• Journal of Korean Society of Water and Wastewater
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• v.22 no.5
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• pp.551-559
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• 2008

An experimental study was carried out to evaluate the potential of flotation process for the secondary clarifier of an activated sludge process. Flotation techniques, applied in this study, include electrofloation (EF) which generated fine bubbles smaller than $35{\mu}m$ in average and diffuser flotation (DF) which generated fine bubbles smaller than $55{\mu}m$ in average. The batch experiments were done with activated sludge displaying various characteristics. It was shown that the efficiency of solids/liquid separation was reduced as the diluted sludge volume index ($DSVI_{30}$) of activated sludge increased. The dependency, however, gradually decreased as the gas to solids (G/S) ratio increased. Thickening efficiency of EF was more than 2~10 times and DF process was more than 1.5~5 times as compared with gravity sedimentation (GS). Stable sludge blanket was maintained regardless of sludge settleability when the G/S ratio was 0.019 in the EF. On the other hand, Serious deterioration in the sludge blanket was observed in the DF depends on G/S ratio and sludge settleability. And For EF and DF, the suspended solids concentration of effluent was not nearly influenced on settleability of activated sludge and more clear than GS. A biological nutrient removal (BNR) process, combined with EF as a secondary clarifier was operated for three months. The mean MLSS (mixed liquid suspended solids) concentration in the reactor and mean solids concentration of return sludge were estimated to be 5,340 mg/L and 16,770 mg/L, respectively. The water quality of effluent was considerably stable and low value was accomplished, that was, standard suspended solids concentration $0.07{\pm}0.51mg/L$ and standard turbidity $1.44{\pm}0.56NTU$. The EF could be applicable for enhancement of efficiency of activated sludge system as well as improvement of the water quality of effluent.

• Journal of The Korean Society of Agricultural Engineers
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• v.48 no.2
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• pp.77-87
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• 2006

The reuse of wastewater for agricultural irrigation may cause human health risk as a result of exposure to pathogens. This study conducted the quantitative microbial risk assessment in paddy field irrigated with treated wastewater. Six treatments were used to irrigate the paddy field from Year 2003 to Year 2005: biofilter-effluent, UV-disinfected water (6, 16, 40, 68 $mW s cm^{-2}$), pond-treated water, wetland-treated water, conventional irrigation water and tap water. Total coliforms, fecal coliforms and E. coli were monitored during rice growing period. Beta - Poisson model was employed to calculate the microbial risk of pathogens ingestion that may occur to farmers and neighbor children. Uncertainty of risk was estimated using Monte Carlo simulation. In this study, the microbial risk was higher during initial cultivation (end of May$\sim$June), and it decreased with time. Biofilter effluent (secondary effluent) irrigation showed higher risk values than others (>$10^{-4}$) and irrigation with UV-disinfected water has the lowest risk range ($10^{-6}{\sim}10^{-5}$). The risk value estimated in 2005 was lower than risk value in 2003 and 2004, it is likely due to clean tap water irrigation in initial transplanting stage. It is suggested that irrigation with UV-disinfected water and pond-treated water would reduce the microbial risk associated with wastewater irrigation in paddy field. In addition, the first irrigation water quality significantly affected the subsequent microbial risk.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.3
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• pp.409-421
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• 2012

Ethanolamine (ETA) is mainly used to prevent corrosion of pipe in secondary cooling system of nuclear power plant. Condensed ETA in wastewater could increase COD and T-N when it was emitted to natural water system. Compared to conventional treatments, electrochemical oxidation process using packed bed bipolar electrodes was adopted to treat COD and T-N. According to arrangement of feeder electrode, single packed bed bipolar electrode reactor and multi-paired packed bed bipolar reactor were developed and conventional zero-valent iron (ZVI) was selected as conducting bipolar electrode. Bipolar electrodes were coordinated three-dimensionally in the reactor. The experimental results showed that COD and T-N was little removed in unit system at different pH condition (pH 8 and 11) on 100V. However, in multi-paired system that applied 600V, COD was eliminated 80.85% (anode-cathode-anode, A-C-A) and 85.11% (cathode-anode-cathode, C-A-C), respectively. T-N was also removed 96.88% (A-C-A) and 90.63% (C-A-C), simultaneously. Current efficiency was estimated both single and multi-paired system. At unit bipolar packed bed reactor, current efficiency was almost zero, however in multi-paired system, current efficiency was 300~500% at A-C-A and 250~350% at C-A-C. Current efficiency was over 100% hence it was confirmed that this system is more effective than conventional electrochemical oxidation system.

