• 제목/요약/키워드: self -assembly

검색결과 690건 처리시간 0.029초

Practical resolution of angle dependency of multigroup resonance cross sections using parametrized spectral superhomogenization factors

  • Park, Hansol;Joo, Han Gyu
    • Nuclear Engineering and Technology
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    • 제49권6호
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    • pp.1287-1300
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    • 2017
  • Based on the observation that ignoring the angle dependency of multigroup resonance cross sections within a fuel pellet would result in nontrivial underestimation of the spatial self-shielding of flux, a parametrized spectral superhomogenization (SPH) factor library (PSSL) method is developed as a practical means of resolving the problem. Region-wise spectral SPH factors are calculated by the normal and transport corrected SPH iterations after ultrafine group slowing down calculations over various light water reactor pin-cell configurations. The parametrization is done with fuel temperature, U-238 number density, fuel radius, moderator source represented by ${\Sigma}_{mod}V_{mod}$, and the number density ratio of resonance nuclides to that of U-238 in a form of resonance interference correction factors. The parametrization is successful in that the root mean square errors of the interpolated SPH factors over the fuel regions of various pin-cells are within 0.1%. The improvement in reactivity error of the PSSL method is shown to be superior to that by the original SPH method in that the reactivity bias of -200 pcm to -300 pcm vanishes almost completely. It is demonstrated that the environment effect takes only about 4% in the reactivity improvement so that the pin-cell based PSSL method is effective in the assembly problems.

Effects of Ionic Strength in the Medium on Sample Preconcentration Utilizing Nano-interstices between Self-Assembled Monolayers of Gold Nanoparticles

  • Nguyen, Ngoc-Viet;Wu, Jian-Sheng;Jen, Chun-Ping
    • BioChip Journal
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    • 제12권4호
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    • pp.317-325
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    • 2018
  • This paper investigated the effects of ionic strength in the medium on a preconcentrator for a protein sample with low concentration. The preconcentration chip was designed and fabricated using a polydimethylsiloxane replica through standard lithophotography. A glass substrate is silanized prior to functionalizing the nanoparticles for self-assembly at a designed region. Due to the overlap of electrical double layers in a nanofluidic channel, a concentration polarization effect can be achieved using an electric field. A nonlinear electrokinetic flow is induced, resulting in the fast accumulation of proteins in front of the induced ionic depletion zone, so called exclusion-enrichment effect. Thus, the protein sample can be driven by electroosmotic flow and accumulated at a specific location. The chip is used to collect fluorescein isothiocyanate-labeled bovine serum albumin (FITC-BSA) diluted in phosphate-buffered saline (PBS) buffer solution. Different concentrations of the buffer media were studied herein. Fluorescence intensity images show that the buffer concentration of 4 mM is more appropriate than all the other ones. The sample of FITC-BSA with an initial concentration of $10{\mu}M$ in the 4 mM PBS solution increases its concentration at the desired region by up to 50 times within 30 min, demonstrating the results in this investigation.

금속 할라이드 페로브스카이트 나노와이어의 광 센서 소자 응용 (Alignment of Metal Halide Perovskite Nanowires and Their Application in Photodetectors)

  • 신문렬;최지훈
    • 한국재료학회지
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    • 제32권6호
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    • pp.307-312
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    • 2022
  • Metal halide perovskite (MHP) nanocrystals (NCs) have emerged as promising materials for various optoelectronic applications including photovoltaics, light-emitting devices, and photodetectors because of their high absorption coefficient, high diffusion length, and photoluminescence quantum yield. However, understanding the morphological evolution of the MHP NCs as well as their controlled assembly into optoelectronic devices is still challenging and will require further investigation of the colloidal chemistry. In this study, we found that the amount of n-octylamine (the capping agent) plays a crucial role in inducing further growth of the MHP NCs into one-dimensional nanowires during the aging process. In addition, we demonstrate that the dielectrophoresis process can permit self-alignment of the MHP nanowires with uniform distribution and orientation on interdigitated electrodes. A strong light-matter interaction in the MHP NWs array was observed under UV illumination, indicating the photo-induced activation of their luminescence and electrical current in the self-aligned MHP nanowire arrays.

Determination of slip modulus of cold-formed steel composite members sheathed with plywood structural panels

  • Karki, Dheeraj;Far, Harry;Al-hunity, Suleiman
    • Steel and Composite Structures
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    • 제43권4호
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    • pp.511-522
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    • 2022
  • An experimental investigation to study the behaviour of connections between cold-formed steel (CFS) joist and plywood structural panel is presented in this paper. Material testing on CFS and plywood was carried out to assess their mechanical properties and behaviour. Push-out tests were conducted to determine the slip modulus and failure modes of three different shear connection types. The employed shear connectors in the study were; size 14 (6mm diameter) self-drilling screw, M12 coach screw, and M12 nut and bolt. The effective bending stiffness of composite cold-formed steel and plywood T-beam assembly is calculated based on the slip modulus values computed from push-out tests. The effective bending stiffness was increased by 25.5%, 18% and 30.2% for self-drilling screw, coach screw, nut and bolt, respectively, over the stiffness of cold-formed steel joist alone. This finding suggests the potential to enhance the structural performance of composite cold-formed steel and timber flooring system by mobilisation of composite action present between timber sheathing and CFS joist.

