• Journal of Korean Society on Water Environment
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• v.26 no.3
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• pp.387-398
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• 2010

SWAT model would be applied to evaluate the pollutant removal capacity with various best management practices (BMPs) in Kyongan stream watershed which plays an important role in water quality conservation and improvement of Paldang reservoir. The methods for the representation of various BMPs scenarios with SWAT is developed and evaluated. Riparian buffer strip, agricultural conservation practices to reduce fertilizer, sediment, and nutrients occurring from farm field (Grassed swale, Contour farming/Parallel terrace, Field border, Farm retention pond, Grade stabilization structure), and washland such as wetland and pond to extend detention and improve water quality are represented in SWAT. And to represent the expansion of existing Waste Water Treatment Plants (WWTPs) in Soil and Water Assessment Tool (SWAT), reduction effect for point source pollutants was simulated. As the result of simulation, the removal rates of SS, TN, TP from scenarios of Kyongan stream watershed are the average annual SS yield by 5.2% to 69.2%, the average annual TN yield by 0.5% to 26.3%, and the average annual TP yield by 1.3% to 32.5%, respectively. This study has demonstrated that the SWAT is a very reliable and useful water quality and quantity assessment tool, and the BMPs representation in SWAT for watershed management is able to effectively simulate in Kyongan Stream watershed.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.336-336
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• 2011

본 연구에서는 강우시 경사지 밭에서 발생하는 토양유실량을 저감하기 위하여 지표피복재의 유무와 강우강도를 달리하여 실외인공강우 실험을 통하여 평가하였다. 인공강우 실험은 경사도 28%와 각 시험포는 $5\times30m$의 크기로 strawmat+PAM+sawdust, control(bare), strawmat+PAM, strawmat+PAM+rice husks를 4개 조성하고, 각 시험포는 하단부에 강우유출수를 채취할 수 있는 설비(flume)를 설치하였다. 대조구 실험을 위하여 각 시험포에서 발생하는 직접유출량과 유사량을 비교 분석하였다. 시험포의 토양은 양질사토로 일반 고랭지 밭의 흙과 동일한 성질을 가지고 있는 토양을 사용하였고, 지표 피복처리는 straw mat, saw dust, rice husk 그리고 PAM 등 4개의 재료를 사용하였다. 인공강우 실험은 1차 10월 18일, 2차 10월 24일, 3차 10월 30일, 4차 11월 7일로 총 21일간 각각 약 1주일의 간격을 두고 실시하였으며 인공강우 시험기의 강우강도는 각 31.1 ~ 44.4 mm/hr로 모의하였다. 연구결과 시험포에서 발생한 유출량은 지표피복을 하지 않은 대조구 시험포보다 지표를 피복한 시험포에서 약 15.7 ~ 19%의 감소한 것으로 나타났다. 유사량은 대조구 시험포보다 약 93.1 ~ 99.3% 감소한 것으로 나타났으며, 유출량과 유사량은 straw mat+PAM+sawdust와 straw mat+PAM+rice husk를 적용한 시험포에서 저감효과가 큰 것으로 나타났다. 이와 같이 지표피복처리는 강우가 발생하였을 때 강우타격력의 감소와 유출수의 유속감소 그리고 침투능을 증가하는 역할을 하여 경사지, 농경지 및 공사현장에서 토양 유실을 저감하며, 하천이나 강으로 유입되는 탁수량의 저감에 큰 효과가 있을 것으로 판단된다.

• Journal of Korean Society on Water Environment
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• v.20 no.6
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• pp.670-675
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• 2004

