• Title/Summary/Keyword: secondary materials

Search Result 1,911, Processing Time 0.038 seconds

P-M interaction curve for reinforced concrete columns exposed to elevated temperature

  • Kang, Hyun;Cheon, Na-Rae;Lee, Deuck Hang;Lee, Jungmin;Kim, Kang Su;Kim, Heung-Youl
    • Computers and Concrete
    • /
    • v.19 no.5
    • /
    • pp.537-544
    • /
    • 2017
  • The strength and deformational capacity of slender reinforced concrete (RC) columns greatly rely on their slenderness ratios, while an additional secondary moment (i.e., the $P-{\delta}$ effect) can be induced especially when the RC column members are exposed to fire. To evaluate the fire-resisting performances of RC columns, this study proposed an axial force-flexural moment (i.e., P-M) interaction curve model, which can reflect the fire-induced slenderness effects and the nonlinearity of building materials considering the level of stress and the magnitude of temperature. The P-M interaction model proposed in this study was verified in detail by comparing with the fire test results of RC column specimens reported in literature. The verification results showed that the proposed model can properly evaluate the fire-resisting performances of RC column members.

Effect of $Li_4Ti_5O_{12}$ coating layer on capacity retention of $LiMn_2O_4$ as cathode materials of lithium ion secondary batteries for HEV application (HEV용 리튬 이차전지 양극물질 $LiMn_2O_4$$Li_4Ti_5O_{12}$ 코팅에 따른 영향)

  • Wai, Yin-Loo;Choi, Byung-Hyun;Jee, Mi-Jung;Lee, Dae-Jin;Shin, Jae-Su;Song, Kwang-Ho
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.11a
    • /
    • pp.125-128
    • /
    • 2007
  • In these recent years, low cost and stable battery electrode materials have been studied for HV/HEV application. Spinel cathode material $LiMn_2O_4$ is widely studied as a promising cathode material of lithium ion secondary batteries because of it is low cost, easily to be prepared and capable to be operated in high voltage range. In this study, $LiMn_2O_4$ was undergoing surface modification with spinel lithium titanium oxide by sol-gel method in order to enhance its capacity retention. Properties of both unmodified and surface-modified $LiMn_2O_4$ were characterized by XRD, SEM, particle size analyzer while their cycling performance was tested with charge and discharge tester.

  • PDF

Modeling and Applications of Electrochemical Impedance Spectroscopy (EIS) for Lithium-ion Batteries

  • Choi, Woosung;Shin, Heon-Cheol;Kim, Ji Man;Choi, Jae-Young;Yoon, Won-Sub
    • Journal of Electrochemical Science and Technology
    • /
    • v.11 no.1
    • /
    • pp.1-13
    • /
    • 2020
  • As research on secondary batteries becomes important, interest in analytical methods to examine the condition of secondary batteries is also increasing. Among these methods, the electrochemical impedance spectroscopy (EIS) method is one of the most attractive diagnostic techniques due to its convenience, quickness, accuracy, and low cost. However, since the obtained spectra are complicated signals representing several impedance elements, it is necessary to understand the whole electrochemical environment for a meaningful analysis. Based on the understanding of the whole system, the circuit elements constituting the cell can be obtained through construction of a physically sound circuit model. Therefore, this mini-review will explain how to construct a physically sound circuit model according to the characteristics of the battery cell system and then introduce the relationship between the obtained resistances of the bulk (Rb), charge transfer reaction (Rct), interface layer (RSEI), diffusion process (W) and battery characteristics, such as the state of charge (SOC), temperature, and state of health (SOH).

The Development of Evaluating Framework for a Science Textbook in a Secondary School (과학 교과서 선정과 평가에 관련된 교사들의 인식조사와 과학 교과서 평가틀 개발에 관한 연구)

  • Choi, Kyung-Hee;Kim, Sook-Jin
    • Journal of The Korean Association For Science Education
    • /
    • v.16 no.3
    • /
    • pp.303-313
    • /
    • 1996
  • The major purpose of this thesis is to construct the evaluating framework of a science textbook with a high confidence and universal validity, referring to a preceeding study and materials involved in research work, and in consideration of the educational conditions of the secondary school. The framework developed in this study are composed of 7 categories: content, organization, representation, laboratory, illustrations, external form or editing system, and supplementary materials. Each category consists of detailed items. Eech item in the check-list is to be given between one and five points, and the total number of possible points in this evaluating framework is 290. As a result, these evaluating items enable quantitative analyses, afford an opportunity which we can look into many-sidedly the respects we should consider when a science textbook is adopted, and they can be estimated partly or synthetically as occasional demands. This study is exepected to contribute to choose a good science textbook as fundamental data in the future, and to help the lasting study or estimation of the textbook.