• Journal of Korean Society on Water Environment
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• v.22 no.6
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• pp.991-995
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• 2006

The layered double hydroxide with the insertion of chloride ions (LDH-Cl), which was synthesized by the co-precipitation method, was applied to investigate the fundamental aspects of the absorptive agent for phosphate removal from wastewater. The adsorption capacity was best described by the Langmuir-FreundIich isotherm, and the estimated isotherm parameters indicate that the LDH-CI capacity for the phosphate removal is much higher than that observed using a natural adsorbent material such iron oxide tailing. The kinetic experiment also showed that the LDH-Cl adsorption reaction rapidly at the adsorptive rate of 0.55 mg-P/g-LDH/min, implying that this adsorbent can be of use in the full-scale applications. The pH had a minimal effect on the LDH adsorption capacity in the range of 5 to 11, although the capacity dropped at the low pHs because of the change in LDH surface properties. Furthermore, other anions such as $Cl^-$ and $NO_3{^-}$ commonly found in the wastewater streams insignificantly affected the phosphate removal efficiencies, while $HCO_3{^-}$ ions had a negative effect on the LDH adsorption capacity due to its high selectivity. The phosphate removal experiment using the actual secondary effluent from a wastewater treatment plant showed the similar decrease in adsorption capacity, indicating that the bicarbonate ions in the wastewater were competing with phosphate for the adsorptive site in the surface of the LDH-Cl. Overall, the synthetic adsorbent material, LDH-Cl, can be a feasible alternative over other conventional chemical agents, since the LDH-Cl exhibits the high phosphate removal capacity with the low sensitivity to other environmental conditions.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.2
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• pp.161-168
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• 2017

Microfiltration (MF) and Ultrafiltration (UF) membrane processes capable of producing highly purified water have been extensively applied as a pretreatment process in the wastewater reuse field with the improvement of membrane properties and resistance, development of operating protocols, and improvement of technologies of backwashing and physicochemical cleaning, and improvement of scale and antifoulants. However, despite of the development of membrane production and process technologies, fouling still remains unresolved. This study confirmed that foulants such as polysaccharides, proteins and humic substances existed in final treated effluent (secondary effluent) by fluorescence excitation emission matrix (FEEM) and fourier transform infrared spectroscopy (FTIR) analysis. In addition, when constructing ozone oxidation and coagulation processes as a hybrid process, the removal efficiency was 5.8%, 6.9%, 5.9%, and 28.2% higher than that of the single process using coagulation in turbidity, color, dissolved organic carbon (DOC), and UV254, respectively. The reversible and irreversible resistances in applying the hybrid process consisting of ozone oxidation and coagulation processes were lower than those in applying ozone oxidation and coagulation processes separately in UF membrane process. Therefore, it is considered possible to apply ozonation/coagulation as a pretreatment process for stable wastewater reuse by and then contributing to the reduction of fouling when calculating the optimal conditions for ozone oxidation and coagulation and then to applying them to membrane processes.

• KSBB Journal
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• v.15 no.2
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• pp.134-138
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• 2000

Addition of carbon and nitrogen source to an alcohol distillery wastewater was tried to increase the cell concentration of a b baker's yeast cultivated in that wastewater. Carbon was found to be primary limiting nutrient and nitrogen secondary limiting o one. Glucose addition increased the cell concentration 1.3 times higher than no addition, and both glucose and $(NH_4)_2S0_4$ a addition did 5.8 times. A fed-batch cultivation by the automatic addition of glucose and ammonium was executed. Added g glu$\infty$se was automatically controlled to low concentration by a method using DO as control parameter. Ammonium was a automatically added as NH40H used as pH $\infty$ntrol agent after initiating glucose addition. By this simple cultivation method t the cell concentration $\infty$내d be efficiently increased from 2.6g/L to 12.0g/L, and maximum specific growth rate and biomass y yield to glu$\infty$se were $0.18hr^{-1}$ and about 0.54g/g respectively. By increasing cell concentration, COD of the wastewater m media could be additionally reduced by about 22%.

