• Title/Summary/Keyword: selective Removal

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A Study on Recycle of Concreted Organic Waste water by Electroflotation Apparatus for Resource Recycle of Non-Metal (비금속 자원 재활용을 위한 전해부상 장치를 이용한 고농도 유기질 폐수의 재활용에 관한 연구)

  • Kim, Ki-Jun;Nam, Sang-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.4
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    • pp.653-658
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    • 2012
  • There is an increasing interest in the use of electrochemical methods for the food waste treatment. The technologies using the electrochemical method provide ideal tools for approaching industrial and food wastes problems. Unlike other chemical treatments, the electrochemical systems do not make the volume of the secondary waste increase. The electrochemical methods can be operated with electrochemical apparatus and inorganic agent allow selective separation and recovery and even quieter than others. This study concerns design factors, electrode construction and wastewater treatment process of the electrochemical apparatus. The experiment of color, COD and BOD removal is much effective in using electrochemical method with ultrasonication and ozonation.

A Study on Inorganic Chemical Treatment Method of Animal Wastes Using by Electroflotation for Recycle (전해부상 장치를 이용한 축산폐수의 유기질비료와 용수 재활용에 관한 연구)

  • Sung Ki-chun;Kim Yong-Ryul;Kim Ki-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.6
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    • pp.588-591
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    • 2004
  • There is an increasing interest in the use of electrochemical methods for the animal waste treatment The technologies using the electrochemical method provide ideal tools for approaching industrial and animal wastes problems. Unlike other chemical treatments, the electrochemical systems do not make the volume of the secondary waste increase. The electrochemical methods can be operated with electrochemical apparatus and inorganic agent allow selective separation and recovery and even quieter than others. This study concerns design factors, electrode construction and wastewater treatment process of the electrochemical apparatus. The experiment of color, COD and BOD removal is much effective in using electrochemical method with ultrasonication and ozonation.

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Effect of the Number of Electron Beam Drip Melting on the Characteristics of Molybdenum ingot (전자빔 drip 용해횟수가 Mo 잉고트 특성에 미치는 영향)

  • Choi, Good-Sun;Rhee, Kang-In;Lee, Dong-Hi
    • Journal of Korea Foundry Society
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    • v.15 no.3
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    • pp.283-290
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    • 1995
  • Molybdenum ingot of 50mm in diameter were obtained from sintered Mo bars by EB drip melting technique. Macroscopic observation of EB remelted ingot indicates that coarse and columnar grains grow in the direction parallel to ingot pulling direction. This can be explained by slow solidification (3mm/min), large temperature gradient and heat flow to this direction. The orientation of columnar structure was found to be <110>, <200> and <211> by the analysis of X-ray diffraction patterns. The contents of typical metallic impurities in Mo sintered bar are 1.2ppm Cr, 3ppm Fe, 44ppm Zr, 150ppm W. Most of metallic impurities were reduced below the order of ppm except zirconium and tungsten by the selective evaporation. In the removal of nonmetallic impurities, oxygen and carbon impurities were lowered from 120 to 6ppm and from 157 to 106ppm, respectively, after first melting. Although the purification effect was not significant with the number of remelting, Vickers hardness was reduced from 217 to 195 and 184 in sequence with increasing the number of remelting.

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The Extraction of Palladium by Polyurethane Foam impregnated with ${\beta}$-Diphenylglyoxime (${\beta}$-디페닐글리옥심으로 침윤시킨 폴리우레탄 포움에 의한 팔라듐의 추출)

  • Sam Woo Kang;Seung Seok Lee
    • Journal of the Korean Chemical Society
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    • v.27 no.4
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    • pp.268-272
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    • 1983
  • Polyurethane foam impregnated with ${\beta}$-diphenylglyoxime has been applied to the extraction of palladium(II) from platinum(IV) and nickel(II) in aqueous solution. Palladium(II) is quantitatively extracted from $0.01{sim}0.05M$ HCl. On the other hand, platinum(Ⅳ) was slightly extracted and nickel(II) was not found to be extraction in the same experimental condition. Based on the results obtained, the selective separation, removal and recovery of Pd(II) from Pt(IV) or Ni(II) was possible by batch or elution method.

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Fabrication of Nanostructured Films of Block Copolymers for Nanolithographical Masks (나노리소그래피 마스크용 블록공중합체 나노구조 필름의 제조)

  • Park Dae-Ho;Sohn Byeong-Hyeok;Jung Jin Chul;Zin Wang-Cheol
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.181-186
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    • 2005
  • We fabricated thin films of polystyrene-block-poly(methyl methacrylate)(PS -b-PMMA) on the self-assembled monolayers(SAM) of 3-(p-methoxyphenyl)propyltrichlorosilane(MPTS) on silicon wafers. Cylindrical nanodomains of PMMA or PS were oriented perpendicular to the surface of silicon wafers due to the neutral affinity of the SAM to PS and PMMA blocks. By selective removal of the PMMA block with UV irradiation and washing, nanoporous films and nanorod assemblies were produced. The nanoporous film can be used for a nanolithographical mask.

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The Formation of Dendrimeric Silane on Poly(carbosilane): Silane Arborols $(V)^1$ (Carbosilane 고분자상의 나무가지꼴 실란거대분자 형성: Silane Arborols $(V)^1$)

  • Kim, Chung Kyun;Park, Eun Mi;Jung, In Kyung
    • Journal of the Korean Chemical Society
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    • v.40 no.5
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    • pp.347-356
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    • 1996
  • The selective cleavage of phenylsilane by triflic acid gives silyltriflates. The removal of phenyl groups in $Ph_3SiH$ and carbosilane polymer $(Ph_2SiCH_2CH_2CH_2)n$ with one to two equiv of triflic acid leads to formation of mono- and disubstituted silyltriflate ester bonds. Reaction with allylmagnesium bromide produces corresponding derivatives with good yields. An organosilane dendrimer with allylated carbosilane polymer has been synthesized up to G3 using repetitive allylation hydrosilylation cycles.

