• 제목/요약/키워드: self quenching

검색결과 54건 처리시간 0.028초

신소호구조가 차단성능에 미치는 영향

  • 김길수;이승수;임기조;강성화
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.227-227
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    • 2009
  • To prevent such accidents, molded case circuit breakers with improved short-circuit current interrupting capacity are needed. This paper is focused on understanding the interrupting capability with respect to double contact structure and puffer assisted self quenching that are based on the shape of the contact system in the current molded case circuit breaker. The new arc quenching structure for increasing the interrupting capacity of molded case circuit breakers is investigated by simulation and experiment.

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채널 내부 대항류 산소부화 부분예혼합 화염의 저신장율 소화특성 (Low Strain Rate Flame Extinction Characteristic of Oxygen Enhanced Opposed Flow Partially Premixed Flame in a Mesoscale Channel)

  • 이민정;김남일
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.243-244
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    • 2014
  • The opposed flow flame in a mesoscale channel was constructed to observe the flame stabilization behaviors at low strain rate conditions (<$10s^{-1}$). The purpose of this study is to get the overall flame behaviors of partially premixed flames with oxygen enhanced conditions at low strain rates. The oxygen ratio in oxidizer was changed from 18 to 30 %. Conclusively, the flame extinction limit approached to about $1s^{-1}$, and divided into three representative regimes corresponding to self propagating flame, transitional flame, quenching flame regimes.

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QST압연법에 의한 고장력봉강 제조기술 (The Production Technology of High-Strength Round Bar by QST Rolling)

  • 신정호;한철호;이종수;장병록
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1997년도 춘계학술대회논문집
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    • pp.240-243
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    • 1997
  • The Quenching and Self Tempering (QST) rolling is treated in terms of an advance process on Controlled Rolling and Cooling Technology (CRCT). In the analysis, the effect of this process is governed by both quenching and finishing conditions in the related with temperature. The objective of the QST model is to simulate the temperature gradient of the stock being rolled in the rolling mill. A comparison of computer simulated and manufactured micro structure as well as mechanical properties shows a good consistency. The micro structure of this high-strength round bar consists of tempered martensite and ferrite + pearlite phases.

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저밀도 폴리에틸렌 필림의 결정화도 및 전기적 특성 (The crystallinity and electrical characteristics of low density polyetylene thin film)

  • 윤중락;권정열;이헌용
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.164-168
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    • 1996
  • The relation between crystallinity and thermal history in low density polyethylene thin films and their effect on electric conduction phenomena and dielectric breakdown was studied. The low density polythylene thin films obtained by the solution growth method heat-treated at 140[$^{\circ}C$] for 2 h and subsequently cooling to various ways. The degree of crystallinity was estimated by the X-ray diffraction measurement for the specimen of slowly cooling, ICE quenching and liquid nitrogen quenching. The result shows that the crystallinity decreases become faster as the cooling speed increased, and that conduction phenomenon is governed by the space charge limited current in high field. It was found that the dielectric breakdown field increases with an increase in cooling speed and test number in self-healing breakdown method.

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PTFE 용삭을 고려한 초고압 복합소호 차단기의 성능 예측 (Prediction of Performance considering Ablated PTFE in High Voltage Self-blast Circuit Breaker)

  • 김진범;권기영;이학성
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.695-698
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    • 2008
  • Self-blast circuit breakers utilize the energy dissipated by the arc itself to create the required conditions for arc quenching during the current zero. During the arcing period, high pressure, temperature and radiation of the arc could burn in pure SF6 gas and PTFE nozzle. Ablated nozzle shape and $SF_6$-PTFE mixture vapor affect the performance of an self-blast circuit breaker. After a number of tests, nozzle in circuit breaker is disassembled, a section of ablated nozzle is investigated precisely. Using computational fluid dynamics, the conservation equation for the gas and temperature, velocity and electric fields within breaker is solved. Before applying a section model, developed program is verified with experimental data. Performance of ablated nozzle shape is compared with original model through analysis program.