Humic acids are macromolecules originated from natural water, soil, and sediment. The characteristics of humic acid enable it to change the distribution of metals as well as many kinds of organic contaminants and to determine the sorption of them from soil solution. To see the effect of humic acid on the removal rate of organic contaminants and heavy metals, batch-scale experiments were performed. As a natural geosorbent, black shale was used as a sorbent media, which showed hight sorption capacity of trichloroethylene (TCE), lead, cadmium and chromium. The effect of sorption-desorption, pH, ionic strength and the concentration of humic acid was taken into consideration. TCE sorption capacity by black shale was compared to natural bentonite and hexadecyltrimethylammonium (HDTMA) modified bentonite. The removal rate was good and humic acid also sorbed onto black shale very well. The organic part of humic acid could effectively enhance the partition of TCE and it act as an electron donor to reduce Cr(VI) to Cr(III). Cationic metal of Pb(II) and Cd(II) also removed from the water by black shale. With 3 mg/L of humic acid, both Pb(II) and Cd(II) were removed more than without humic acid. That could be explained by sorption and complexation with humic acid and that was possible when humic acid could change the hydrophobicity and solubility of heavy metals. Humic acid exhibited desorption-resistivity with black shale, which implied that black shale could be an alternative sorbent or material for remediation of organic contaminants and heavy metals.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.2
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• pp.223-230
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• 2011

An electrolytic oxidation process was applied to remove odorous compounds from non-point odor sources including wastewater pipelines and manholes. In this study, a distance between the anode and the cathode of the electrolytic process was varied as a system operating parameters, and its effects on odor removal efficiencies and reaction characteristics were investigated. Odor precursors such as sediment organic matters and reduced sulfur/nitrogen compounds were effectively oxidized in the electrolytic process, and a change in oxidation-reduction potential (ORP) indicated that an stringent anaerobic condition shifted to a mild anoxic condition rapidly. At an electrode distance of 1 cm and an applied voltage of 30 V, a system current was maintained at 1 A, and the current density was 23.1 $mA/cm^{2}$. Under the condition, the removal efficiency of hydrogen sulfide in gas phase was found to be 100%, and 93% of ammonium ion was removed from the liquid phase during the 120 minute operating period. Moreover, the sulfate ion (${SO_4}^{2-}$) concentration increased about three times from its initial value due to the active oxidation. As the specific power consumption (i.e., the energy input normalized by the effective volume) increased, the oxidation progressed rapidly, however, the oxidation rate was varied depending on target compounds. Consequently, a threshold power consumption for each odorous compound needs to be experimentally determined for an effective application of the electrolytic oxidation.

• Ocean Science Journal
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• v.40 no.3
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• pp.127-143
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• 2005

The taxonomic sufficiency approach has been proposed as a surrogate for the typical analysis of species-abundance data, especially in conditions involving prominent pollution gradients. Here, we evaluate the use of taxonomic sufficiency with infralittoral macrobenthic data derived from samples taken in a moderate polluted subtropical environment in southeastern Brazil, analysing five taxonomic levels and including two functional levels throughout polychaete feeding guilds and trophic groups. The data were collected seasonally at nine stations and studied for two abundance data series (0.5 and 1.0 mm sieve mesh-size). The results showed a similar ordination pattern between the two sieve mesh-size, but with the 0.5 mm sieve data a different pattern was observed during austral summer. A slight loss of information was detected using genus, family, polychaete species and their feeding guilds as taxonomic/functional units. These results together with those of the cost! benefit ratio, suggested that the family level seemed to be sufficient to detect the impact caused by moderate pollution in this shallow-water, subtropical environment. In additional, through the use of feeding guilds, similar patterns are obtained. Correlation analysis showed that chlorophyll a, total organic matter, zinc, and chromium sediment content were the variables that best explained the biological pattern observed and not always the best correlation coefficient occurring at the species level. The feeding guild approach seems to be useful and generates interpretable results similar to those obtained with the species level of the whole macroinfauna. The results showed an important cost reduction in the sample processing, suggesting that it is possible to adopt a coarser taxonomic level monitoring program even in species-rich communities.

