• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.432-436
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• 2001

In this study, calcium sulfate(gypsum) powder was obtained using waste sulfuric acid and stainless refinery sludge by- produced from chemical reagent and the iron industry, by the neutralization of waste sulfuric acid. As variables for the experiment the mole ratio of the H$_2$SO$_4$ : Ca(OH)$_2$, the pH, the reaction temperature and time, the amount of catalyst were used. The crystal shape and microstructure of obtained powder were observed by XRD and SEM, and the thermal property was investigated by DTA. As the NaCl is added 0~20wt% as a catalyst to the H$_2$SO$_4$ : Ca(OH)$_2$, system it can be found that the crystal shape goes through the processes as follows : gypsum dihydratlongrightarrowgypsum hemihydrate＋gypsum dihydratelongrightarrowgypsum hemihydrate. And gypsum hemihydrate is $\beta$-type as the result of DTA. As waste sulfuric acid and stainless refinery sludge were used, the pH of reacted solution (which was 0.8) was rapidly raised up to 8~9 by the addition of stainless sludge and gypsum dihydrate was produced as a by-product. Therefore, it was found that stainless refinery sludge is sufficiently applicable for the neutralization of waste sulfuric acid.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.8 no.4
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• pp.1-6
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• 2009

Air drying technology was developed as an equipment for reducing of moisture content from wastewater treatment and waterworks sludge cake and reproducing it by reusable matter. Advantage of cyclone type pneumatic dehydrator is simple and excellent drying performance. The air drying equipment was composed to the air ejector which made high-speed fluid field, and cyclone which made circling fluid field. Dewatered cake was crushed at the high-speed zone as first step, and formed with dried powder of sphere shape by the collision between particles at the circling fluid zone. In this study, a CFD analysis has been performed to predict air-sludge particles flow in cyclone and ejector of pneumatic dehydrator. The computational results showed typical Rankine vortex structure which was frequently found in swirling flow phenomena. And the conical type wedge in lower part of a cyclone prevented accumulation of the sludge particles in the cyclone. Therefore, this technology was effective in drying of dehydrated cake of waterworks sludge.

• Analytical Science and Technology
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• v.12 no.4
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• pp.318-325
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• 1999

Sludges from the wastewater of hanji production were analysed to see that sludges from the bleaching process, the bleach washing process, and the paper preparation process were fibrous, while sludges from the process cooking with NaOH and the process of final chemical and microbiological treatment were non-fibrous. Sludge solution from the bleaching process had the most amount of solid matters. Sludges from the bleaching process, the bleach washing process, and the final chemical and microbiological treatment process contained about 80-90 %(w/w) moisture. Owing to hypochlorite ion, pH of sludge from the bleaching process was higher than any other sludge samples. The inorganic components of sludges were determined by ICP-AES. The major inorganic component of sludge from the process cooking with NaOH was Na, while the sludge from the bleaching process had Na and Ca, major components in the final chemical and microbiological treatment process were Ca and Al. Trace amount of Mg, Fe, K, P, Mn and Ti were observed in sludges. Sludge from the bleaching process had ashes more than any other sludges. Shape of sludges observed by SEM was appeared to fibrous or crystalline, and the breadth of fibrous sludge was $5{\sim}50{\mu}m$. The sludge from the bleaching process had the most amount of matters soluble by cold and hot water and by alcohol-benzene.

• Journal of Korean Society of Water and Wastewater
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• v.13 no.4
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• pp.35-44
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• 1999

In this study, it was attempted to remove nitrate and carbon in a single-stage reactor using acetate as substrate. Hybrid type upflow sludge baffled filter reactor was adopted using anaerobic sludge. Sludge bed in the bottom of reactor was intended to remove carbon and nitrate by denitrification and methanogenesis. And floating media in the upper part of reactor were intended to remove remaining carbon which was not removed due to the inhibition of nitrogen oxide on methane producing bacteria. The reactor removed over 96% of COD and most of nitrate with volumetric loading rate of $4.0kgCOD/m^3{\cdot}day$, hydraulic retention time of 24hr, 4,000mgCOD/L, and $266mgNO_3-N/L$. Nitrate in anaerobic sludge was converted to nitrogen gas(denitrification) or ammonia (ammonification) according to pH of influent, COD removal efficiency was easily affected by the change of volumetric loading rates and nitrate concentration. And when influent pH was about 4.7, most nitrate changed to ammonia while when influent pH was about 6.8~7.0, most nitrate denitrified independent of $COD/NO_3-N$ ratio. Most granules were gray and a few were black. In gray-colored granule, black inner side was covered with gray substance and SEM illustrated Methanoccoci type microorganisms which were compact spherical shape. Anaerobic filter removed residual COD effectively which was left in sludge bed due to the inhibition of nitrogen oxide.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.1
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• pp.62-75
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• 2000