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박테리아의 Quorum Sensing 및 생물막 형성 억제를 위한 Quorum Quenching 연구 동향 (Bacterial Quorum Sensing and Quorum Quenching for the Inhibition of Biofilm Formation)

  • 이정기
    • 한국미생물·생명공학회지
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    • 제40권2호
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    • pp.83-91
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    • 2012
  • 본 총설은 N-acyl-homoserine lactone (AHL)에 기반한 quorum sensing(QS)을 비롯한 다양한 QS 시스템 및 생물막 형성과의 관련성에 대한 연구 동향을 정리하였다. 또한 anti-QS으로서 quorum quenching 전략을 이용한 생물막 억제 연구 동향에 대해 중점적으로 서술하였다. 세균의 독특한 신호전달 체계인 QS는 AHL과 같은 특정한 신호분자의 농도에 의해 세균의 집단적 행동 양식이 결정되는 세포밀도-의존성 유전자 발현 조절 메커니즘이다. QS 시스템은 미생물의 부착 및 생물막 형성에 있어 중요한 역할을 한다. AI-1이나 AI-2에 의한 QS는 생물막 형성 과정에 필요한 세포외 다당류, 단백질, 세포 외 DNA 등 주요한 구성 성분 등의 생산뿐만 아니라, 세균의 운동성 조절, 부착, 생물막 해체 과정까지도 조절하는 기능을 한다. 일부 세균의 경우 QS시스템 이외에도 second messenger로 알려진 c-di-GMP에 의한 signaling이 QS와 서로 연결되어 생물막 형성이나 병독성과 같은 타깃들을 함께 조절한다. 생물막은 병원성 세균에 의한 감염 시 여러 가지 병독성 가운데 가장 중요한 요소 중 하나이기 때문에, 생물막 형성을 조절하는 QS를 차단하기 위한 다양한 anti-quorum sensing 전략이 연구되고 있다. Anti-QS 접근 방식은 의학적 이용뿐만 아니라 물에 노출되어있는 MBR을 비롯한 많은 산업적 장치 등에서 생물막 형성으로 인한 손상 및 오염을 방지하기 위해 쓰일 수 있다. Anti-QS 전략 중 신호분자인 AHL을 무력화 시키는 quorum quenching 효소(AHL-lactonase, AHL-acylase, oxidoreductas)를 이용하여 생물막 형성을 억제할 수 있으며, 막을 이용한 수처리 공정에서 막에 발생하는 biofouling을 완화시킬 수 있는 새로운 anti-fouling 처리 기술로서 이러한 QQ 효소의적용 가능성을 보여 주고 있다.

초고압 복합소호 차단부의 열가스 거동 예측 (Prediction of Hot Gas Behavior in High Voltage Self-blast Circuit Breaker)

  • 김진범;여창호;서경보;권기영;이학성
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2494-2499
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    • 2007
  • Self-blast circuit breakers utilize the energy dissipated by the arc itself to create the required conditions for arc quenching during the current zero. The high-current simulation provides information about the mixing process of the hot PTFE cloud with $SF_6$ gas which is difficult to access for measurement. But it is also hard to simulate flow phenomenon because the flow in interrupter with high current, $SF_6$-PTFE mixture vapor and complex physical behavior including radiation, calculation of electric field. Using a commercial computational fluid dynamics(CFD) package, the conservation equation for the gas and temperature, velocity and electric fields within breaker can be solved. Results show good agreement between the predicted and measured pressure rise in the thermal chamber.

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Relaxation Process of the Photoexcited State and Singlet Oxygen Generating Activity of Water-soluble meso-Phenanthrylporphyrin in a DNA Microenvironment

  • Hirakawa, Kazutaka;Ito, Yusuke;Yamada, Takashi;Okazaki, Shigetoshi
    • Rapid Communication in Photoscience
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    • 제3권4호
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    • pp.81-84
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    • 2014
  • To examine the microenvironmental effect of DNA on the photosensitized reaction, the electron-donor-connecting porphyrin, meso-(9-phenanthryl)-tris(N-methyl-p-pyridinio) porphyrin (Phen-TMPyP), was synthesized. Phen-TMPyP can bind to oligonucleotides with two binding modes, depending on the DNA concentration. The fluorescence lifetime measurement of Phen-TMPyP shows a shorter component than that of the reference porphyrin without the phenanthryl moiety. However, the observed value is much longer than those of previously reported similar types of electron-donor-connecting porphyrins, suggesting that electron-transfer quenching by the phenanthryl moiety is not sufficient. The fluorescence quantum yield of Phen-TMPyP ($5{\mu}M$) decreased with an increase in DNA concentration of up to $5{\mu}M$ base pair (bp), possibly due to self-quenching through an aggregation along the DNA strand, increased with an increase in DNA concentration of more than $5{\mu}M$ bp and reached a plateau. The fluorescence quantum yield of Phen-TMPyP with a sufficient concentration of DNA was larger than that of the reference porphyrin. The singlet oxygen ($^1O_2$) generating activity of Phen-TMPyP was confirmed by the near-infrared emission spectrum measurement. The quantum yield of $^1O_2$ generation was decreased by a relatively small concentration of DNA, possibly due to the aggregation of Phen-TMPyP, and recovered with a sufficient concentration of DNA. The recovered quantum yield was rather smaller than that without DNA, indicating the quenching of $^1O_2$ by DNA. These results show that a DNA strand can stabilize the photoexcited state of a photosensitizer and, in a certain case, suppresses the $^1O_2$ generation.

