• 제목/요약/키워드: self -assembly

검색결과 690건 처리시간 0.025초

Synthesis of Monodisperse Spherical SiO2 and Self-Assembly for Photonic Crystals

  • Lee, Byung-Kee;Jung, Young-Hwa;Kim, Do-Kyung
    • 한국세라믹학회지
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    • 제46권5호
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    • pp.472-477
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    • 2009
  • Monodisperse spherical $SiO_2$ particles of various sizes ($\sim$350 nm and $\sim$800 nm) and size distributions were synthesized from TEOS and MTMS. The particle size and size distribution were controlled by changing the volume ratio of water to ethanol and the reaction temperature. Narrow-sized $SiO_2$ particles with $\sim$3% size distribution were obtained. Self-assembly of the $SiO_2$ particles for photonic crystals were performed by the solvent evaporation method. The number of ordered $SiO_2$ layers can be controlled by changing the amount of the dispersed $SiO_2$ volume fraction in the solvent.

자기력과 self-assembly에 의한 3차원 바이오칩의 개발 (Development of 3-Dimensional Biochip Using Magnetic Interaction and Self-Assembly)

  • 최용성;박대희;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 C
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    • pp.1909-1911
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    • 2003
  • This research describes a new constructing method of multifunctional biosensor using many kinds of biomaterials. A metal particle and an array was fabricated by photolithographic. Biomaterials were immobilized on the metal particle. The array and the particles were mixed in a buffer solution, and were arranged by magnetic force interaction and self-assembly. A quarter of total Ni dots were covered by the particles. The binding direction of the particles was controllable, and condition of particles was almost with Au surface on top. The particles were successfully arranged on the array. The biomaterial activities were detected by chemiluminescence and electrochemical methods.

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자기력에 의한 바이오칩의 개발 (Development of Biochip by Magnetic Force Interaction)

  • 최용성;박대희;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.196-199
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    • 2003
  • In this paper, we have been described a new constructing method of multichannel biosensor using self-assembly by magnetic force interaction. A metal particle and an array was fabricated by photolithographic. Biomaterials were immobilized on the metal particle. The array and the particles were mixed in a buffer solution, and were arranged by magnetic force interaction and self-assembly. A quarter of total Ni dots were covered by the particles. The binding direction of the particles was controllable, and condition of particles was almost with Au surface on top. The particles were successfully arranged on the array. The biomaterial activities were detected by chemiluminescence.

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Self-Assembly Modification of Perfluorosulfonic Acid Membranes for the Application to Direct Methanol Fuel Cells

  • Moon, Go-Young;Rhim, Ji-Won
    • Macromolecular Research
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    • 제16권6호
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    • pp.524-531
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    • 2008
  • The mitigation or elimination of methanol crossover for perfluorosulfonic acid fuel cell membranes has been investigated extensively for direct methanol fuel cell applications with the aim of increasing the electrochemical performance and enhancing the utilization rate of methanol. Self-assembly modifications by applying an oppositely charged polyelectrolyte to Nafion membranes were attempted in order to block or reduce methanol crossover while maintaining the other advantageous properties of Nafion membranes. It was reported that anionic polyallylamine hydrochloride (PAH) was the most efficient polyelectrolyte in reducing methanol crossover, and considerable cell performance was obtained even at a methanol feed concentration of 10 M.

Self-Reported Variables as Determinants of Upper Limb Musculoskeletal Symptoms in Assembly Line Workers

  • Guerreiro, Marisa M.;Serranheira, Florentino;Cruz, Eduardo B.;Sousa-Uva, Antonio
    • Safety and Health at Work
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    • 제11권4호
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    • pp.491-499
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    • 2020
  • Background: Assembly lines work is frequently associated to work-related upper limb musculoskeletal disorders. The related disability and absenteeism make it important to implement efficient health surveillance systems. The main objective of this study was to identify self-reported variables that can determine work-related upper limb musculoskeletal symptoms-discomfort/pain-during a 6-month follow-up. Methods: This was a prospective study with a 6-month follow-up period, performed in an assembly line. Upper limb musculoskeletal discomfort/pain was assessed through the presence of self-reported symptoms. Uni- and multivariate logistic regression analyses were used to evaluate which self-reported variables were associated to upper limb symptoms after 6 months at the present and to upper limbs symptoms in the past month. Results: Of the 200 workers at baseline, 145 replied to the survey after 6 months. For both outcomes, "having upper limb symptoms during the previous 6 months" and "education" were possible predictors. Conclusion: Our results suggest that having previous upper limb symptoms was related to its maintenance after 6 months, sustaining it as a specific determinant. It can be a hypothesis that this population had mainly workers with chronic symptoms, although our results give only limited support to self-reported indicators as determinants for upper limb symptoms. Nevertheless, the development of an efficient health surveillance system for high demanding jobs should implicate self-reported indicators, but also clinical and work conditions assessment should be accounted on the future.

