• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.800-804
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• 2011

A potentiometric sensor based on the Schiff base $(N^2E,N^{2'}E)-N^2,N^{2'}$-bis(thiophen-2-ylmethylene)-1,1'-binaphthl-2,2'-diamine has been synthesized and explored as an ionophore PVC-based membrane sensor selective for the silver ($Ag^+$) ion. Potentiometric investigations indicate a high affinity of this receptor for the silver ion. Seven membranes have been fabricated with different compositions, with the best performance shown by the membrane with an ionophore composition (w/w) of: 1.0 mg, PVC: 33.0 mg, DOA: 66.0 mg in 1.0 mL THF. The sensor worked well within a wide concentration range of $1.0{\times}10^{-2}$ to $1.0{\times}10^{-7}$ M, at pH 5, at room temperature (slope 57.4 mV/dec.), and with a rapid response time of 9 s; the sensor also showed good selectivity towards the silver ion over a huge number of interfering cations, with the highest selectivity coefficient for $Hg^{2+}$ at -3.7. Thus far, the best lower detection limit was $4.0{\times}10^{-8}$ M.

• Bulletin of the Korean Chemical Society
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• v.25 no.1
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• pp.59-62
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• 2004

The ammonium ion-selective electrodes ($NH^+_4$-ISEs) based on the tetrahydrofuran(THF)-containing-16-crown-4 derivatives,1,4,6,9,11,14,16,19-tetraoxocycloeicosane ($L^1$) and 5,10,15,20,-tetramethyl-1,4,6,9,11,14,16,19-tetraoxocycloeicosane ($L^2$), were prepared and the electrode characteristics were tested. The conditioned $NH_4^+$-ISEs (E1) based on $L^1$ with TEHP as a plasticising solvent mediator gave best results with near-Nernstian slope of 53.9 mV/decade of activity, detection limit of $10^{-4.9}$ M, and enhanced selectivity coefficients for the $NH^+_4$ ion with respect to an interfering $K^+$ ion (log $K^{pot}_{NH_4^+,K^+}$ = -1.84). This result was compared to other ammonium ionophores reported previously, for example, that of nonactin (log $K^{pot}_{NH_4^+,K^+}$ = -0.92). The proposed electrode showed no significant potential changes in the range of 3.0 < pH < 9.0.

• Clinical Pain
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• v.19 no.2
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• pp.90-96
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• 2020

Objective: To investigate the diagnostic accuracy of two physical examinations (straight leg raise [SLR] and Bragard test) and electromyography (EMG) in patients with lumbosacral monoradiculopathy in acute and chronic state on confirmation of different diagnostic criteria (MRI vs MRI and diagnostic selective nerve root block [DSNRB]). Method: We identified 297 participants retrospectively from the departmental database. MRI evidence of L5 or S1 nerve root compression and a positive result in diagnostic SNRB served as reference standards. They were divided into two groups by the symptom duration: lasting more than 12 weeks in the chronic group and less than 12 weeks in the acute group. The diagnostic value of clinical tests and EMG were compared. Results: The clinical tests (SLR and Bragard test) done in acute stage on detection by MRI and DSNRB had the highest sensitivity (68%) compared to the chronic stage (63%), but sensitivity was low (57%) on confirmation of MRI alone. However, there was no significant difference on sensitivity and specificity of EMG regardless of reference standards and symptom duration. Electromyography was a significant predictor of neuropathic abnormalities on both acute (OR, 6.3; 95% CI, 2.4 to 16.7; p<0.01) and chronic (OR, 6.8; 95% CI, 2.9 to 16.3; p<0.01). Conclusion: In general, individual physical tests are easy to do and a combination of those tests could be a sensitive indicator of L5 or S1 radiculopathy. Furthermore, the use of provocation tests could provide useful information, especially in proceeding therapeutic selective nerve root block.

• Journal of the Korean Society for Marine Environment & Energy
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• v.14 no.4
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• pp.280-286
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• 2011

In this research, the oil detection method and the characteristic of sensor using the selective reaction of silicone rubber in response to hydrocarbon oil will be described. As a sensing principle, the swelling property of silicone rubber in response to hydrocarbon fuel is used, also a strain gauge is used to transduce the volume change to an electrical signal. The sensor core is manufactured with a strain gauge embedded in silicone rubber by the curing process and experiments for characteristics of sensor core with various oils were carried out. It is shown that the sensor core can be used as an oil spill detection sensor. Also, for the application to the sea area, a buoy type sensor platform is integrated with a sensor core and a strain amplifier and it is tested in the simulated oil spill condition. In this study, it is proven that the integrated sensor can be used for the detection of various oils.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.45 no.11
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• pp.1-8
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• 2008

