• Title/Summary/Keyword: self -assembly

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3-D fcc Photonic Bandgap Structure of Silica Nanospheres (Silica nanospheres의 3차원 광결정 구조)

  • 우연경;하나영;황지수;장혜정;우정원
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.14-15
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    • 2003
  • 광결정(photonic crystal)은 주기적인 유전율 차이를 가지고 있는 인공적인 광학 물질이다. 그래서 이러한 광결정을 지나가는 전자기파는 마치 반도체와 같은 밴드갭을 가지게 된다. 우리는 silica nanosphere를 사용해서 자연의 보석 중, opal과 유사한 3차원 fcc(face-centered cubic) structure를 가지는 광결정을 만들었다. 평평한 유리기판을 용액에 수직으로 담근 후, 용액을 상온에서 증발시키면 자기 조립 방법(self-assembly method)으로 광결정이 만들어진다. (중략)

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Effects of ITO surface modification using self-assembly molecules on the characteristics of OLEDs

  • Oh, Se-Young;Kim, Dong-Hwi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.632-635
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    • 2007
  • We have synthesized 4'-nitrobiphenyl-4-carboxylic acid (NBCA) and fabricated the hole-only device consisting of ITO/NBCA SAM/TPD (1500 ${\AA}$)/Al (500 ${\AA}$) and the organic light emitting diodes (OLEDs) consisting of ITO/NBCA SAM/TPD (600 ${\AA}$)/Alq3 (600 ${\AA}$)/Al (600 ${\AA}$). The prepared hole-only device with NBCA exhibited lower driving voltage than the device with 4-nitrobenzoic acid (NBA). OLEDs using NBCA also show high external quantum efficiency.

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A study on elemental mercury adsorption behaviors of nanoporous carbons with carbon dioxide activation

  • Bae, Kyong-Min;Park, Soo-Jin
    • Carbon letters
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    • v.15 no.4
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    • pp.295-298
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    • 2014
  • In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs' pore structures and total pore volumes were analyzed by reference to $N_2$/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on their specific surface area and micropore fraction.

a new process for fabricating electrically conducting thin films

  • Onoda, Mitsuyoshi;Yoshino, Katsumi
    • Electrical & Electronic Materials
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    • v.8 no.6
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    • pp.795-805
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    • 1995
  • A novel thin film processing technique has been developed for the fabrication of ultrathin films of conducting polymers with molecular-level control over thickness and multilayer architecture. This new self-assembly process opens up vast possibilities in applications which require large area, ultrathin films of conducting polymers and more importantly in applications that can take advantage of the unique interactions achievable in the complex, supermolecular architectures of multilayer films.

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Self-Aggregation of Synthetic Magnesium Bacteriochlorins as a Photosynthetic Antenna Model

  • Kunieda, Michio;Mizoguchi, Tadashi;Tamiaki, Hitoshi
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.353-355
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    • 2002
  • We prepared 3-(1-hydroxyethyl)-bacteriopyrochlorophy11-a (3) possessing magnesium atom and phytyl ester from modification of natural bacteriochlorophyll(BChl)-a. A dichloromethane solution of (3$^1$R) and (3$^1$S)-3 was diluted with 100~1000 fold volume of cyclohexane to give new species absorbing near-infrared lights. The resulting Q, maximum of (3$^1$R)-3 was 860 nm and red-shifted by 2150 $cm^{-1}$ / from the monomeric. In the nonpolar organic solvent, epimeric (3$^1$S)-3 showed a 1ess red-shifted peak at 798 nm as well as a residual monomeric band. Such visible spectra indicated that 3 diastereose1ectively aggregated in cyclohexane to afford oligomers possessing a simi1ar supramolecular structure with chlorosomal aggregates of natural BChl-d, 7,8-dehydro-form of 3.

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Nano-scale Au nanopaticles Pattern and Application by Using NSOM Lithography (근접상 주사 현미경(NSOM)을 이용한 금(Au)나노입자의 패터닝과 기술응용)

  • Huh K.S.;Chang W.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1539-1542
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    • 2005
  • Self-assembled monolayers (SAMs) formed by the adsorption of alkanethiols, $HS(CH_2)_nX$, where X is an organic functional group, onto gold surfaces have attracted widespread interest as templates for the fabrication of molecular and biomolecular microstructures. Previously photopatterning has been thought of as being restricted to the micron scale, because of the wellknown diffraction limit. So, we have explored a novel approach to nanofabrication by utilizing a femtosecond laser coupled to a near-field scanning optical microscope (NSOM).

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