• 제목/요약/키워드: self ignition temperature

검색결과 48건 처리시간 0.021초

경질 폴리우레탄폼의 착화성 및 열방출특성 연구 (A Study on Ignitability and Heat Release Rate Characteristics of Rigid Polyurethane Foam)

  • 공영건;이두형
    • 한국화재소방학회논문지
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    • 제17권4호
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    • pp.117-123
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    • 2003
  • 본 연구에서는 Setchkin 착화성시험장치와 산소소비원리를 이용한 콘칼로리미터를 사용하여 난연처리되지 않은 경질우레탄폼의 착화특성 및 열방출특성 및 플래쉬오버 가능성에 대하여 연구하였다. 연구결과 경질폴리우레탄폼의 유도발화온도(FIT)는 $383^{\circ}C$$390^{\circ}C$, 자연발화온도(SIT)는 $493^{\circ}C$$495^{\circ}C$로 나타났으며 자연발화온도가 유도발화온도에 비해 약 $100^{\circ}C$ 높게 나타났다. 콘칼로리미터실험에서는 착화시간은 heat flux의 크기가 증가할수록 빨라졌으며 동일한 heat flux 크기에서는 밀도가 작을수록 착화시간은 짧게 나타났다. 열방출율은 $50 ㎾\m^2$에서 가장 크게 나타났으며, 최대열방출율의 경우 heat flux의 크기와 밀도가 커질수록 증가하는 경향을 보였다. 착화시간과 열방출율의 관점에서 경질폴리우레탄폼의 화재성능은 가해진 heat flux의 크기와 밀도에 큰 영향을 받는 것으로 나타났으며, Petrella의 제안방법에 의해 플래쉬오버 가능성을 분류한 결과 플래쉬오버 가능성이 큰 것으로 분류되었다.

A STUDY ON OXIDATION TREATMENT OF URANIUM METAL CHIP UNDER CONTROLLING ATMOSPHERE FOR SAFE STORAGE

  • Kim, Chang-Kyu;Ji, Chul-Goo;Bae, Sang-Oh;Woo, Yoon-Myeoung;Kim, Jong-Goo;Ha, Yeong-Keong
    • Nuclear Engineering and Technology
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    • 제43권4호
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    • pp.391-398
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    • 2011
  • The U metal chips generated in developing nuclear fuel and a gamma radioisotope shield have been stored under immersion of water in KAERI. When the water of the storing vessels vaporizes or drains due to unexpected leaking, the U metal chips are able to open to air. A new oxidation treatment process was raised for a long time safe storage with concepts of drying under vacuum, evaporating the containing water and organic material with elevating temperature, and oxidizing the uranium metal chips at an appropriate high temperature under conditions of controlling the feeding rate of oxygen gas. In order to optimize the oxidation process the uranium metal chips were completely dried at higher temperature than $300^{\circ}C$ and tested for oxidation at various temperatures, which are $300^{\circ}C$, $400^{\circ}C$, and $500^{\circ}C$. When the oxidation temperature was $400^{\circ}C$, the oxidized sample for 7 hours showed a temperature rise of $60^{\circ}C$ in the self-ignition test. But the oxidized sample for 14 hours revealed a slight temperature rise of $7^{\circ}C$ representing a stable behavior in the self-ignition test. When the temperature was $500^{\circ}C$, the shorter oxidation for 7 hours appeared to be enough because the self-ignition test represented no temperature rise. By using several chemical analyses such as carbon content determination, X-ray deflection (XRD), Infrared spectra (IR) and Thermal gravimetric analysis (TGA) on the oxidation treated samples, the results of self-ignition test of new oxidation treatment process for U metal chip were interpreted and supported.

