• 제목/요약/키워드: self -assembly

검색결과 690건 처리시간 0.025초

수정진동자를 이용한 Viologen Self-Assembly 단분자막의 전기화학적 특성 (The electrochemical study on Viologen SA monolayer using QCM)

  • 김정명;윤희찬;송성훈;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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    • pp.21-23
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    • 2002
  • In this paper, the electrochemical behavior of Viologen self assembly monolayer has been investigated with QCM, which has been known as nano-gram order mass detector. The self assemvly process of Viologen was monitored using resonant frequency $({\Delta}F)$ and resonant resistance(R). QCM measurements indicated a mass adsorption for Viologen assembling on the gold sufrace with a frequency change about 135[Hz] and calculated its surface coverage($\Gamma$) to be $3.5273{\times}10^{-9}[mol/cm^{2}]$. Also reversible redox process was observed and analyzed with ionic interaction at the Viologen/solution interface using ${\Delta}F$.

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Unprecedented Molecular Architectures by the Controlled Self-Assembly of ${\beta}$-Peptide Foldamer

  • Kwon, Sun-Bum;Lee, Hee-Seung
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.204-204
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    • 2011
  • During past decades, several types of peptide-based scaffolds, ranging from simple aromatic dipeptide to small protein fragments, have been studied to understand the underlying mechanism and mimic to create artificial nano/microstructures. However, a limited number of design principles have still been reported in peptidic scaffolds allowing well-defined self-assembled structure formation, presumably due to the intrinsic large conformational flexibility of natural peptides. In this presentation, we report the first example of highly homogeneous, well-defined and finite architectures by the ${\beta}$-peptide self-assembly.

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휴대폰용 카메라 모듈의 조립에 대한 연구 (A Research on the Assembly of the Camera Modules for Mobile Phones)

  • 최재성;이경수;임동현;송준엽;이창우;곽윤근;김수현
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.989-992
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    • 2005
  • This paper is about the assembly of camera modules for mobile phones. We have particularly researched the assembly process proper for mega-pixel lens assemblies in the camera modules. Herein, we propose that self-adjustment function makes it possible to assemble these lens assemblies without fraction of components. In advance, we observed the assembly process of the lens assemblies to verify the possibility, and checked out it through experiments based on some assumptions.

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Self-Assembly and Photopolymerization of Diacetylene Molecules on Surface of Magnetite Nanoparticles

  • Vinod, T.P.;Chang, Ji-Hoon;Kim, Jin-Kwon;Rhee, Seog-Woo
    • Bulletin of the Korean Chemical Society
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    • 제29권4호
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    • pp.799-804
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    • 2008
  • An amphiphilic diacetylene compound was deposited on the surface of nano sized magnetite particles ($Fe_3O_4$) using a self-assembly method. The diacetylene molecular assembly formed on the surface of nanoparticle was subjected to photopolymerization. This resulted in the formation of a polymeric assembly on the surface of the nanoparticles in which the adjacent diacetylene molecules were connected through conjugated covalent networks. The presence of immobilized polymer species on the surface of nanoparticles is expected to protect them from agglomeration and ripening, thereby stabilizing their physical properties. In this work, $Fe_3O_4$ nanoparticles were prepared by chemical coprecipitation method and the diacetylene molecule 10,12- pentacosadiynoic acid (PCDA) was anchored to the surface of $Fe_3O_4$ nanoparticles through its carboxylate head group. Irradiation of UV light on the nanoparticles containing immobilized diacetylenes resulted in the formation of a polymeric assembly. Presence of diacetylene molecules on the surface of nanoparticles was confirmed by X-ray photoelectron spectroscopy and FT-IR measurements. Photopolymerization of the diacetylene assembly was detected by UV-Visible spectroscopy. Magnetic properties of the nanoparticles coated with polymeric assembly were investigated with SQUID and magnetic hysteresis showed superparamagnetic behaviors. The results put forward a simple and effective method for achieving polymer coating on the surface of magnetic nanoparticle.