• 제목/요약/키워드: secondary materials

검색결과 1,920건 처리시간 0.031초

Surface Characterization of Carbon Fibers as Anode Materials for Li Secondary Batteries

  • Takamura, Tsutomu;Awano, Hidekazu;Ura, Tetsuya;Ikezawa, Yasunari
    • 분석과학
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    • 제8권4호
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    • pp.583-590
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    • 1995
  • Pitch-based mesophase carbon fibers prepared at different temperatures were heat-treated at temperatures lower than those of the preparation and the electrochemical Li doping/undoping characteristics were evaluated in relation to the data of IR, mass, etc. Presence of surface hydroxyls were confirmed by FTIR for lower temperature sample which showed poor anode characteristics. Upon oxidative heating, removal of surface hydroxyls took place, resulting in a remarkable improvement of the electrode characteristics. At the same time, surface roughening took place, which was confirmed by SEM and double layer capacity measurements. In situ mass spectra obesrved during the heat-treatments showed gas evolution of $H_2O$, CO, $CO_2$, $C_2H_4$, and/or $H_2$ depending on the conditions. These data together with those of weight loss and conductivity provided us a valuable information in regard to the evaluation of the electrochemical characteristics.

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Factors Associated with Use and Types of Multiple Concurrent Care and Education Arrangements in Early Childhood in South Korea

  • An, Miyoung
    • International Journal of Human Ecology
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    • 제15권2호
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    • pp.81-92
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    • 2014
  • This paper explores factors associated with multiple concurrent care and education arrangements in early childhood in South Korea. It draws on a subsample from the Korean Longitudinal Survey of Women and Families. Results show that about one-fifth of the families utilized multiple arrangements for their first preschool child. The primary non-parental option in multiplicity was nurseries or kindergartens. Home care and education options such as home study materials were found to be most prevalent secondary non-parental option, followed by services at private institution as well as relative care. Children's age, care cost, non-parental care time and time constraints were found to be positively related to the incidence of multiplicity for the first preschool child while family income and cost constraints were negatively associated. As a secondary option in the multiplicity, services at private institutions increased with children's age, care cost and when the grandparents live far from the parents' house. Home care and education utilization was found more among mothers with low degree of time constraints. Utilization of relative support decreased with the children's age and meant lower care cost and increased with mother's employment, fathers' education, family income, cost constraints and when grandparents live nearby. This paper, based on the associated factors, suggests how issues of children enrichment and constraints might be related to the multiplicity.

Electrochemical Performance of Spherical LiCoO2 Powders Synthesized Using Ultrasonic Spray Pyrolysis Method (I) : Effect of Pyrolysis Conditions on Powder Characteristics

  • Kim, Seon-Hye;Choa, Yong-Ho;Shim, Kwang-Bo;Cho, Byung-Won;Kim, Chang-Sam
    • 한국세라믹학회지
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    • 제41권11호
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    • pp.793-796
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    • 2004
  • Process Parameters were studied in synthesis of LiCoO$_2$ Powder by ultrasonic spray Pyrolysis. Concentration of the mixed solution influenced the size, shape, and yield of the synthesized powder. The yield was affected primarily by the height of the solution, and then by the flow rate of a carrier gas. The temperature of the reactor governed the crystallinity and morphology of the powder. LiCoO$_2$ powders were synthesized as a layered high temperature phase above 800$^{\circ}C$. The synthesized powders were sphere and secondary Particles consisted of primary particles of 55-70 nm. The secondary Particles became bigger from 0.28 to 1.43 $\mu\textrm{m}$ as the concentration of the solution was increased from 0.05 to 2.0 M. The 2.0 M solution provided the highest production rate.