• Journal of The Korean Society of Agricultural Engineers
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• v.62 no.4
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• pp.13-22
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• 2020

The Doam Lake watershed has a significant impact on the downstream water system due to nutrients and sediment outflow during rainfall caused by steep slopes, soil losses, and fertilization. These non-point sources are unclear in the discharge area and are affected by land use patterns, soil characteristics, and topographical features of the watershed. Therefore, this study conducted rainfall monitoring from July to October 2019 in Songcheon upstream of the Doam Lake watershed, one of the non-point pollution source management areas. Then, after analyzing rainfall runoff, Event Mean Concentration (EMC) and Mass First Flush ratio (MFFn) were calculated to compare and analyze the characteristics of rainfall and the non-point pollutant discharge. As a result of the analysis, it showed various non-point pollutant emission characteristics for each rainfall event. In addition, the concentration of EMC and the MFFn were affected by the average rainfall intensity and the maximum rainfall intensity, and were not significantly affected by the number of antecedent drying days. In the future, it is expected that effective non-point source reduction measures and management measures according to rainfall intensity through continuous monitoring and analysis will be needed.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2813-2818
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• 2010

A novel method was developed for the speciation of chromium in natural water samples based on homogeneous liquid-liquid extraction and determination by flame atomic absorption spectrometry (FAAS). In this method, Cr(III) reacts with a new Schiff's base ligand to form the hydrophobic complex, which is subsequently entrapped in the sediment phase, whereas Cr(VI) remained in aqueous phase. The Cr(VI) assay is based on its reduction to Cr(III) by the addition of sodium sulfite to the sample solution. Thus, separation of Cr(III) and Cr(VI) could be realized. Homogeneous liquid-liquid extraction based on the pH-independent phase-separation process was investigated using a ternary solvent system (water-tetrabutylammonium ion ($TBA^+$)-chloroform) for the preconcentration of chromium. The phase separation phenomenon occurred by an ion-pair formation of TBA and perchlorate ion. Then sedimented phase was separated using a $100\;{\mu}L$ micro-syringe and diluted to 1.0 mL with ethanol. The sample was introduced into the flame by conventional aspiration. After the optimization of complexation and extraction conditions such as pH = 9.5, [ligand] = $1.0{\times}10^{-4}\;M$, [$TBA^+$] = $2.0{\times}10^{-2}\;M$, [$CHCl_3$] = $100.0\;{\mu}L$ and [$ClO_4$] = $2.0{\times}10{-2}\;M$, a preconcentration factor (Va/Vs) of 100 was obtained for only 10 mL of the sample. The relative standard deviation was 2.8% (n = 10). The limit of detection was sufficiently low and lie at ppb level. The proposed method was applied for the extraction and determination of chromium in natural water samples with satisfactory results.

• Journal of Ecology and Environment
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• v.30 no.2
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• pp.109-119
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• 2007

The effect of water flow on the growth of Gafrarium tumidum was studied in the field using open cages constructed with stainless steel net and perspex in which holes were drilled. Cages with different flows (25, 50 and 75% of the control) were made by varying the area of perspex being drilled. Reduction in flow rate was directly proportional to the undrilled area, and the mean flow rate of the different treatment groups varied from 3.12 cm/s for the 25% exposure to 12.48 cm/s for the control cages. At the end of the 3-month experiment, no significant differences in sediment characteristics were found among the treatments. Growth in shell length, shell weight and tissue dry weight was, however, positively correlated with flow rate. Percentage increases ranged from $3.0{\sim}8.3%$ for shell length, $9.9{\sim}23.1%$ for shell weight and $17.2{\sim}53.3%$ for tissue dry weight. Condition index of the clam was not significantly different among the treatments. Seston depletion effect could reduce growth in G. tumidum only when water flow was reduced to 25% of the control. G. tumidum also exhibited different responses in shell and tissue growth at low flow rates, in which shell growth continued to decrease as flow rate decreased whereas tissue growth was relatively independent of low flows at 25 and 50% of the control. It was suggested that when seston flux was reduced at slow flows, it would be a better strategy for G. tumidum to channel energy for gonad development instead of shell growth during the reproductive stage.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.373-376
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• 2006

