• Title/Summary/Keyword: self -assembly

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Fabrication of Organic Thin Film by Using Self-Assembly and Negative Difference Resistance Research (자기조립법을 이용한 유기박막의 소자 제작과 부성저항특성 연구)

  • Son, Jung-Ho;Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1572-1574
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    • 2002
  • In this paper, we discuss the electrical properties of self-assembled (2'-amino-4,4-di(ethynylp henyl)-5'-nitro-1-(thioacetyl)benzene), which has been well known as a conducting molecule having possible application to molecular level NDR device. The phenomenon of negative differential resi(NDR) is characterized by decreasing current th a junction at increasing voltage, also fabricatio MIM-type molecular electronic device and the Molecular Level Using Scanning Tunneling Microscopy.

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Dynamic Flow Lithography Technologies (역학적 유체 리소그래피 기술)

  • Chung, Su-Eun;Park, Wook;Kwon, Sung-Hoon
    • Journal of Biomedical Engineering Research
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    • v.30 no.6
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    • pp.453-460
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    • 2009
  • In this review paper, concepts in optofluidics are applied to an advanced manufacturing technology based on self-assembled microparts. The "optical" aspect of optofluidics will be described in the context of photolithography, and the "fluidic" aspect will be discussed in the context of self-assembly. First, optofluidic maskless lithography will be introduced as a dynamic fabrication method to generate microparticles in microfluidic channels. Next, the history and application of optofluidic lithography will be presented.

Surface-Enhanced Raman Spectroscopic Studies of Oriented Monolayers on Electrode Surfaces

  • Yoon, Wan-Shik;Im, Jung-Hyuk;Kim, Jae-Ho
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.699-705
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    • 1995
  • Monolayers of hypericin, a photodynamic polycyclic quinoidal compound, were prepared at the air-water interface, and were transferred to metal substrates to form Langmuir-Blodgett (LB) monolayers. The structural characteristics of hypericin LB monolayers and self-assembled (SA) monolayers were investigated using surface-enhanced resonance Raman scattering (SERRS) spectroscopy. Both the spectroscopic data and the surface pressure - area (${\pi}-A$) isotherms suggest that hypericin forms ${\pi}-{\pi}$ aggregates that orient vertically to the subphase surface. Whereas the ordering and orientation of control was less effective in SA monolayers, a higher structural regularity was attained in LB systems. The effect of subphase on the structural integrity of the monolayer was also investigated.

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2D Nanodot and Nanowires Arrays of Titania and Silica with Tunable Morphologies via Self-Assembled Block Copolymers and Sol-gel Chemistry (자기조립 이중블록공중합체와 졸-겔 공정을 이용한 이산화티타늄과 이산화규소 2차원 나노점 및 나노선 배열의 모폴로지 제어)

Study on Charge Transfer Characteristics of Self-Assembled Viologen Monolayers

  • Park Sang-Hyun;Lee Dong-Yun;Kwon Young-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.4
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    • pp.161-164
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    • 2005
  • Viologen has been extensively investigated in the paper because their well-behaved electrochemistry has led to their use in a variety of theses, including the electron acceptor for the electric charge delivery mediation of the devices. It was formed monolayer in QCM by self-assembly method. We could know the adsorbed mass of viologen molecules from the frequency shift. We calculated that the adsorbed mass was about 196 [$ng/cm^2$]. We studied the electron transfer property of viologen by the cyclic voltammetry among the electrochemical process so we changed an anion like 0.1 M $NaClO_4$ and $Na_3PO_4$ electrolyte solution and investigated the interrelationship between scan rate and peak current when scan rates were increased twice.

Fabrication of Microcantilever-based Biosensor Using the Surface Micromachining Technique (표면 미세 가공기술을 이용한 마이크로 캔틸레버의 제작과 바이오센서로의 응용)

  • Yoo Kyung-Ah;Joung Seung-Ryong;Kang C. J.;Kim Yong-Sang
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.1
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    • pp.11-15
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    • 2006
  • We propose an optical and an electrical detection methods for detecting various bio-molecules effectively with microcantilevers. The microcantilevers were fabricated employing surface micromachining technique that has attractive advantages in terms of cost efficiency, simplicity and ability of fabricating in array. The fluid cell system for injection of bio-molecular solution is fabricated using polydimethylsiloxane (PDMS) and a fused silica glass. The microcantilever is deflected with respect to the difference of the surface stress caused by the formation of self-assembled bio-molecules on the gold coated side of the microcantilever. It detected cystamine dihydrochloride and glutaraldehyde molecules and analyzed individual concentrations of the cystamine dihydrochloride solution. We confirm that the deflections of bending-up or bending-down are occurred by the bio-molecule adsorption and microcantilever can be widely used to a ${\mu}-TAS$ and a lab-on-a-chip for a potential detection of various bio-molecules.