중등 환경 교과서의 환경 소양 요소 분석 (Analysis of Environmental Literacy Components for Secondary School Environmental Education Textbooks)

  • 이기영;손연아;신동희
    • 한국환경교육학회지:환경교육
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    • 제19권3호
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    • pp.80-92
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    • 2006
  • The purpose of this study was to make valuable suggestions for improving environmental education(EE) teaching materials. For the purpose of this study, we analyzed four secondary school EE textbooks in the perspective of environmental literacy components. The findings of this study are as follows: (1) As a whole, the EE textbooks tend to focus the understanding environmental knowledge much more than environmental activities. (2) In 'main text' domain of EE textbooks, environmental information, including environmental issue knowledge, is much more focused than environmental attitudes and behavior, including socio-political and environmental issue knowledge. (3) In 'graphic data' domain, environmental information about environmental issue knowledge was most prevalent. (4) Most learning activities focus on 'issue skill' component, rather than 'attitude' and 'action' component. (5) The objectives of EE in the 7th national Curriculum were not explicitly embedded in textbooks and too much is inclined toward 'knowledge' and 'skill'. Accordingly, it is necessary to develop 'module-type' EE textbooks to enable integrative EE. Also, it is suggested to develop specific strategies for linking environmental knowledge and attitude/behavior.

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마그네시아와 돌로마이트의 특성에 미치는 $Fe_2O_3$ 의 첨가영향 (Effects of $Fe_2O_3$ Addition on the Properties of MgO and Dolomite)

  • 박재원;홍기곤
    • 한국세라믹학회지
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    • 제34권7호
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    • pp.738-746
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    • 1997
  • MgO clinker and two kinds of dolomite clinkers with different microstructures and CaO contents were used as starting materials, and the effects of Fe2O3 addition on the properties of MgO and dolomite were investigated in the range of 2 to 8 wt% of Fe2O3 content. Secondary phases contributed to densification of MgO-Fe2O3 and dolomite-Fe2O3 were magnesioferrite and dicalciumferrite, respectively. Sinterabilities of MgO-Fe2O3 and dolomite-Fe2O3 were directly proportional to the amount of secondary phases. Also, sinterability of dolomite itself was dependent on the microstructure of starting material including distribution of CaO and MgO as well as the addition amount of Fe2O3. The flexural strength of MgO-Fe2O3 content was almost constant. The hydration resistance of dolomite with large size of MgO and discontinuous distribution of CaO was higher than that of dolomite with small size of MgO and continuous distribution of CaO. Also, the minimum content of Fe2O3 to prevent they hydration of dolomite was about 4wt%. As increasing Fe2O3 content, the penetration resistance of MgO-Fe2O3 was improved by the increment of magnesioferrite. On the other hand, the penetration resistance of dolomite-Fe2O3 was decreased because of the increment of dicalciumferrite having low melting point.

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철부식생성물 저감을 위한 고온 pH(t) 상향 연구 (Study on Increasing High Temperature pH(t) to Reduce Iron Corrosion Products)

  • 신동만;허남용;김왕배
    • Corrosion Science and Technology
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    • 제10권5호
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    • pp.175-179
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    • 2011
  • The transportation and deposition of iron corrosion products are important elements that affect both the steam generator (SG) integrity and secondary system in pressurized water reactor (PWR) nuclear power plants. Most of iron corrosion products are generated on carbon steel materials due to flow accelerated corrosion (FAC). The several parameters like water chemistry, temperature, hydrodynamic, and steel composition affect FAC. It is well established that the at-temperature pH of the deaerated water system has a first order effect on the FAC rate of carbon steels through nuclear industry researches. In order to reduce transportation and deposition of iron corrosion products, increasing pH(t) tests were applied on secondary system of A, B units. Increasing pH(t) successfully reduced flow accelerated corrosion. The effect of increasing pH(t) to inhibit FAC was identified through the experiment and pH(t) evaluation in this paper.

중등 교사와 학생의 환경 교육 교재에 대한 의견 분석 (Secondary Teachers' and Students' Opinion on Environmental Education Textbooks)

  • 신동희;손연아;고희령;이기영;이동엽
    • 한국환경교육학회지:환경교육
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    • 제19권1호
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    • pp.64-79
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    • 2006
  • This study was designed to make valuable suggestions for the development of environmental education(EE) teaching materials through teachers' and students' opinions. In the summer of 2005, an opinionnaire was sent to 1,749 secondary school EE teachers and 270 teachers of them answered. One hundred and six middle school students and 196 high school students in Kyunggi area were also participated in this survey. The opinionnaire in this study was based on the six standards, fairness and accuracy, depth, emphasis on skill building, action orientation, instructional soundness, and usability, developed by NAAEE(1998). Most teachers were totally dependent on textbooks in their teaching EE. They evaluated current EE textbooks most positively in the perspective of 'fairness and accuracy', whereas they evaluated them most negatively in the perspective of 'usability'. The problems of EE textbooks were differently recognized by teachers and students. The lack of contents stimulating students' interest was considered as the most serious problem of EE textbooks by students. Simultaneously, it was considered as the least serious problem of EE textbooks by teachers. Both EE teachers and students expect the future EE textbooks would consist of proper contents to reflect EE characteristics.

