도가 30 wt%일 때, 형태안정성 측면에서 최적의 농도임을 확인할 수 있었다.

• 설비공학논문집
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• 제25권3호
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• pp.126-130
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• 2013

In this study, a shape-stabilized phase change material (SSPCM) was prepared by octadecane and exfoliated graphite nanoplate (xGnP) in a vacuum, to improve thermal storage performance. The octadecane as an organic phase change material (PCM) is very stable against phase separation of PCM, and has the proper temperature range for thermal comfort in the building; and the xGnP is a porous carbon nano-material. Scanning electron microscope (SEM) and Fourier transformation infrared spectrophotometer (FT-IR) were used to confirm the chemical and physical stability of the Ocatadecane/xGnP SSPCM. In addition, thermal properties were determined by Deferential scanning calorimeter (DSC), and Thermogravimetric analysis (TGA). The specific heat of Octadecane/xGnP SSPCM was $14.1J/g{\cdot}K$ at $31.3^{\circ}C$. The melting temperature ranges of melting and freezing were found to be $26{\sim}35^{\circ}C$ and $26{\sim}19^{\circ}C$, respectively. At this time, the latent heats of melting and freezing were 110.9 J/g and 104.5 J/g, respectively. The Octadecane was impregnated into xGnP by as much as about 56.0% of the Octadecane/xGnP SSPCM's mass fraction.

• 한국태양에너지학회 논문집
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• 제33권1호
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• pp.73-78
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• 2013

Hexadecane and exfoliated graphite nanoplate (xGnP)composite was prepared as a shape-stabilized phase change material (SSPCM) in a vacuum to develope thermal energy storage. The Hexadecane as an organic phase change material (PCM) is very stable against phase separation of PCM and has a melting point at $18^{\circ}C$ that is under the thermally comfortable temperature range in buildings. The xGnP is a porous carbon nanotube material with high thermal conductivity. Scanning electron microscope (SEM) and Fourier transformation infrared spectrophotometer (FT-IR)were used to confirm the chemical and physical stability of Hexadecane/xGnP SSPCM. In addition, thermal properties were determined by Deferential scanning calorimeter(DSC) and Thermogravimetric analysis (TGA). The specific heat of Hexadecane/xGnPSSPCM was $10.0J/g{\cdot}K$ at $21.8^{\circ}C$. The melting temperature range of melting and freezing were found to be $16-25^{\circ}C$ and $17-12^{\circ}C$. At this time, the laten heats of melting and freezing were 96.4J/g and 94.8J/g. The Hexadecane was impregnated into xGnP as much about 48.8% of Hexadecane/xGnP SSPCM's mass fraction.

• 복합신소재구조학회 논문집
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• 제6권2호
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• pp.1-7
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• 2015

As energy consumption of building and the reduction of carbon dioxide emissions have been emphasized, phase change materials(PCM) have been introduced as building materials due to its high heat storage performance. Using shape-stabilizing technique, octadecane/xGnP shape-stabilized PCM(SSPCM) can prevent leakage and improve heat storage performance. The objectives of this study are to propose mix design method of concrete mixed with SSPCM and to evaluate mechanical behaviors of the concrete mixed with SSPCM manufactured according to the proposed mix design. Based on the previously reported material test result, the existing mix design of plain concrete(Concrete standard specification, 2009) is modified to consider reduction of strength in concrete due to the addition of SSPCM. To verify the proposed mix design, specimens are fabricated according to the proposed mix design and axial strength tests and three-point loading tests are performed. Test results show that compressive strengths of the tested specimens reach the designed strength even when two different mix ratios of SSPCM are used. From three-point loading tests, flexural stresses decrease as mix ratio of SSPCM increases.