• Title/Summary/Keyword: secondary materials

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A study on structural analysis of GRINDING DISC ASS'Y for secondary battery material decompositiom (이차전지 원료 해쇄용 GRINDING DISC ASS'Y 구조해석에 대한 연구)

  • Yun, Dong-Min;Jeon, Yong-Han
    • Design & Manufacturing
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    • v.16 no.1
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    • pp.36-42
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    • 2022
  • Globally, as population growth and economic development continue, resource consumption is increasing rapidly. As an alternative to electric vehicles was suggested as the environmental pollution problem emerged, the number of registered electric vehicles in Korea increased by more than 137 times compared to 2013. Secondary batteries are expected to expand into various markets such as small IT devices and electric vehicles, and the most important part of electric vehicles is the battery (secondary battery). Therefore, in this study, to analyze the stability of the CSM (Classifier Separator Mill) grinding disc that crushes secondary battery raw materials, structural analysis and vibration analysis of the 1st to 4th grinding discs and the final model were performed. The change of bending by the weight of the Grinding Disc is at least 0.065㎛ and maximum 0.075㎛, and the change by the standard gravity is judged to be very low. The strain is at least 0.00031㎛/㎛ and maximum 0.00078㎛/㎛, and even if the number of Hamer increases, the change by the weight is judged to be insignificant. When the Grinding Disc rotates at a maximum of 6000rpm, the deformation and deformation rate of the first to third models are similar, but the fourth model (Hamer 10EA) is more than three times and the final model (Hamer 12EA) is about four times. However, the maximum deformation is 28.21㎛, which is considered to be insignificant when the change is 6000rpm. Six modes of natural Frequency analysis of the 1st~4th order and final model of the grinding disc appeared to be bent or twisted.

Experimental Debonding Failure Behaviors of Composite Skin-Stiffener Bonded Specimens (복합재료 스킨-보강재 접합 시편의 파손 특성에 대한 시험 연구)

  • Kim, Kwang-Soo;An, Jae-Mo;Jang, Young-Soon;Yi, Yeong-Moo
    • Composites Research
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    • v.20 no.6
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    • pp.8-14
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    • 2007
  • Debonding failure characteristics of the composite skin-stiffener specimens were experimentally investigated. The influences of bonding methods, types of stiffener shape and various secondary bonding parameters were evaluated. Present test results combined with the previous test results[1] showed that the failure displacement of the skin-stiffener specimens well evaluates the skin-stiffener debonding failure strength of the composite stiffened panels. The specimens with an open type stiffener had lower bending stiffness and larger failure displacement than those with a closed type stiffener. Secondary bonding and co-curing with adhesive had better failure strength than co-curing without adhesive film. Secondary bonded specimens failed by adhesive failure and co-cured specimens failed by delamination failure. As the bondline thickness was thinner, the skin-stiffener specimens had higher failure strength. The fillets had no influence on failure strength of the specimens. The influence of the surface roughness was shown according to types of stiffener shape.

Development of Instruction Materials for Underachieving Students to Correction of Misconception (수학 학습 부진 학생을 위한 오개념 교정 지도 자료 개발 연구)

  • Choe, Seung Hyun;Nam, Geum Cheon;Ryu, Hyunah
    • Journal of Educational Research in Mathematics
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    • v.23 no.2
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    • pp.117-133
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    • 2013
  • Mathematical misconception is one of the big obstacles of the underachieving students to learn mathematics correctly. This study aims to develop the instruction materials for secondary school students who are underachieving in mathematics to reduce the occurrence of the misconception and to help them to build the correct concept in the mathematical learning. Before developing the material, we tried to collect the misconception cases occurring in common mathematics lesson. This materials tries to provide key educational contents for mathematics teachers who is responsible for teaching underachieving student and help them to creative interesting ideas for lessons. The materials could be used not only as an teaching materials for underachieving students or students with the misconceptions, but also could be used as training materials for mathematics teachers.