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해양에서 열화된 완도선 수침고목재의 화학적.미시형태적 변화 (Chemical and micromorphological changes of archaeological waterlogged wood degraded in marine situations.)

  • 김익주
    • 보존과학연구
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    • 통권11호
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    • pp.87-105
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    • 1990
  • Chemical and micro morphological changes of archaeological waterlogged woods from shipwrecked materials in marine situations were investigated which were submerged in seabed for over 900 years. Tested Wood species were Pinusdensiflora, Zelkova serrata, Quercus acutissima and Camellia japonica. The obtained results were summarized as follows; Chemical analysis showed that lignin content was increased, whereas the amout of holocellulose was heavily decreased in the degraded archaeological lwoods(DAW), when compared to the recent woods. The amount of alkalineextractives in the DAW was extremley high. IR spectra showed that disappearance of absortion band at $1,730㎝^-1$ intensity increase at 1,600, 1,500 and $1,270㎝^-1$ and the emergence of single band around $1,050㎝^-1$.Microscopic investigation showed that cell wall of latewood tracheids and fiber in the DAW were severely degraded while, early wood tracheids less degraded. Degradation in the cell wall was mainley occurred in $S_2$layer, while the middle lamella was the least degraded. The micro morphological characteristics of DAW were separation of secondary wall from middle lamella, cavities aligned with micro fibril angle in $S_2$layer and granular appearance of secondary wall by the bacterial attack.

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음향방출법에 의한 항공기용 가스터빈 재료의 크리프 수명예측 평가 (Evaluation on Creep Life Prediction of Aircraft Gas Turbine Material by AE)

  • 공유식;윤한기;오세규
    • 동력기계공학회지
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    • 제6권1호
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    • pp.55-60
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    • 2002
  • There has been no report on the life prediction for gas turbine materials at high temperatures based on the creep properties and their relationship with the AE(acoustic emission) properties as a means of real-time non-destructive testing. One of the important issues is thus to develop a reliable method of evaluating creep properties by the AE technique. In this paper, the real-time evaluation of high temperature creep time and AE cumulative counts for nickel-based superalloy Udimet 720 was performed on round-bar type specimens under pure load at the temperatures of 811, 922 and 977K. The total AE cumulative counts until the starting point of secondary creep($N_1$) and that of tertiary creep($N_2$) have quantitative relationship with the tertiary creep time and the rupture time. It is thus possible to construct the life prediction system based on creep and the prevention system of tertiary creep by using AE technique.

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중국 뢰스의 나노 방해석 (Nanosized Calcite in the Chinese Loess)

  • 정기영
    • 한국광물학회지
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    • 제20권4호
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    • pp.255-260
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    • 2007
  • 중국 서부에 분포하는 황토대지의 뢰스(loess)는 아시아 내륙에서 발생하는 광물먼지의 퇴적물일 뿐만 아니라, 우리나라 봄철 황사의 기원물질이기도 하다. 간빙기의 뢰스는 퇴적 후에 고토양으로 풍화되는 과정에서 풍성 일차 탄산염 광물 입자들이 용해되어 이차 탄산염광물로 재침전된다. 뢰스 및 고토양의 광물학적 분석에 의하면 풍성 탄산염 입자는 대부분 실트 크기이나, 재침전된 이차 탄산염광물은 너비가 $30{\sim}50nm$ 정도로 일정하고 다양한 길이를 갖는 나노 크기의 방해석들이었다. 나노방해석은 황토대지에서 점토광물과 함께 실트질 뢰스와 고토양의 세립 기질을 구성하는 주요 자생 광물로서, 우리나라에서 채집된 황사 입자에서 확인된 나노 방해석들의 기원물질로 해석된다.