발포 프라스틱의 착화특성 및 연소가스 분석 (Ignition Characteristics and Combustion Gas Analysis of the Plastics Foam)

  • 이근원;김관응
    • 한국안전학회지
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    • 제16권1호
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    • pp.48-52
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    • 2001
  • This study was undertaken to investigate fire risk characteristics of the plastics foam that is used an insulating materials in workplaces. The ignition characteristics and combustion gas of the plastics foam were carried out using the ISO self-Ignition tester, the Cone Calorimeter, and NES combustion analyzer. The experimental materials used were commercial samples and their composition is not disclosed by the manufacturer. As the experimental results, the self-ignition temperature of the plastics foam ranges from $410^{\circ}C$ to $510^{\circ}C$, and the flash-ignition temperature of plastics foam ranges from $370^{\circ}C$ to $450^{\circ}C$. The difference of ignition temperature on density with plastics foam type was smaller since the amount of combustible gas to ignite is not caused enough. The time to ignition of the polyethylene foam in samples of the plastics foam was shorter, and its of polyethylene foam was longer. The concentration of carbon dioxide of the polyethylene foam shows higher in samples of the plastics foam. It is found that the concentration values of carbon monoxide of the plastics foam show very fatality on people during exposure of 30 minutes in fire.

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자전 고온 반응 합성법을 이용한 NiTi계 형상기억 합금의 제조에 관한 연구 (Processing of NiTi Shape Memory Alloy by Self- propagating High-temperature Synthesis)

  • 윤종필
    • 한국분말재료학회지
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    • 제2권2호
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    • pp.158-164
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    • 1995
  • Synthesis of the NiTi shape memory alloy using the thermal explosion mode of the self-propagating high-temperature synthesis has been investigated. The significant fractions of intermetallics phases were found to form at the Ti/Ni powder interface during the heating to the ignition temperature and seemed to influence the relative fraction of phases in the final products. As the heating rate to the ignition temperature was increased, the combustion temperature and the fraction of NiTi in the final reaction products were increased. The synthesis reaction under 70 MPa compressive pressure yielded a reaction product with 98% theoretical density.

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제어자발화 가솔린기관의 성능 특성 (Performance Characteristics of a Controlled Auto-Ignition Gasoline Engine)

  • 김홍성
    • 한국기계가공학회지
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    • 제4권1호
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    • pp.56-62
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    • 2005
  • In this study, A controlled auto-ignition (CAI) single cylinder gasoline engine is considered, focusing on the extension of operating conditions. The fuel is injected indirectly into electrically heated inlet air flow. Investigated are the engine performance characteristics under the wide range of operating conditions such as 32 to 63 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, and 150 to $180^{\circ}C$ in the inlet-air temperature. A controlled auto-ignition gasoline engine which has the super ultra lean-burn with self-ignition of gasoline fuel can be achieved by heating inlet air.

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압축점화 가솔린기관의 성능 및 배기특성 (Performance and Emission Characteristics of Compression Ignition Gasoline Engine)

  • 김홍성;김문헌
    • 대한기계학회논문집B
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    • 제27권7호
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    • pp.1007-1014
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    • 2003
  • This work deals with a controlled auto-ignition (CAI) single cylinder gasoline engine, focusing on the extension of operating conditions. The fuel is injected indirectly into electrically heated inlet air flow. In order to keep a homogeneous air-fuel mixing, the fuel injector is water-cooled by a specially designed coolant passage. Investigated are the engine performance and emission characteristics under the wide range of operating conditions such as 32 to 63 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, and 150 to 18$0^{\circ}C$ in the inlet air temperature. The compression ignition gasoline engine can be achieved that the ultra lean-burn with self-ignition of gasoline fuel by heating inlet air. For example. the allowable lean limit of air-fuel ratio is extended until 63 at engine speed of 1000 rpm and inlet air temperature of 17$0^{\circ}C$. It can be achieved that the emission concentrations of carbon monoxide, hydrocarbons and nitrogen oxide had been significantly reduced by CAI combustion compared with conventional spark ignition engine.