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Characteristics of Indium Tin Zinc Oxide Thin Film Transistors with Plastic Substrates (고분자 기판과 PECVD 절연막에 따른 ITZO 박막 트랜지스터의 특성 분석)

  • Yang, Dae-Gyu;Kim, Hyoung-Do;Kim, Jong-Heon;Kim, Hyun-Suk
    • Korean Journal of Materials Research
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    • v.28 no.4
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    • pp.247-253
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    • 2018
  • We examined the characteristics of indium tin zinc oxide (ITZO) thin film transistors (TFTs) on polyimide (PI) substrates for next-generation flexible display application. In this study, the ITZO TFT was fabricated and analyzed with a SiOx/SiNx gate insulator deposited using plasma enhanced chemical vapor deposition (PECVD) below $350^{\circ}C$. X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS) results revealed that the oxygen vacancies and impurities such as H, OH and $H_2O$ increased at ITZO/gate insulator interface. Our study suggests that the hydrogen related impurities existing in the PI and gate insulator were diffused into the channel during the fabrication process. We demonstrate that these impurities and oxygen vacancies in the ITZO channel/gate insulator may cause degradation of the electrical characteristics and bias stability. Therefore, in order to realize high performance oxide TFTs for flexible displays, it is necessary to develop a buffer layer (e.g., $Al_2O_3$) that can sufficiently prevent the diffusion of impurities into the channel.

The Effects of Sodium Doping on the Electrical Properties of the Cu2ZnSn(S,Se)4 (CZTSSe) Solar Cells (용액법을 이용한 나트륨 도핑에 따른 Cu2ZnSnSe4 (CZTSSe) 박막의 합성 및 특성 평가)

  • Shim, Hongjae;Kim, Jihun;Gang, MyungGil;Kim, Jinhyeok
    • Korean Journal of Materials Research
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    • v.28 no.10
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    • pp.564-569
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    • 2018
  • $Cu_2ZnSn(S,Se)_4$ (CZTSSe) films were prepared on Mo coated soda lime glass substrates by sulfo-selenization of sputtered stacked Zn-Sn-Cu(CZT) precursor films. The precursor was dried in a capped state with aqueous NaOH solution. The CZT precursor films were sulfo-selenized in the S + Se vapor atmosphere. Sodium was doped during the sulfo-selenization treatment. The effect of sodium doping on the structural and electrical properties of the CZTSSe thin films were studied using FE-SEM(field-emission scanning electron microscopy), XRD(X-ray diffraction), XRF(X-ray fluorescence spectroscopy), dark current, SIMS(secondary ion mass spectrometry), conversion efficiency. The XRD, XRF, FE-SEM, Dark current, SIMS and cell efficiency results indicated that the properties of sulfo-selenized CZTSSe thin films were strongly related to the sodium doping. Further detailed analysis and discussion for effect of sodium doping on the properties CZTSSe thin films will be discussed.

Solvent Extraction Separation of Co, Mn and Zn from leaching solution from Ni-Cd battery by Na-PC88A

  • Ahn Jong-Gwan;Park Kyoung-Ho;Sohn Jeong-Soo;Kim Dong-Jin;Lee Jaereyeong;Jeong HunSaeong
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.618-623
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    • 2003
  • Solvent extraction experiments for separation of impurities from Ni-rich solution were carried out for manufacturing of high purity Ni compounds from acid leaching solution of spent Ni-Cd secondary battery. Artificial and leaching solutions were used as aqueous phases and PC88A saponified by sodium in kerosene were used as organic phase. The extraction order is Zn>Mn>Co>Ni and extraction percentage of metal ions was increased with increase of the concentration of extractant, initial pH of aqueous phase and ratio of O/A. The separation of cobalt, zinc and manganese from nickel was effectively accomplished at the condition of extraction stage=l, O/A=1 and initial pH 5.0 with 1.0 $mol/dm^3$ PC88A saponified to $50\%$ with NaOH.