In this paper, we analyze the symbol error rate (SER) performance of maximum likelihood (ML) joint detection in downlink multiple-input multiple-output (MIMO) multicarrier code division multiple access (MC-CDMA) systems by deriving a tight union bound on the symbol error rate (SER). The union bound for ML joint detection is utilized to demonstrate the performance of MIMO MC-CDMA systems quantitatively in multiuser and frequency selective Rayleigh fading environments. An analysis of the diversity order of the systems shows the effects of multiple users, spread subcarriers, and multiple antennas on the ML joint detection performance. Furthermore, the analysis shows that MIMO MC-CDMA systems without full loading can achieve more diversify than MIMO orthogonal frequency division multiplexing (OFDM) systems.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.18 no.11
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• pp.1635-1644
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• 1993

In this paper, we examine the statistical characteristics of edge enhancing filters and their efficacy as preprocessing operator before edge detection. In particular, edge enhancing filters called the Comparison and Selection(CS), Hachimura-kuwahara(HK), and Selective Average(SA) filters are considered. These filters can reduce noise while producing step-type edges, thus seem to be effective for preprocessing noisy images prior to applying edge detecors. The ability of edge enhancing filters to suppress white Gaussian noise and the error probabilities occured during the edge detection following SA prefiltering are evaluated statistically through numerical analysis. The effect of prefiltering on edge detection is assessed by applying the edge enhancing fitters to a noise image degraded by additive white noise prior to applying the Sobel operator and the Laplacian of Gaussian( LoG ) operator, respectively. It is shown that the edge enhancing filters tend to produce ideal step-type edges while reducing the noise reasonably well, and the use of edge enhancing filters prior to edge detection can improve the performance of subsequent edge detector.

• Journal of Korean Society for Geospatial Information Science
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• v.14 no.3 s.37
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• pp.3-11
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• 2006

The need for edge detection about topography data from the high resolution satellite imagery is happening with increasing frequency according to many people utilize the its imagery as various fields recently. Many experts is recognizing of other GIS will make use of the road detection from the high resolution satellite imagery, including ITS (Intelligent Transportation Systems) and urban planning. This paper is comparative analysis of LPF (Low Pass Filtering) and HPF (High Pass Filtering) for roads edge detection from high resolution satellite imagery. As a result, LPF and HPF can be highlight selective pixels at edge area about input data. In case or applying to other techniques such as LPF for the same purpose, they aye more effective for wide road width which often cause the slight distortion of boundary or overall change of brightness values on the whole Image. Whereas, HPF has ability to enhance selectively detailed components in a target image.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.49 no.1
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• pp.94-102
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• 2012

Recently entered into an aging socity as the number of elderly drivers is increasing. Traffic accidents of elderly drivers are caused by driver inattentions such as poor vehicle control due to aging, visual information retrieval problems caused by presbyopia, and objects identifying problems caused by low contrast sensitivity. In this paper, detection method of ROIs on the road is proposed. The proposed method creates the saliency map to detect the candidate ROIs from the input image. And, the input image is segmented to obtain the ROIs boundary. Finally, selective visual attention regions are detected according to the presence or absence of a segmented region with saliency pixels. Experimental results from a variety of outdoor environmental conditions, the proposed method presented a fast object detection and a high detection rate.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.718-724
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• 2008

The ion selective microelectrode (ISME) has been used for measuring the ion profile of DO, $NH_4{^+}-N$, $NO_2{^-}-N$ and $NO_3{^-}-N$ in biofilm. In this study we evaluated the detection limit and validity of ISME and applied ISME for the continuous measurement of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentration in the modified Ludzack-Ettinger (MLE) process. Average detection limits of $NH_4{^+}-N$ and $NO_3{^-}-N$ ISME were $10^{-4.44}M$ and $10^{-4.62}M$, respectively. Since the ISME with $5{\sim}10{\mu}m$ of tip diameter showed a faster response time than that of $1{\sim}5{\mu}m$, the ISME with a tip diameter of $5{\sim}10{\mu}m$ was fabricated and used to make real-time ion detections. Direct monitoring of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentrations in the aerobic (2) tank causes the instability of the electromotive force (EMF) for the initial 5~8 hours and also causes remarkable error values of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentration. This phenomenon is caused by aeration and mixing in the reactor. Thus, the measuring chamber was newly designed for the aerobic (2) tank and then the EMF of the ISME were stabilized in less than 1 hour. Errors of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentration were decreased after stabilization of the EMF. The ISME analysis were well corresponded to the results of auto analyzer and ion chromatography. Consequently, the concentration of $NH_4{^+}-N$ and $NO_3{^-}-N$ could be continuously measured for 178 hours by the ISME.

• Clean Technology
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• v.11 no.2
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• pp.69-74
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• 2005

A metal ion detector with a submicron size electrode was fabricated by field-induced AFM oxidation. The square frame of the mesa pattern was functionalized by APTES for the metal ion detection, and the remaining portion was used as an electrode by the self-assembly of MPTMS for Au metal deposition. The conductance changed with the quantity of adsorbed copper ions, due to electron tunneling between the mobile and surface electrodes. The smaller electrode has a lower limit of detection due to the enhancement in electron tunneling through metal ions that are adsorbed between the conductive-tip (mobile) and the surface (fixed) electrode. This two-electrode system immobilized with different functional groups was successfully used in the selective adsorption and detection of target materials.