• Journal of Korean Society on Water Environment
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• v.22 no.1
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• pp.51-58
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• 2006

The effluent limitations for individual industry based on the best available technology economically achievable (BAT) have been required to achieve effective regulation. BAT assessment criteria that are suitable for the circumstances of Korean industry were developed in the previous study. The criteria were applied to determine the BAT for leather tanning and finishing industry. For the evaluation BAT, a subcategorization for the industry considering wastewater characteristics, source equipments, raw material and so on should be suggested. Three subcategories: A) Unharing, Chrome Tan, Retan-Wet Finish, B) Chrome Tan, Retan-Wet Finish, and C) Furskins were proposed in this study. Wastewater discharged from the each category contains high concentration of COD, chrome, nitrogen and sulfide. In particular, the concentration of nitrogen from the subcategory A is significantly greater. Twenty sites were surveyed and wastewater qualities were analyzed. Therefore, six different technologies were applied to the subcategory A for the end-of-pipe treatment technology, and a technology was used in the subcategory B and C, respectively. The technology candidates were evaluated in terms of environmental impacts, economically achievability, treatment performance and economical reasonability. As the result, the technology options for each subcategories: A) primary chemical precipitation + modified Ludzack-Ettinger process (MLE) + secondary chemical precipitation, B) chemical precipitation + typical activated-sludge process + Fenton oxidation, C) chemical precipitation + typical activated-sludge process + batch Fenton oxidation or batch activated carbon treatment were selected as the BAT, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.2
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• pp.295-302
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• 2012

The coagulation of combined sewer overflows ($CSO_{s}$) was investigated by jar-testing with several commercial coagulants. $CSO_{s}$ sample showed different characteristics of coagulation from secondary wastewater with three common coagulants, aluminum sulfate, ferric chloride and polyaluminum chloride (PACl). Jar-tests showed that relatively wide range of optimal SS and T-P removal yielded with alum and ferric chloride compared with cationic polymers, though efficient SS and T-P removal can be achieved with all three coagulants. The decrease of pH was caused by the increase in dosage of aluminum sulfate, ferric chloride and PACl as coagulants. The pH was changed from 7.0 to 4.7 with the dosages of ferric chloride 25 mL/L. Aluminum sulfate revealed pH of 5.0 and PACl was highest pH of 5.4 after dosing of coagulants. The optimal pH to treat $CSO_{s}$ with aluminum sulfate were 6-6.5; with PACl 6-7, and with ferric chloride higher than 7.

• Journal of Korean Society on Water Environment
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• v.20 no.2
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• pp.132-144
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• 2004

The purpose of this study was to evaluate alternatives for stable operation of WWTP(Wastewater Treatment Plant) with a higher rate of inflows and a higher concentration of pollutants during wet weather to minimize the pollution loads being discharged into receiving waters. 3Q(Q: dry weather flow) of a base flow is normally intercepted and flows into WWTP as it was current practice. It is revealed by simulation that the bypassing alternative of 1Q through secondary treatment and 2Q into the stream after primary treatment was as good as it is expected. The bypass pollution loads were in the range of 23.9 ~ 38.5 % of the total loads flowing into the WWTP indicating that the bypassed flows need an extra treatment such as stormwater detention reservoir, high-rate coagulation with sedimentation, and step-feed. The high-rate coagulation with sedimentation was the most effective with respect to removal of the pollution loads.

• Journal of Environmental Health Sciences
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• v.30 no.1
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• pp.50-58
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• 2004

The present study was designed to evaluate primary production organic matter in basin of lake around by execution of total maximum daily loading. BOD influent loading of Uiam lake was 2,819 kg/day, which was less then 28.3 percent, total effuluent loading as 3,619 kg/day, in comparision with BOD, total nitrogen influent loading was 4,681 kg/day, which was less then 10.0 percent, total effuluent loading as 5,150 kg/day. But in case of total phosphors influent loading was 73.3 kg/day, which was more then 34.2 percent, total run off loading as 48.3 kg/day. The result of survey reduction plan of primary production organic matter in basin of lake around which objectives of abstract is as follows. First plan was reduction of primary production organic matter by moving the outlet of municipal wastewater treatment center from present place to lake downstream. Secondary plan was improvement by diffusion type of outlet municipal wastewater treatment center. The third plan was reduction of environmental impact by passing and storing of municipal wastewater. Finally plan was decline water surface level which was present hydrouric retention time was reduction from 7.6 day to 6.0 day per meter.