Job Training and Safety Education for Modular Construction using Virtual Reality

  • Choi, Hyeongho;Chae, Jeonghyeun;Kang, Youngcheol
    • 한국건설관리학회논문집
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    • 제24권5호
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    • pp.63-72
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    • 2023
  • This study investigates the virtual reality (VR) simulation to train construction workers for modular construction. Recently, the construction industry has been experiencing a growing demand for modular construction due to a shortage of labors and an increasing social need for safety. While the demand for modular construction has been increasing, construction labors suffer a basic knowledge regarding modular construction. The users of the simulation, developed by Unity program and Oculus Quest 2, experience the removal of hazardous elements at the location whether the modular unit suspended by a crane is lowered, the lowering and assembly of units through crane operation, and the fall from the roof which is the most frequent accidents in modular construction. The simulation was tested by 15 subjects. The effectiveness of the education was measured through a survey on self-efficacy, perceived usefulness, usability, and presence. It was found that the VR training is suitable for educating on the modular construction activities and safety issues related to them. This study also found that perceived usefulness is the factor that has the greatest impact on self-efficacy. This study can contribute to resolving the labor education issues for the deployment of modular construction.

The C-terminal Region of Human Tau Protein with Ability of Filament Formation

  • Chung, Sang-Ho
    • Animal cells and systems
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    • 제1권2호
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    • pp.317-321
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    • 1997
  • Tau protein is one of the microtubule-associated proteins in the mammalian brain. In Alzheimer's disease, tau protein is immobilized in the somatodendritic compartment of certain nerve cells, where it forms a part of the paired helical filament (PHF). To understand the role of tau protein in the formation of PHF, a recombinant human tau protein expressed in Escherichia coli and five synthetic peptide fragments (peptide 1 to peptide 5), corresponding to the C-terminal region of tau protein, were prepared and their ability in self-assembly to form filamentous structures was examined. The recombinant human tau protein formed short rod-like structures in 0.1M MES buffer containing 1 mM $MgCI_2$, while a synthetic peptide fragment 1 containing 55 amino acid residues could assemble into a lot of long filamentous structures in water and particularly twisted helical structures in 0.1M MES buffer containing 1 mM $MgCI_2$. This suggests that the C-terminal region possesses a filament-forming ability and may be related to the formation of the helical structure by providing a powerful filament-forming driving force.

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Isolation and Structural Determination of a Complete Set of Intact Bacteriochlorophyll-d Homologs and Isomers from Green Sulfur Bacterium Chlorobium vibrioforme and Their Aggregation Properties in Hydrophobic Solvents

  • Mizoguchi, Tadashi;Saga, Yoshitaka;Tamiaki, Hitoshi
    • Journal of Photoscience
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    • 제9권2호
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    • pp.344-346
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    • 2002
  • Eight intact bacteriochlorophyll (BChl)-d homologs and isomers were isolated from a strain of green sulfur bacterium Chlorobium vibrioforme. All the molecular structures of the BChl-d components were fully determined by a combination of mass spectrometry and $^1$H-NMR spectroscopy. The aggregation behavior of the isomerically pure BChls-d in hydrophobic organic solvents was examined with respect to the stereoisomeric configuration at the C3$^1$ position as well as the bulkiness of the C8 and C12 side-chains by using electronic- absorption spectroscopy.

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Supramolecular Micelle from Amphiphilic Mn(III)-porphyrin Derivatives as a Potential MRI Contrast Agent

  • Choi, Kwang-Mo;Lee, Do-Hyung;Jang, Woo-Dong
    • Bulletin of the Korean Chemical Society
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    • 제31권3호
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    • pp.639-644
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    • 2010
  • Amphiphilic porphyrin derivatives have been synthesized and characterized by $^1H$ NMR and MALDI-TOF-MS. All porphyrin derivatives showed very high solubility to aqueous medium as well as hydrophobic organic solvent. The UV-vis absorption of the porphyrin derivatives showed significant broadness and decrease of maximum intensity of absorption in aqueous solution. SEM experiment showed the formation of spherical micellar structure. The $T_1$ relaxation time of aqueous medium was drastically decreased in the presence of Mn(III)-porphyrin derivative, indicating that the supramolecular micelle has strong possibility to use as a $T_1$ contrast agent.

High-Performance Single-Crystal Organic Nanowire Field-Effect Transistors of Indolocarbazole Derivatives

  • 박경선;정진원;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.368-368
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    • 2012
  • We report solution-processed, high-performance single-crystal organic nanowire transistors fabricated from a novel indolocarbazole (IC) derivative. The direct printing process was utilized to generate single-crystal organic nanowire arrays enabling the simultaneous synthesis, alignment and patterning of nanowires using molecular ink solutions. Using this method, single-crystal organic nanowires can easily be synthesized by self-assembly and crystallization of organic molecules within the nanoscale channels of molds, and these nanowires can then be directly transferred to specific positions on substrates to generate nanowire arrays by a direct printing process. These new molecules are particularly suitable for p-channel organic field-effect transistors (OFETs) because of the high level of crystallinity usually found in IC derivatives. Selected area diffraction (SAED) and X-ray diffraction (XRD) experiments on these solution-processed nanowires showed high crystallinity. Transistors fabricated with these nanowires gave a hole mobility as high as 1.0 cm2V-1s-1 with nanowire arrays with the direct printing process.

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PDMS기판에 이온빔 처리에 따른 수평 액정의 배향 연구

  • 김영환;오병윤;김병용;이원규;임지훈;나현재;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.159-159
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    • 2009
  • We characterize a flexible self-assembled liquid crystal display (LCD) fabricated from a polyimide (PI) alignment layer with polydimethylsiloxane pixel walls. Ion beam (IB) irradiation aligned LC molecules in the PI layer and bonded two flexible plastic substrates in a one-step assembly of the pixel walls. X-ray photoelectron spectroscopic analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy provided chemical and physical evidence for the formation of stable chemical bonds between the PI layer and the PDMS pixel walls in addition to the important maintenance of a uniform 6 um gap between the two substrates without the use of any epoxy resins or other polymers.

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