Photochemical Property and Photodynamic Activity of Tetrakis(2-naphthyl) Porphyrin Phosphorus(V) Complex

  • Hirakawa, Kazutaka;Aoki, Shunsuke;Ueda, Hiroyuki;Ouyang, Dongyan;Okazaki, Shigetoshi
    • Rapid Communication in Photoscience
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    • 제4권2호
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    • pp.37-40
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    • 2015
  • To examine the photosensitized biomolecules damaging activity, dimethoxyP(V)tetrakis(2-naphthyl)porphyrin (NP) and dimethoxyP(V)tetraphenylporphyrin (PP) were synthesized. The naphthyl moiety of NP hardly deactivated the photoexcited P(V)porphyrin ring in ethanol. In aqueous solution, the naphthyl moiety showed the quenching effect on the photoexcited porphyrin ring, possibly through electron transfer and self-quenching by a molecular association. Binding interaction between human serum albumin (HSA), a water soluble protein, and these porphyrins could be confirmed by the absorption spectral change. The apparent association constant of NP was larger than that of PP. It is explained by that more hydrophobic NP can easily bind into the hydrophobic pockets of HSA. The photoexcited PP effectively induced damage of the tryptophan residue of HSA, through electron transfer-mediated oxidation and singlet oxygen generation. NP also induced HSA damage during photo-irradiation and the contributions of the electron transfer and singlet oxygen mechanisms were speculated. The electron transfer-mediated mechanism to the photosensitized protein damage should be advantageous for photodynamic therapy in hypoxic condition. The quantum yield of the HSA photodamage by PP was significantly larger than that of NP. The quenching effect of the naphthyl moiety is considered to suppress the photosensitized protein damage. In conclusion, the naphthalene substitution to the P(V)porphyrins can enhance the binding interaction with hydrophobic biomacromolecules such as protein, however, this substitution may reduce the photodynamic effect of P(V)porphyrin ring in aqueous media.

금형재료용 주철의 다이오드 레이저 표면경화처리에 관한 연구(II) - 표면경화의 적용 부위에 따른 열처리 특성의 차이 - (A Study on the Diode Laser Surface Hardening Treatment of Cast Iron for Die Material(II) -Comparison of Hardening Characteristics by the Parts Applied Heat Treatment-)

  • 김종도;송무근;황현태
    • Journal of Advanced Marine Engineering and Technology
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    • 제35권8호
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    • pp.1048-1054
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    • 2011
  • 레이저 표면경화처리는 고밀도 에너지 열원에 의해 레이저 조사부위만 급속 가열한 후 표면의 열이 내부로 전도되어 급속히 자기냉각 됨으로써 표면을 경화시키는 방법이다. 이 표면처리 방법은 열처리에 의한 열변형이 거의 없고, 표면경화처리 이후 다른 공정을 수반하지 않는다. 또한 국부적인 가공이 가능하기 때문에 복잡한 형상을 가지는 금형에는 적합한 표면처리 방법이다. 본 연구에서는 열처리에 적합한 빔 프로파일을 가진 고출력 다이오드 레이저를 이용하여 금형재료용 주철의 표면처리를 실시하였다. 프레스 금형 공정에 따른 금형의 형상이 다르기 때문에 적용부위에 따라 시험편을 평면과 모서리부로 나누어 열처리를 실시하였다. 이때 모서리부의 열처리는 광학헤드를 $10^{\circ}$ 기울인 상태에서 진행하였다. 그 결과, 모서리부의 열처리는 평면부와 비교하여 형상에 따른 열전달 루트가 제한되므로, 입열이 집중되기 쉬워 평면 열처리보다 빠른 이송속도에서 경화가 이루어졌다.