• Journal of Environmental Science International
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• v.27 no.11
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• pp.1023-1028
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• 2018

Shape memory materials are widely used in high-tech industries. Although shape memory polymers have been developed, they have a disadvantage, only unidirectional resilience. Shape memory polymers with bi-directional recovery resilience have been actively studied. In this study, a bidirectional shape memory polyurethane was synthesized using poly(${\varepsilon}$-caprolactone) diol, methylene dicyclohexyl diisocyanate, and hydroxyethyl acrylate. The first physical curing occurred between hard segments and hydrogen bondings when the solution was dried. The second curing in acrylate groups was performed by UV exposure. A degree of curing was analyzed by infrared spectroscopy. The shape memory properties of 2 step-cured polyurethanes were investigated as a function of UV curing time.

• Transactions of the Society of Information Storage Systems
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• v.11 no.2
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• pp.36-40
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• 2015

The demand for flexible devices including solar cells, memories and batteries has increased rapidly over the past decades. In most flexible devices, polymer-based materials are used to enable the mechanical deformations such as bending or folding. Shape Memory Polymers (SMPs) is a high molecular compound polymer with flexibility and shape recovery characteristics. In this work, flexible shape memory device was fabricated by simply coating the conducting material, carbon nano-tube (CNT), on a shape memory polymer. Furthermore, durability of the device under various type of mechanical deformations was assessed. It is believed that the result of this work will aid in realization of a stretchable and wearable electronic device for practical applications.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.45 no.12
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• pp.1007-1012
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• 2017

In this study, we performed the deployment test of shape memory polymer specimens for space antenna design. Poly(cyclootene) was cross-linked by dicumyl peroxide to make a PCO shape memory polymer. A miniature specimen with 120 mm diameter for a deployable antenna was fabricated with the PCO shape memory polymer. To investigate the deployment performance, the folded specimen as a temporary shape was heated by two heaters to the $15^{\circ}C$ higher temperature than the glass transition temperature of shape memory polymer. Firstly, the specimen was installed horizontally and tested. The deploying motion was captured by a digital camera and analyzed by a Tracker program. To reduce the effects of gravity, the specimen was installed vertically and tested again. The deployment performance of a shape memory polymer was investigated by comparing the results of horizontal and vertical installation tests.

• Elastomers and Composites
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• v.45 no.3
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• pp.188-198
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• 2010

The term 'shape memory polymers (SMPs)' describes a class of polymers which can remember the original shape and recover from deformed to its original shape by the applied stimuli, e.g., heat, electricity, magnetic field, light, etc. SMPs are classified as one of the 'smart polymers' and have great potentials as high-value-added materials. Especially, low thermal, electrical, and mechanical properties of SMPs can be improved by incorporating the various fillers. This paper aims to review the SMPs and their basic principles, and the trends of the development of SMPs nanocomposites.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.21 no.10
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• pp.1609-1618
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• 1997

Thermo-mechanical behaviors of polymer matrix composite(PMC) with continuous TiNi fiber are studied using theoretical analysis with 1-D analytical model and numerical analysis with 2-D multi-fiber finite element(FE) model. It is found that both compressive stress in matrix and tensile stress in TiNi fiber are the source of strengthening mechanisms and thermo-mechanical coupling. Thermal expansion of continuous TiNi fiber reinforced PMC has been compared with various mechanical behaviors as a function of fiber volume fraction, degree of pre-strain and modulus ratio between TiNi fiber and polymer matrix. Based on the concept of so-called shape memory composite(SMC) with a permanent shape memory effect, the critical modulus ratio is determined to obtain a smart composite with no or minimum thermal deformation. The critical modulus ratio should be a major factor for design and manufacturing of SMC.

• Proceedings of the IEEK Conference
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• 2005.11a
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• pp.825-828
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• 2005

In this paper, we propose a new nonvolatile unit memory cell and proposal peripheral circuit using the polymer material. Memory that relies on bistable behavior- having tow states associated with different resistances at the same applied voltage - has attracted much interest because of its nonvolatile properties. Such memory may also have other merits, including simplicity of structure and manufacturing, and the small size of memory cells. We have plotted the load line graphs for the use of a polymer memory character, hence we have designed in the band-gap reference shape of a write/erase drive, and then designed in the 2-stage differential amplifier shape of a sense amplifier in the consideration of a low current characteristic of a polymer memory cell. The simulation result shows that is has high gain about 80dB by sensing the very small current.

• Fibers and Polymers
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• v.7 no.4
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• pp.328-332
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• 2006

Poly(ethylene terephthalate) (PET) and poly(ethylene glycol) (PEG) copolymers cross-linked with pentaerythritol, a four-way cross-linker, are prepared to compare their mechanical and shape memory properties with the one cross-linked by glycerol. Composition of PEG and pentaerythritol is varied to search for the one with the best mechanical and shape memory properties. The highest shape recovery rate is observed for the copolymer composed of 30 mol% PEG-200 and 2.5 mol% pentaerythritol. Four-way cross-linking by pentaerythritol significantly improves shape recovery rate and retention of high shape recovery rate after repeated use compared to the one cross-linked by glycerol, a three-way cross-linker, and difference and advantage of additional cross-linking point are discussed.

• Composites Research
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• v.31 no.6
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• pp.347-354
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• 2018

Shape memory polymer composites have been studied for deployable antennas in space because they have advantages of lightweight, large deformability, good processability, and low cost. In this research, shape memory polymer composites (SMPCs) were manufactured using carbon nanotubes (CNTs) as reinforcements and were used to fabricate SMPC antenna. The SMPCs were prepared by dispersing CNTs in the polymer matrix. Various dispersion methods were investigated to determine the most suitable one, focusing on the mechanical properties of SMPCs including their fracture behavior. The shape memory properties of SMPCs were measured and finally, the deployment behavior of the SMPC antenna was analyzed.

• Journal of Institute of Control, Robotics and Systems
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• v.10 no.11
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• pp.976-980
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• 2004

This study has introduced how to make conducting shape memory polyurethane(CSMPu) as a possible application to smart actuators. Different from conventional polyurethane, CSMPu can have a high conductivity and then electric power supplies enough energy to deform. To prepare conducting polyurethane, carbon nanotubes were incorporated into shape memory polyurethane. Basic experiments to reveal its characteristics have been conducted for a development of actuators. From the results conducted in the present study, optimized conditions for the process of actuating deformation were found. Thermo-electric characteristics such as the relation between temperature and specific resistance and trend curves of resistance variations according to elongations were measured. These data provided a strong possibility of CSMPu as a smart actuator.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2012.10a
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• pp.809-810
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• 2012