• Title/Summary/Keyword: serpentine

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Heavy metal concentration of plants in Baekdong serpentine area, western part of chungnam (충남 서부 백동 사문암지역 식물체의 중금속 함량)

  • 송석환;김명희;민일식;장인수
    • Journal of Korea Soil Environment Society
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    • v.4 no.2
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    • pp.113-125
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    • 1999
  • Heavy metal elements were analysed to assess degrees of heavy metal contents for the plants, M. sinensis, A. vulgaris and G. oldhamiana, from the Baekdong serpentine area within the western part of Chungnam. The area was divided into two sites ; serpentine area (SP, consisting of serpentinite, SP) and non-serpentine area (NSP, containing amphibole schist, AS and gneiss, GN). Their host rocks(R) and top soils(S) were also collected from the each site. As the results of the study, the plants contain high concentration of Ni Cr, Co in the SP and Fe, Zn in the AS and GN. Plants from the AS of the NSP contain mainly high content in the most of elements. Averages of Ni, Co and Cr for the plants decreased in the order of SP, AS and GN. In the total element contents, M. sinensis and A. vulgaris decreased in the order of Fe > Ni or Cr > Zn > Co > As > Sc within the SP and in the order of Fe > Zn > Cr > Ni, within the GN. Comparing among the parts of plants, root parts were higher in the most of elements than the above grounds. In the relative element ratios of plants collected from the SP and GN (SP/GN) M. sinensis was lower than A. vulgaris in the most of elements, suggesting that the M. sinenis shows low absorption within the infertile serpentine soil and high absorption within the fertile gneiss soil. In the element contents of the top soils and their host rocks, the SP shows higher Ni, Co and Cr contents than the others. Their total contents decreased from SP to AS and GN, suggesting that the soils reflect the composition of their host rocks. Total element contents of the SP decreased in the order of Fe> Cr or Ni> Co> Zn> As> Sc and, for the GN, in the order of Fe> Zn> Cr> Ni> Co or Sc, respectively. In the relative element ratios, R/S of the SP decreased in the order of Cr> As> Fe> Sc> Co> Ni> Zn and for the GN, in the order of Sc> Fe> Ni> Zn> Cr> Co. Comparing with plants within the each site, their top soils were higher than the plants in the most of elements. and their increase and decrease trends for each element are similar. Differences of element contents between the top soils and plants decreased in the order of SP, AS and GN. Plants of the GN were moi-e similar to their soils than those of the others, suggesting that each plant species show different absorptions within the different soils. Comparing with the plants of GN, higher Ni, Co, Cr contents within those of the SP and their survival within the infertile serpentine soil suggest that the M. sinensis, A vulgaris and G. oldhamiana may be the tolerance species in the serpentine soil. Comparisons with the upper crust show that M. sinensis, and A. vulgaris within the SP show high Hi and Cr contents. suggestive of hyperaccumulation. Upper results with the previous studies for the contaminated soils developed as parent materials with the serpentinites suggest additional studies for ecological behaviors for the plant and degrees of accumulations for the elements need to know phytoextraction of the heavy metal elements within the soils.

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A Study on Performance of Polymer Electrolyte Membrane Fuel Cell Using Metal Foam (Metal foam을 사용한 고분자 전해질 연료전지 성능 연구)

  • KIM, MYO-EUN;KIM, CHANG-SOO;SOHN, YOUNG-JUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.6
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    • pp.554-559
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    • 2015
  • Single cell of PEMFC (polymer electrolyte membrane fuel cell) is composed of bipolar plates, gasket, GDL and the MEA. Bipolar plate's function is the collecting electricity, helping oxygen/hydrogen gas diffuse evenly and draining the water and heat. In this work, we have conducted experiments to low contact resistance and improve the performance of a $25cm^2$ single cell by using metal forms. We have following experimental cases: 1) Conventional graphite serpentine channel bipolar plate; 2) Channel-less bipolar plate with nickel(Ni) based metal foam which coated by various materials. We focused the difference in contact resistance and performance of the single cell with metal foam depending on various coating materials. The experimental results show the similar performance of single cells between with serpentine channel bipolar plates and with channel-less bipolar plate using metal foams. In addition, single cell with metal foam shows potential to higher performance than conventional channel.