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Enhancement in Piezoelectric Properties of PZT-Based Ceramics by High Energy Ball-Milling Treatment of Solid-State Synthesized Powders

  • Kim, Dae-Uk;Lee, Han-Bok;Hung, Nguyen Viet;Pham, Ky Nam;Han, Hyoung-Su;Lee, Jae-Shin
    • Journal of Powder Materials
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    • v.17 no.5
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    • pp.404-408
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    • 2010
  • The effects of high energy ball-milling (HEBM) on the sintering behavior and piezoelectric properties of 0.1 wt% $Li_2CO_3$ doped 0.8Pb($Mg_{1/3}Nb_{2/3}$)$O_3$-0.2Pb($Zr_{0.475}Ti_{0.525}$)$O_3$ (PMN-PZT) ceramics were investigated. It was found that HEBM treatment was quite effective to reduce the average particle size down to 300 nm, leading to increased density as well as enhanced piezoelectric properties of a sintered specimen even though prolonged HEBM resulted in unwanted secondary phases that caused a degradation of piezoelectric properties. The dielectric constant ($\varepsilon_r$), piezoelectric coupling factor ($k_p$) and piezoelectric constant $d_{33}$ of 0.1 wt% $Li_2CO_3$ doped PMN-PZT ceramics prepared via HEBM for 10 h reached 2040, 0.68 and 554 pC/N, respectively.

Development of Learning Materials on Constructibility of Roots of Cubic Polynomials (삼차방정식 해의 작도(불)가능성에 대한 학습 자료 개발)

  • Shin, Hyunyong;Han, Inki
    • Communications of Mathematical Education
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    • v.30 no.4
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    • pp.469-497
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    • 2016
  • In this research, we develop a systematic learning the materials on constructibility of cubic roots. We propose two sets of materials: one is based on concepts of field, vector space, minimal polynomial in abstract algebra, another based on properties of cubic roots in elementary algebra. We assess the validity, applicability, defects and merits of developed materials through prospective teachers, in-service teachers, and professionals. It could be expected that materials be used for advanced secondary students, mathematics majoring college students and mathematics teachers. Furthermore, we may expect the materials be useful for understanding and solving the (un)constructibility problems.

Microstructure Characteristics and Electrical Properties of Sintered $(Bi,La)_4Ti_3O_{12}$ Ferroelectric Ceramics

  • Yoo, H.S.;Son, Y.H.;Hong, T.W.;Ur, S.C.;Ryu, S.L.;Kweon, S.Y.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.533-534
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    • 2006
  • 1mm-thick BLT ceramics were sintered in accordance with a bulk ceramic fabrication process. All XRD peaks detected in the sintered ceramics were indexed as the Bi-layered perovskite structure without secondary phases. Density was increased with increasing the sintering temperature up to $1050\;^{\circ}C$ and the maximum value was about 98% of the theoretical density. The remanent polarization (2Pr) value of BLT ceramic sintered at $1050\;^{\circ}C$ was approximately $6.5\;{\mu}C/cm^2$ at the applied voltage of 4.5kV. From these results, a BLT ceramic target for plused laser deposition (PLD) system was successfully fabricated.

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Thermal Stability Analysis of 2-D Spacecraft Appendage (위성체 2-D 구조물의 열 안정성 해석)

  • 윤일성;송오섭;김규선
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.99-104
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    • 2001
  • Thermally induced vibration response of solar array is investigated. The solar array model consists of composite thin walled beam and solar blanket, spreader bar. The composite thin walled beam incorporates a number of nonclassical effects of transverse shear, primary and secondary warping, rotary inertia and anisotropy of constituent materials. The solar blanket is a membrane subjected to uniform tension in the z direction. The spreader bar is a rigid member. A coupled thermal structure analysis that includes the effects of structural deformations on heating and temperature gradient is investigated. A stability criterion given in parameters for establishes the conditions for thermal flutter.

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