• 제목/요약/키워드: self diffusions

검색결과 15건 처리시간 0.022초

Poly(acrylonitrile)-poly(vinyl chloride) 공중합체의 자체 확산 계수와 유동 자유 홀부피 (Self Diffusion Coefficients and Free Hole Volumes of Poly(acrylonitrile)-poly(vinyl chloride) Copolymers)

  • 김남정
    • Elastomers and Composites
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    • 제46권3호
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    • pp.245-250
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    • 2011
  • Poly(acrylonitrile)-poly(vinyl chloride) 공중합체 섬유의 비결정성 영역에서의 자체 확산 계수와 홀 부피를 응력완화 실험으로 규명하였다. 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하였다. 이론적인 응력완화식 에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 유동 파라메타로부터 섬유고분자 물질의 홀부피, 자체확산, 점성, 열역학파라메타 등을 계산하였다. 이들 시료의 유동 파라메타는 유동 단위의 홀 부피, 자체확 산, 유동 활성화 에너지와 직접적인 연관을 갖는 것으로 규명되었다.

UNIQUENESS OF POSITIVE STEADY STATES FOR WEAK COMPETITION MODELS WITH SELF-CROSS DIFFUSIONS

  • Ko, Won-Lyul;Ahn, In-Kyung
    • 대한수학회보
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    • 제41권2호
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    • pp.371-385
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    • 2004
  • In this paper, we investigate the uniqueness of positive solutions to weak competition models with self-cross diffusion rates under homogeneous Dirichlet boundary conditions. The methods employed are upper-lower solution technique and the variational characterization of eigenvalues.

[ W12 ]-ESTIMATES ON THE PREY-PREDATOR SYSTEMS WITH CROSS-DIFFUSIONS AND FUNCTIONAL RESPONSES

  • Shim, Seong-A
    • 대한수학회논문집
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    • 제23권2호
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    • pp.211-227
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    • 2008
  • As a mathematical model proposed to understand the behaviors of interacting species, cross-diffusion systems with functional responses of prey-predator type are considered. In order to obtain $W^{1_2}$-estimates of the solutions, we make use of several forms of calculus inequalities and embedding theorems. We consider the quasilinear parabolic systems with the cross-diffusion terms, and without the self-diffusion terms because of the simplicity of computations. As the main result we derive the uniform $W^{1_2}$-bound of the solutions and obtain the global existence in time.

REM 모델에 의한 Poly(methyl acrylate)-Poly(acrylonitrile) 공중합체 완화스펙트럼의 pH 영향 (pH Effect on Relaxation Spectra of Poly(methyl acrylate)-Poly(acrylonitrile) Copolymers by REM Model)

  • 김남정
    • 폴리머
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    • 제37권2호
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    • pp.135-140
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    • 2013
  • Poly(methyl acrylate)-poly(acrylonitrile) 공중합체의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기 중, 증류수, pH 3, 7, 11 용액에서 실행하였다. Ree-Eyring and Maxwell 모델로부터 얻은 완화스펙트럼 식에 실험적인 응력완화 곡선을 대입하여 poly(methyl acrylate)-poly(acrylonitrile) 공중합체의 완화스펙트럼을 얻었다. 완화스펙트럼의 계산은 Laplace 변환법을 사용한 컴퓨터 프로그램을 이용하였다. 이들 시료의 완화스펙트럼은 유동단위의 분자량과 자체확산 분포와 밀접한 관계가 있음을 알 수 있었다.

Self-Diffusion of THO within Tactic Poly(2-hydroxyethyl methacrylate) Membranes

  • Kim, Hye-Kyeong;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • 제4권3호
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    • pp.128-132
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    • 1983
  • The self-diffusion experiment of water was performed across two series of tactic poly(2-hydroxyethyl methacrylate), P(HEMA) membranes prepared by crosslinking with various amount of hexamethylene diisocyanate (HMDIC). The tagging material was tritium hydroxide (THO) and the efflux of THO was counted on a Liquid Scintillation Counter. The transport data of THO show that the permeability decreases as the amount of HMDIC increased from 2.5 to 10 mole % and the self-diffusions coefficient shows a parallel trend with it. The diffusivity data was discussed in terms of the change of water structural orderliness within membranes. Using the relation between viscosities and diffusivities derived from Eyring's absolute rate theory, the corresponding viscosities of water within two series of tactic P(HEMA) membranes were obtained. From this, it is seen that the viscosity of water within tactic P(HEMA) membranes may have the same values with those of supercooling water whose temperature ranges from -28 to -$36^{\circ}C.$.