Fabrication of a Three-dimensional Terahertz Photonic Crystal Using Monosized Spherical Particles

  • Takagi, Kenta;Seno, Kazunori;Kawasaki, Akira
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.374-375
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    • 2006
  • Three-dimensional artificial crystals with periodicity corresponding to terahertz wave lengths were fabricated by self-assembling monosized metal spherical particles. The metal crystals were weakly sintered to utilize them as templates. The metal templates were inverted to air spheres crystal embedded in dielectric resin though infiltration and etching. The resulting resin inverted crystals clearly presented the photonic stop gaps within terahertz wave region and the frequencies of the gaps were confirmed to agree well with calculation by plane wave expansion method.

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Characterization of biotin-avidin recognition system constructed on the solid substrate

  • Lim, Jung-Hyurk
    • Analytical Science and Technology
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    • v.18 no.6
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    • pp.460-468
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    • 2005
  • The biotin-avidin complex, as a model recognition system, has been constructed through N-hydroxysuccinimide(NHS) reaction on a variety of substrates such as a smooth Au film, electrochemically roughened Au electrode and chemically modified mica. Stepwise self-assembled monolayers (SAMs) of biotin-avidin system were characterized by surface-enhanced resonance Raman scattering (SERRS) spectroscopy, atomic force microscopy (AFM) and surface plasmon resonance (SPR). A strong SERRS signal of rhodamine tags labeled in avidin from the SAMs on a roughened gold electrode indicated the successful complex formation of stepwise biotin-avidin recognition system. AFM images showed the circular shaped avidin aggregates (hexamer) with ca. $60{\AA}$ thick on the substrate, corresponding to one layer of avidin. The surface coverage and concentration of avidin molecules were estimated to be 90% and $7.5{\times}10^{-12}mol/cm^2$, respectively. SPR technique allowed one to monitor the surface reaction of the specific recognition with high sensitivity and precision.

Phage Litmus: Biomimetic Virus-Based Colorimetric Sensors for Explosive Detection

  • O, Jin-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.90.1-90.1
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    • 2013
  • Nature utilizes various of the colorization process. Some species of birds can express their mood of tempers by changing their collagen structures on skin. For example, turkey can change their skin color by expansion of the collagen structures, which are associated with the distinct color changes. Here, we developed bioinspired virus-based colorimetric sensors which can be genetically tuned for target molecule. Using M 13 bacteriophage, we fabricated responsive self-assembled color matrices composed of quasi-ordered fiber bundle structures. These virus matrices can exhibit color change by stimuli through fiber bundle structure modulation. Upon exposure of volatile organic compounds, the resulting multi-colored matrices exhibited distinct color changes with different ratios that can be recognized by the naked eyes. Using the directed evolutionary approaches, we genetically engineered the virus matrix to incorporate binding motif for explosive detection (i.e., trinitrotoluene (TNT)). Through utilizing a common handheld device (i.e., iPhone), we could distinguish TNT molecules down to 20 ppb in a selective manner. Our novel biomimetic virus colorimetric sensor can overcome current limitation for low response selectivity.

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Finite element analysis for 3-D self-contact problems of C.v.joint rubber boots (3차원 자체접촉을 위한 유한요소해석에 의한 등속조인트 고무부트의 변형해석)

  • Lee, H.W.;Kim, S.H.;Lee, C.H.;Huh, H.;Lee, J.H.;Oh, S.T.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.12
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    • pp.2121-2133
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    • 1997
  • A finite element code is developed for 3-D self-contact problems, using continuum elements with a SRI(Selective Reduced Integration) scheme to prevent locking phenomenon by the incompressibility of rubber. Contact treatment is carried out in two ways : using the displacement constraints in case of rigid contact ; and imposing the same contact forces on two contact boundaries in case of self-contact. The finite element code developed is applied to the deformation analysis of C.V.joint boots which maintain lubrication conditions and protect the C.V.joint assembly from impact and dust. The boot accompanies large rotation depending on the rotation of the wheel axis and leading to the self-contact phenomena of the boot bellows. Since this contact phenomenon causes wear of the product and has great influence on the endurance life of the product, it is indispensable to carry out stress analysis of the rubber boots. In case of self-contact, various methods for determining contact forces have been suggested with an appropriate contact formulation. Especially, the types of penetration in self-contact are modularized to accelerate conputation with a contact algorithm.