COMPUTATIONAL STUDY FOR PERFORMANCE EVALUATION OF FLOW CHANNELS INSIDE CDI UNIT CELL (수치모사를 이용한 CDI Unit Cell 내부의 유로성능 평가)

  • Sohn, D.Y.;Choi, Y.H.;Park, D.W.;Jung, C.H.
    • Journal of computational fluids engineering
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    • v.15 no.1
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    • pp.31-36
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    • 2010
  • In the present study, computations for flow fields inside the CDI unit cells with electrodes and spacers have been made to evaluate their performance. Three types of unit cells that include a planar type, a serpentine channel type, and a spiral wound type were considered and their flow characteristics were compared. From the computational results, it is found that the serpentine channel type has a large flow resistance and can not guarantee the outflow flux for industrial applications. On the other hand, the planar type can sustain a large enough outflow flux but it's efficiency is low for the electrode-use because of the non-uniform velocity distribution inside the cell and dead zones in every corner. Finally, The spiral wound type has not only a large outflow flux as much as the planar type has, but also a high efficiency for the electrode-use because of uniform velocity distribution. From this comparison, we can expect that the spiral wound type of CDI unit cell would have a high performance deionization capability.

NO2 gas sensing characteristics of patterned carbon nanotube mats (패턴이 형성된 탄소나노튜브 매트의 이산화질소 감응 특성)

  • Cho, Woo-Sung;Moon, Seung-Il;Paek, Kyeong-Kap;Park, Jung-Ho;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.15 no.3
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    • pp.199-204
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    • 2006
  • Carbon nanotube (CNT) mats grown by thermal chemical vapor deposition on a micromachined substrate with a chrome heater and a diaphragm were investigated as sensing materials of resistive gas sensors for nitrogen dioxide ($NO_{2}$) gas. The aligned CNT mats fabricated into mesh and serpentine shapes by the patterned cobalt catalyst layer. CNT mats showed a p-type electrical resistivity with decreasing electrical resistance upon exposure to $NO_{2}$. All sensors exhibited a reversible response at a thermal treatment temperature of $130^{\circ}C$ for about 5 minutes. The resistance change to $NO_{2}$ of the mesh-shaped CNT mats was larger than that of the serpentine-shaped CNT mats.

VISUALIZATION OF THE INTERNAL WATER DISTRIBUTION AT PEMFC USING NEUTRON IMAGING TECHNOLOGY: FEASIBILITY TEST AT HANARO

  • Kim Tae-Joo;Jung Yong-Mi;Kim Moo-Hwan;Sim Cheul-Muu;Lee Seung-Wook;Jeon Jin-Soo
    • Nuclear Engineering and Technology
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    • v.38 no.5
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    • pp.449-454
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    • 2006
  • Neutron imaging technique was used to investigate the water distribution and movement in Polymer Electrolyte Membrane Fuel Cell (PEMFC) at HANARO, KAERI. The Feasibility tests were performed in the first and second exposure rooms at the neutron radiography facility (NRF) at HANARO in order to check the ability of each exposure room, respectively. The feasibility test apparatus was composed of water and pressurized air before making up the actual test apparatus. Due to the low neutron intensity in the second exposure room, the exposure time was too long to investigate the transient phenomena of PEMFC. Although the exposure time was improved to 0.1 sec in the first exposure room, it was difficult to discriminate detail water movement at the channel due to the high noise level. Therefore, the experimental setup must be optimized according to the test conditions. Water discharge characteristics were investigated under different flow field geometries by using feasibility test apparatus and the neutron imaging technique. The water discharge characteristics of a 3-parallel serpentine are superior to those of a 1-parallel serpentine, but water at Membrane Electrode Assembly (MEA) was not removed, regardless of the flow field type.