Most of biological treatment to remove contaminants in municipal wastewater have been conducted by activated sludge process. But, the process have several probIems such as enormous site needed for construction of treatment facilities, unstable treatment due to limited ability to control load fluctuation, frequent sludge bulking and appearance of lots of surplus sludge. In this study, the experiments were performed through submerging biofilm of PEPP media in existing aeration tank with raw water from municipal wastewater treatment plant and then submerging PVDC and PEPP media, different from shape and chemical peculiarity in anoxic reactor. Throughout the experience, nutrient removal efficiency according to HRT, nitrogen phosphorous removal efficiency, behavior of nitrogen and dewatering efficiency have been compared and analysed with those of activated sludge process. As the results, BOD removal efficiency according to BOD volumetric load and F/M ratio was not found any differency in two processes, but was decreased below 90% as going along the condition of high load in activated sludge process. Kinetic coefficient was $K_{max}=1.162day^{-1}$, $K_s=53.77mg/L$, $Y=0.166mgVSS/mgBOD_{rem}$. and $K_d=0.019day^{-1}$. It was found that the removal efficiency, even though in aerobic condition, in biofilm process equipped anoxic reactor was higher than the one in activated sludge process within the range of 70~80%, and became better as HRT increased. Phosphorous removal efficiency was not found any differency in two processes. In biofilm process, treament efficiency even in conditions of high load was not decreased, because the biomass concentration could be maintained in high condition compared with activated sludge process. As HRT increased, suspended and attached biomass was increased and the other hand, F/M ratio was decreased as biomass' increasing. Biomass thickness was increased. from $10.43{\mu}m$ to $10.55{\mu}m$ as HRT increased and density of biomass within $40.79{\sim}41.16mg/cm^2$. The results also present that the dewatering efficiency of sludge generated in biofilm process was higher than in activated sludge process, and became better as HRT increased.

• Korean Journal of Materials Research
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• v.29 no.10
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• pp.592-602
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• 2019

Feasibility is investigated for reduction of chromium ore by Si sludge with mixed silicothermic and carbothermic reaction. The reduction behavior of chromium ore using Si sludge is investigated precisely to determine the effects of carbon addition, reaction time, and reaction temperature. The pellets are dropped into the furnace after temperature stabilized. As the amount of C addition increases, the amounts of CO and $CO_2$ gas generation increase. After the dropping of the pellets, the pellets are heated and the reaction starts at about 1,573 K or higher. The pellets maintain their shape until 10 min after the drop, and then melted. As the holding time increased, the size of the reduced metal particles increased. The chromium ore is rapidly reduced by the Si sludge, and the slag penetrated into the chromium ore and reduction progressed inside. As the reduction temperature increased, the reaction initiation time is shortened and the reaction fraction of the reduction reaction increased. As the reaction temperature increased, agglomeration of reduced ferrochrome metal is promoted.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.9 no.3
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• pp.42-48
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• 2010

The aim of this study is to investigate the influence of driving atomizing nozzle position, the slope of sludge entering tube and supplying air flow rate on the performance of sludge air dryer. This paper deals with optimization of the geometry of the atomizing nozzle for sludge drying using computational fluid dynamics and drying performance test using pilot air dryer. The air drying system was composed of the atomizing nozzle which made high-speed fluid field. dewatered cake was crushed at the high-speed zone as the first step and formed intto dried powder of sphere shape by the collision between particles at the circling zone. The CFD analysis results show when the slope of entering sludge tube is smaller, suction air amount is increased. It is shown that the developed atomizing nozzle is very excellent in the drying performance through pilot test.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.917-921
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• 2002

In this paper, we made different types of non-thermal plasma reactors such as Metal-particle reactor with $Al_2O_3$ to measure NOx removal characteristic and the dielectric effect for NOx removal. NOx removal rate is not so good when we use just dielectric of $Al_2O_3$ at the Metal-particle reactor, also we just put sludge pellets(100%) without Metal-particle reactor with $Al_2O_3$ and dielectric such as $TiO_2$, $BaTiO_3$ to measure the effect of sludge for NOx removal so that NOx removal rate is almost the same. However NOx removal rate is more than 90% in case of the reactor of composition shape used both dielectric of $Al_2O_3$ and sludge pellets at the same time. In case of the shape of plasma reactor with dielectric, the Metal-particle reactor with $Al_2O_3$, and the metal-particle reactor with both $Al_2O_3$ and dielectric such as $TiO_2$, $BaTiO_3$ at the same time, they are almost the same effect for NOx removal, so we made MNPR(Metal-particle Non-thermal Plasma Reactor with $Al_2O_3$) to reduce these kinds of demerits. Finally, we think MNPR should be much better than other reactors for NOx removal.

• Analytical Science and Technology
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• v.10 no.6
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• pp.418-426
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• 1997

Dewatered digested sewage sludge were heated with microwave and their drying characteristics were investigated on the effect of their surface area, shape, diameter and thickness. The drying characteristics of identical samples in a conventional drying oven were studied. In conventional drying, constant rate period was not found and moisture was evaporated with capillary action. Moisture in the sludge was a bound water and free water was not exist. In microwave drying, the falling rate period was divided into two zones. In falling rate drying period, moisture movement occured by diffusion. The evaporation surface area was a significant variable, the greater heating surface area promoted water removal rate over wide region of water content. Drying rate was slow and constant rate drying period was found in wide moisture content region with increasing diameter. Drying characteristics appeared differently in various shape. In microwave heating, first of all temperature of sludge center was increased and was the highest. Temperature in the constant rate drying period was remained constantly at $80{\sim}100^{\circ}C$.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.269-274
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• 2001

The purpose of this study is to evaluate basic properties of artificial aggregate using concrete sludge according to mixing ratio. Cement, waste phosphogypsum and Powder of blast furnace slag are used with binder of artificial aggregate. Specific gravity, absorption are tested for basic property, and impacting, abrasion and crushing tests are done for characteristics of strength on the aggregate, including comparison with crushed stone. Bry specific gravity was ranged about 1.16 to 1.30 the test result of the aggregates and shape is round In the result of tests, it is concluded that qualities of the aggregates using concrete sludge are slightly lower than crushed stone but it is similiar with sintering artificial lightweight aggregate in high temperature.