Eyring-Halsey 모델의 유동파라메타로부터 열역학 성질과 자체 확산 (Thermodynamic Properties and Self Diffusions from Rheological Parameters of Eyring-Halsey Model)

  • 김남정
    • 대한화학회지
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    • 제58권3호
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    • pp.251-257
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    • 2014
  • Poly(methyl acrylate)-poly(acrylonitrile) 공중합체의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기 중, 증류수 용액에서 실행하였다. Eyring-Halsey 모델의 이론적인 응력완화식에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 비결정성 영역에서의 유동단위의 고찰을 위하여 유동 파라메타와 결정크기로부터 섬유고분자 물질의 자체확산, 홀 부피, 점성, 열역학파라메타 등을 계산하였다. 이들 시료의 유동 파라메타는 유동 단위의 홀부피, 자체확산, 유동 열역학 파라메타와 직접적인 연관을 갖는 것으로 규명되었다.

용매 환경에서의 폴리아미드 고분자 재료의 자체확산과 유변학적인 특성 (Self Diffusions and Rheological Properties of Polyamide Polymer Materials in Various Solvents)

  • 김남정
    • 한국응용과학기술학회지
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    • 제36권4호
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    • pp.1050-1059
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    • 2019
  • 비결정성 영역에서의 유동단위의 고찰을 위하여 유동 파라메타와 결정크기로부터 폴리아미드 섬유고분자 물질의 자체확산, 홀 부피, 유동 열역학 파라메타 등을 계산하였다. 폴리아미드 섬유의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기, 증류수, 산, 염기 용액에서 실행하였다. REM 모델의 이론적인 응력완화 식에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 이들 시료의 유동 파라메타는 완화 스펙트럼, 자체확산, 점도 및 유동 활성화 에너지와 직접적인 연관을 갖는 것으로 규명되었다.

Motivations and Characteristics of Hashtag Users

  • Kim, Gwon-Il;Jung, Ga Yeon;Song, Ye Ji;Park, Jee-Sun
    • 패션비즈니스
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    • 제19권6호
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    • pp.112-126
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    • 2015
  • In social environments, hashtags have been widely adopted and have become a new form of language for users. The current study attempts to enhance our understanding of users and their motivations to use hashtags when posting fashion-related information. Specifically, this study examines whether user characteristics (fashion leadership, conspicuousness) influence their motivations to use hashtags (curation, self-presentation, information diffusion), which then leads to behavioral intentions to continue to use hashtags and recommend the same to others. An online survey was administered to test our research questions. A total of 136 consumers in their 20s, 30s, and 40s living in Korea were used for data analysis. Structural equation modeling was conducted, which revealed that fashion leadership and conspicuousness had a positive impact on users' motivations of curation, self-presentation, and information diffusion. Motivations of self-presentation and information diffusions were found to affect users' behavioral intentions while curation had no significant impact. Practical implications are presented.

MR 영상에서 확산현상에 의한 경계강조 (Edge Enhancement due to Diffusion Effect in Magnetic Resonance Imaging)

  • 홍인기;노용만;조장희
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1995년도 추계학술대회
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    • pp.124-127
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    • 1995
  • Due to the self-diffusion of nuclear spins, the edge of phantoms is enhanced in the magnetic resonance imaging (MRI), especially in the case of microscopy [1]. According to several published works, theory has been established that the edge enhancement is caused by the motion narrowing around bounded regions due to diffusions of nuclear spins during data acquisition. It is found, however, that the signal decreases due to the diffusion attenuation and image is distorted as edge of the image is sharpened. In this paper, we wilt investigate this signal loss during data acquisition and its effects on image, i.e., image edge enhancement due to the diffusion phenomenon. This result is new and different from the previously discussed edge enhancement due to the diffusion, namely, by motion narrowing effect or spin bouncing effect at the boundary.

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