본 연구의 목적은 동해 울릉분지의 제4기 후기 퇴적물 내의 유기물, 공극수와 메탄의 특징 및 상호작용을 규명하는데 있다. 연구지역에서 채취한 코어퇴적물을 원소 분석한 결과 C/N 및 C/S 비(wt. %)는 퇴적물 내 유기물이 주로 해양조류 기원을 가지고, 일반적인 해양 또는 정체 환경에서 퇴적되어Tdam을 지시한다. 그러나 Rock-Eval 열분석 결과는 유기물 기원이 육상식물(Type III)이고, 열적 성숙단계가 미성숙단계임을 보여준다. 이러한 원소분석과 열분석간의 상반된 결과는 유기물이 침강하는 동안 또는 퇴적 후 이루어진 강한 산화작용에 기인한 것으로 추정된다. 퇴적물 내 공극수의 황산염 농도가 퇴적물의 심도가 증가할수록 감소하며, 감소하는 경향은 크게 두 가지 (적선성, concave down)로 나누어진다. 이는 모든 코어에서 황산엽 환원작용이 일어나고 있음을 지시한다. 또한 직선선의 황산엽농도 구배는 무산소 메탄 산화작용(AMO)의 전형적인 특징이다. 황산염 농도의 수직적 구배를 이용하여 SMI(sulfate-methane interface) 심도를 계산하면, 남부울릉분지의 코어 (03GHP-01, 03GHP-02; <3.5mbsf)가 북부울릉분지 코어(01GHP-05, 01GHP-07, 03GHP-03, 03GHP-04, 03GHP-05; > 6mbsf)보다 낮은 값을 갖는다. 위와 같은 SMI 심도차는 메탄의 상부 분산량과 밀접한 관련있는 것으로 추정된다. 메탄가스의 탄소 안정동위원소 $({\delta}^{13}C)$ 분석값들은 -83.5%o에서 -69.5%o의 범위를 가지고 있고, 이산화탄소 환원작용($CO)_2$ reduction)에 의한 생물 (biogenic) 기원임을 지시한다.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.272-272
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• 2015

본 연구는 초생대 필지단위 모의프로그램인 VFSMOD-W(Vegetative Filter Strip MODel-W) 모형을 이용하여 새만금 유역의 밭경지 특성을 반영한 다양한 시나리오에 기반하여 초생대기법을 적용 하였을 경우의 유사저감효과에 대해 모의해 보았다. '새만금유역 농업비점오염 저감기법 개발'과제의 일환으로 초생대 현장실험을 위해 조성된 익산 밭경지 시험포의 실측치를 이용하여 모형의 보정이 이루어졌으며, 결과는 유출량의 경우 NSE=0.833와 $R^2=0.99$를, 유사량의 경우 NSE=0.794와 $R^2=0.99$로 각각 매우 높게 나타났다. 모의를 위한 시나리오는 새만금유역의 밭경지 특성을 고려하여 1ha, 5ha, 10ha의 밭규모에, 밭경사는 7%와 15%으로, 토성은 양토인 정방형 형태의 밭경지를 대상으로 하였다. 초생대 초종은 Grass mixture로 적용하였고, 규모는 밭경지 면적의 10%로 고정하여, 50mm, 100mm, 150mm, 200mm의 일강우량에 대해 초생대 유출 및 유사에 대한 모의를 실시하였다. 그 결과 새만금유역에 초생대 적용 시 유출저감효과는 밭경사 7%와 15%일 때 1.5~13.5%와 1.4~12.1%의 범위로 각각 나타났으며, 경사에 따른 차이는 미비하였으나 강우량과 밭경지 규모에 따른 유출저감효과의 차이가 크게 나타났다. 유사의 경우에는 밭경사 7%와 15%일 때 20.4~97.0%와 15.7~86.0%의 저감효과를 각각 보였으며, 유출에 비해 초생대 적용에 따른 유사저감효과가 월등히 높게 나타났다. 강우량의 차이에 따른 유사저감효과는 50mm일 때 58.4~97.0%, 200mm일 때 15.7~32.9%를 나타내어 강우인자의 영향이 밭규모와 경사 등의 밭경지 특성에 비해 유사 발생량 및 저감효과에 가장 크게 미침을 알 수 있었다. 본 모의 결과를 통해 새만금유역의 초생대기법 적용은 새만금호의 수질오염저감 및 개선에 기여할 수 있을 것으로 기대되며, 현장 실용화를 위해서는 다양한 현장인자들에 적합한 세부적인 설계기술 개발이 요구된다.