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8 Antenna Polar Switching Up-Down Relay Networks

  • Li, Jun;Lee, Moon-Ho;Yan, Yier;Peng, Bu Shi;Hwang, Gun-Joon
    • Journal of electromagnetic engineering and science
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    • v.11 no.4
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    • pp.239-249
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    • 2011
  • In this paper, we propose a reliable $8{\times}8$ up-down switching polar relay code based on 3GPP LTE standard, motivated by 3GPP LTE down link, which is 30 bps/Hz for $8{\times}8$ MIMO antennas, and by Arikan's channel polarization for the frequency selective fading (FSF) channels with the generator matrix $Q_8$. In this scheme, a polar encoder and OFDM modulator are implemented sequentially at both the source node and relay nodes, the time reversion and complex conjugation operations are separately implemented at each relay node, and the successive interference cancellation (SIC) decoder, together with the cyclic prefix (CP) removal, is performed at the destination node. Use of the scheme shows that decoding at the relay without any delay is not required, which results in a lower complexity. The numerical result shows that the system coded by polar codes has better performance than currently used designs.

Fabrication of Metal Nanobridge Arrays using Sacrificial Silicon Nanowire

  • Lee, Kook-Nyung;Lee, Kyoung-Gun;Jung, Suk-Won;Lee, Min-Ho;Seong, Woo-Kyeong
    • Journal of Electrical Engineering and Technology
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    • v.7 no.3
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    • pp.396-400
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    • 2012
  • Novel fabrication method of nanobridge array of various materials was proposed using suspended silicon nanowire array as a sacrificial template structure. Nanobridges of various materials can be simply fabricated by direct deposition with thermal evaporation on the top of prefabricated suspended silicon nanobridge arrays, which are used as a sacrificial structure. Since silicon nanowire can be easily removed by selective dry etching, nanobridge arrays of an intended material are finally obtained. In this paper, metal nanobridges of Ti/Au, around 50-200 nm in thickness and width, 5-20 ${\mu}m$ in length were fabricated to prove the advantages of the proposed nanowire or nanobridge fabrication method. The nanobridges of Ti/Au after complete removal of sacrificial silicon nanowire template were well-established and bending of nanobridge caused by the tensile stress was observed after silicon removing. Up to 50 nm and 10 ${\mu}m$ of silicon nanowire in diameter and length respectively was also very useful for nanowire templates.

Preparation of novel NF membrane via interfacial cross-linking polymerization

  • Lehi, Arash Yunessnia;Akbari, Ahmad;Soleimani, Hosna
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.173-187
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    • 2015
  • The goal of present work is the preparation of a novel positively charged nanofiltration (NF) membrane and its development for the cation removal of aqueous solutions. This NF membrane was fabricated by the surface modification of polysulfone (PSf) ultrafiltration support. The active top-layer was formed by interfacial cross-linking polymerization of poly(ethyleneimine) (PEI) with p-xylylene dichloride (XDC) and then quaternized with methyl iodide to form a perpetually positively charged layer. In order to improve the efficiency of nanofiltration membrane, the concentration of PEI, XDC and methyl iodide solutions, PEI coating and cross-linking time have been optimized. As a result, a high water flux and high $CaCl_2$ rejection (1,000 ppm) was obtained for the composite membrane with values of $18.29L/m^2.h$ and 93.62% at 4 bar and $25^{\circ}C$, respectively. The rejections of NF membrane for different salt solutions followed the order of $Na_2SO_4$ < $MgSO_4$ < NaCl < $CaCl_2$. Molecular weight of cut off (MWCO) was calculated via retaining of PEG solutions with different molecular weights that finally, it revealed the Stokes and hydrodynamic radius of 1.457 and 2.507 nm on the membrane selective layer, respectively. The most efficient positively charged nanofiltration membrane exhibited a $Ni^{2+}$ rejection of 96.26% for industrial wastewater from Shamse Hadaf Co. (Kashan, Iran).

Selective Removal of Cr (VI) and Cr (III) in Aqueous Solution by Surface Modified Activated Carbon

  • Lee, Jeong-Min;Kim, Min-Il;Lee, Young-Seak
    • Carbon letters
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    • v.9 no.1
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    • pp.23-27
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    • 2008
  • The adsorption and reduction of Cr (VI) to Cr (III) by surface modified activated carbon (AC) in an aqueous solution was studied. The effects of surface modifications on the properties of the carbons were investigated by the analysis of specific surface area, carbon surface pH, acid/base surface values and functional groups. In order to understand the Cr(VI) adsorption and reduction ratio from Cr(VI) to Cr(III), the Cr adsorption capacity of AC was also measured and discussed by using inductively coupled plasma and UV spectrophotometer. The modifications bring about substantial variation in the chemical properties whereas the physical properties such as specific surface area, pore volume and pore size distribution nearly were not changed. Total Cr adsorption efficiency of as-received activated carbon (R-AC) and nitric acid treated activated carbon (N1-AC and N2-AC) were recorded on 98.2, 99.7 and 100%. Cr(III) reduction efficiency of R-AC increased largely from 0.4% to 28.3% compared to N1-AC and N2-AC.