Invertible Nanofibers with Tunable Stiffness from Self-Assembly of an Amphiphilic Wedge-Coil Molecule

  • Kim, Jung-Keun;Lee, Eun-Ji;Lee, Myong-Soo
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.249-249
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    • 2006
  • We have prepared an amphiphilic wedge-coil molecule consisting of a hydrophobic wedge-like segment and a hydrophilic poly(ethylene oxide) (PEO) segment. The wedge-coil block molecule self-assembles into cylindrical nanofibers in both polar as well as nonpolar solvents. Remarkably, the resulting nanofibers, as solvent polarity change from water to n-hexane, change from highly flexible coil-like to stiff rod-like characteristics. This dynamic switching in the stiffness of the nanofibers in response to solvent polarity is attributed to the structural inversion of cylindrical core from bulky dendritic segments with amorphous nature to crystallizable linear PEO segments.

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니트로기를 가진 자기조립된 유기 초박막의 부성미분저항 특성에 관한 연구 (A Study on the Negative Differential Resistance Properties of Self-Assembly Organic Thin Film with Nitro Group)

  • 김승언;손정호;김병상;신훈규;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.811-813
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    • 2003
  • We investigated the electrical properties of self-assembled (4,4'-Di(ethynylphenyl)-2'-nitro-1-thioacetylbenzene), which has been well known as a conducting molecule having possible application to molecular level negative differential resistance(NDR)[1]. Generally, the phenomenon of NDR can be characterized by the decreasing current with the increasing voltage[2]. To deposit the SAM layer onto gold electrode, we transfer the prefabricated nanopores into a 1mM self-assembly molecules in THF solution. Au(111) substrates were prepared by ion beam sputtering method of gold onto the silicon wafer. As a result, we measured the voltage-current properties and confirmed the negative differential resistance properties of self-assembled organic thin film and measured, using Scanning Tunneling Microscopy(STM).

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Capillarity-Driven Self-Assembly of Silver Nanowires-Coated Fibers for Flexible and Stretchable Conductor

  • Li, Yi;Chen, Jun;Han, Xiao;Li, Yinghui;Zhang, Ziqiang;Ma, Yanwen
    • Nano
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    • 제13권12호
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    • pp.1850146.1-1850146.9
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    • 2018
  • The rapid development of smart textiles requires the large-scale fabrication of conductive fibers. In this study, we develop a simple, scalable and low-cost capillary-driven self-assembly method to prepare conductive fibers with uniform morphology, high conductivity and good mechanical strength. Fiber-shaped flexible and stretchable conductors are obtained by coating highly conductive and flexible silver nanowires (Ag NWs) on the surfaces of yarn and PDMS fibers through evaporation-induced flow and capillary-driven self-assembly, which is proven by the in situ optical microscopic observation. The density of Ag NWs and linear resistance of the conductive fibers could be regulated by tuning the assembly cycles. A linear resistance of $1.4{\Omega}/cm$ could be achieved for the Ag NWs-coated nylon, which increases only 8% after 200 bending cycle, demonstrating high flexibility and mechanical stability. The flexible and stretchable conductive fibers have great potential for the application in wearable devices.

Mechanism of amyloidogenesis: nucleation-dependent fibrillation versus double-concerted fibrillation

  • Bhak, Ghi-Bom;Choe, Young-Jun;Paik, Seung-R.
    • BMB Reports
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    • 제42권9호
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    • pp.541-551
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    • 2009
  • Amyloidogenesis defines a condition in which a soluble and innocuous protein turns to insoluble protein aggregates known as amyloid fibrils. This protein suprastructure derived via chemically specific molecular self-assembly process has been commonly observed in various neurodegenerative disorders such as Alzheimer's, Parkinson's, and Prion diseases. Although the major culprit for the cellular degeneration in the diseases remains unsettled, amyloidogenesis is considered to be etiologically involved. Recent recognition of fibrillar polymorphism observed mostly from in vitro amyloidogeneses may indicate that multiple mechanisms for the amyloid fibril formation would be operated. Nucleation-dependent fibrillation is the prevalent model for assessing the self-assembly process. Following thermodynamically unfavorable seed formation, monomeric polypeptides bind to the seeds by exerting structural adjustments to the template, which leads to accelerated amyloid fibril formation. In this review, we propose another in vitro model of amyloidogenesis named double-concerted fibrillation. Here, two consecutive assembly processes of monomers and subsequent oligomeric species are responsible for the amyloid fibril formation of $\alpha$-synuclein, a pathological component of Parkinson's disease, following structural rearrangement within the oligomers which then act as a growing unit for the fibrillation.

유체 자가-조립을 위한 버블 항력 연구 (Drag Force on Bubbles for Fluidic Self-Assembly)

  • 임현승;이성호
    • 대한기계학회논문집B
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    • 제36권1호
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    • pp.47-54
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    • 2012
  • 본 연구는 전통적인 픽-엔-플레이스 방법을 대체하기 위한 새로운 유체 자가-조립 방법을 개발하였다. 이 방법은 종래의 연구보다 경제적이고 효과적인 방법이다. 이를 위해, 중요한 변수인 항력, 모세관 힘, 복원력을 선정하여 이들이 칩과 기판의 부착 및 정렬에 미치는 영향을 알아보기 위해 이론값과 실험값을 비교하였다. 유체 자가-조립 실험에서는 $500{\mu}m$ 솔드 볼에서 96.5% 부착률과 미정렬 $5^{\circ}$ 인 우수한 결과를 도출하였다.