흡입공기온도의 변화에 따른 제어자발화 가솔린기관의 성능 및 배기 특성 (Performance and Emission Characteristics of a Controlled Auto-Ignition Gasoline Engine according to Variation of the Inlet-Air Temperature)

  • 김홍성
    • 동력기계공학회지
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    • 제10권1호
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    • pp.19-24
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    • 2006
  • This work treats a controlled auto-ignition (CAI) single cylinder gasoline engine, focusing on the extension of operating conditions. The fuel was injected indirectly into electrically heated inlet air flow. In order to keep a homogeneous air-fuel mixing, the fuel injector was water-cooled by a specially designed coolant passage. The engine performance and emission characteristics were investigated under the wide range of operating conditions such as 40 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, 150 to $180^{\circ}C$ in the inlet-air temperature, and $60^{\circ}$ BTDC in the injection timing. The ultra lean-burn with self-ignition of gasoline fuel by heating inlet air was achieved in a controlled auto-ignition gasoline engine. It could be also achieved that the emission concentrations of carbon monoxide, hydrocarbons and nitrogen oxide significantly reduced by CAI combustion compared with conventional spark ignition engines.

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분사시기의 변화에 따른 제어자발화 가솔린기관의 성능 및 배기특성 (Performance and Emission Characteristics of a Controlled Auto-Ignition Gasoline Engine according to Variation of the Injection Timing)

  • 김홍성
    • 동력기계공학회지
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    • 제9권1호
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    • pp.14-22
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    • 2005
  • This work deals with a controlled auto-ignition (CAI) single cylinder gasoline engine, focusing on the extension of operating conditions. The fuel is injected indirectly into electrically heated inlet air flow. In order to keep a homogeneous air-fuel mixing, the fuel injector is water-cooled by a specially designed coolant passage. Investigated are the engine performance and emission characteristics under the wide range of operating conditions such as 40 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, $150\;to\;180^{\circ}C$ in the inlet-air temperature, and $80^{\circ}$ BTDC to $20^{\circ}$ ATDC in the injection timing. A controlled auto-ignition gasoline engine can be achieved that the ultra lean-burn with self-ignition of gasoline fuel by heating inlet air. It can be achieved that the emission concentrations of carbon monoxide, hydrocarbons and nitrogen oxide had been significantly reduced by CAI combustion compared with conventional spark ignition engine.

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단일액적의 증발 및 착화특성에 관한 연구 (A Study of Evaporation and Ignition Characteristics of Single Fuel Droplet)

  • 백병준
    • Journal of Advanced Marine Engineering and Technology
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    • 제22권4호
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    • pp.551-559
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    • 1998
  • Evaporation and ignition characteristics of fuel droplet have major influences on the efficiency and performance of engine. In the present study the experiment of evaporation and self-ignition of single fuel was performed under the various ambient conditions. An individually suspended droplet of n-heptane n-hexadecane ethyl-alcohol and light oil were employed as a liquid droplet. Evaporation and ignition characteristics were measured by using the video-camera and image processing technique under the various ambient temperatures (up to 1000310 OC)and partial pressure of oxigen(up to 60%) The evaporation curve shows that the droplet life time ignition delay time decreases as the ambient temperature and partial pressure of oxigen increase, The temperature variations of droplet were also reported for various fuel and ambient temperatures. The numerical simulations were carried out to predict droplet diameter and temperature with favorable agreement.

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추진장약 K676 및 K677의 저장온도가 저장수명에 미치는 영향 (A Study on the Effect of Storing Temperature upon the Self Life of Propelling Charge K676 and K677)

  • 조기흥;장일호
    • 한국군사과학기술학회지
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    • 제8권1호
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    • pp.14-24
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    • 2005
  • A propellant mainly consisting of nitric ester including nitrocellulose, nitroglycerine and nitroguanidine is characteristic of being decomposed naturally. And this phenomenon is known as being affected mostly by its storing temperature. In this research, the effect of storing temperature on self life has been studied by measuring the contained quantity of residual stabilizer of propellant KM30A1, ignition powder and combustible cartridge case, which are parts of 155MM propelling charge K676 and K677; the method for the measurement is acceleration aging test, and decomposition reaction equation and Berthlot Equation were used for the calculation. The result of this research shows that propellant KM30A1, ignition powder, combustible cartridge case in order of decreasing self life, and the self life decreases to 1/3 as the temperature increases by $10^{\circ}C$.