  • PDF

A Study on the Mechanical Properties of Al-8.6% Si-3.6% Cu Alloy Cast in Plaster Mold (석고주조(石膏鑄造)한 Al-8.6% Si-3.6% Cu 합금(合金)의 기계적(機械的) 성질(性質)에 관(關)한 연구(硏究))

  • Yeo, In-Dong;Kim, Dong-Ok;Kang, In-Chan
    • Journal of Korea Foundry Society
    • /
    • v.4 no.4
    • /
    • pp.5-13
    • /
    • 1984
  • This paper is presented for showing the effect of cooling rate on dendrite arm spacing, correlated with the chilling power of molding materials (conventional plaster, foamed plaster, silica sand) and section thickness, and also showing relationship between dendrite arm spacing and mechanical properties for an aluminum - 8.6 percent silicon - 3.6 percent copper alloy. Local solidification time $(t_f)$ and secondary dendrite arm spacing (d) could be varied widely in accordance with the molding materials and casting thickness, and the following relationship is obtained: $d=9.4t_f\;^{0.31}$ A good correlation between dendrite arm spacing and mechanical properties such as ultimate tensile strength, yield strength, hardness was found, that is, mechanical properties decreased in a linear manner with increase in log of secondary dendrite arm spacing. Ultimate tensile strength in conventional plaster mold casting decreased by 15 percent comparing with the sand casting, where as in foamed plaster mold casting, it decreased by 30 percent comparing with the sand casting. From those results, it has been verified that DAS might be the most representative parameter for predicting mechanical properties varing with the different cooling condition.

  • PDF

Influences of Precipitation of Secondary Phase by Heat Treatment on Thermal Properties of Al-4.5%Cu Alloy (열처리에 따른 제2상 석출이 Al-4.5%Cu 합금의 열 물성에 미치는 영향)

  • Choi, Se-Weon
    • Korean Journal of Materials Research
    • /
    • v.30 no.8
    • /
    • pp.435-440
    • /
    • 2020
  • The relationship between the precipitation of secondary phase and the thermal properties of Al-4.5%Cu alloy (in wt.%) after various heat treatments has been studied. Solid solution treatment of alloy was performed at 808 K for 6 hours, followed by warm water quenching; then, the samples were aged in air at 473 K for different times. The thermal diffusivity of the Al-4.5%Cu alloy changed with the heat treatment conditions of the alloy at temperatures below 523 K. The as-quenched specimen had the lowest thermal diffusivity, and as the artificial aging time increased, the thermal diffusivity of the specimen increased in the temperature range between 298 and 523 K. For the specimen aged for five hours, the thermal conductivity was 12% higher than that of the as-quenched specimens at 298 K. It is confirmed that the thermal diffusivity and thermal conductivity of the Al-4.5%Cu alloy significantly depend on their thermal history at temperatures below 523 K. The precipitation and dissolution of the Al2Cu phase were confirmed via DSC for the alloys, and the formation of coefficient of thermal expansion peaks in TMA was caused by precipitation. The precipitation of supersaturated solid solution of Al-4.5%Cu alloys had an additional linear expansion of ≈ 0.05 % at 643 K during thermal expansion measurement.

SPECTROSCOPIC ANALYSIS OF THE R CANIS MAJORIS BINARY SYSTEM

  • A-THANO, N.;MKRTICHIAN, D.E.;KOMONJINDA, S.
    • Publications of The Korean Astronomical Society
    • /
    • v.30 no.2
    • /
    • pp.231-232
    • /
    • 2015
  • R Canis Majoris is a bright, short-period ($1^d$.1359) Algol-type eclipsing binary. For a long time, it was considered to be a low-mass binary star with $M_1=1.1M_{\odot}$ and $M_2=0.17M_{\odot}$ primary and secondary components, respectively (Tomkin, 1985). Glazunova, Yushchenko & Mkrtichian (2009) found new masses for the primary and secondary components of $M_1=1.81M_{\odot}$ and $M_2=0.23M_{\odot}$, respectively and resolved a long-standing problem with the low masses of components for this binary. Budding and Butland (2011) confirmed the results of Glazunova, Yushchenko & Mkrtichian and obtained improved orbits and masses. New spectroscopic observations of R CMa were done during 8 nights on December 2012 with the 2.4-meter telescope of the Thai National Observatory (TNO) and fibre-fed medium resolution echelle spectrograph. We obtained new, accurate orbital radial velocities of the two components of this binary system. Results of these investigations and the new orbital parameters are presented.

Quantitative Estimation of PM-10 Source Contribution in Gumi City by the Positive Matrix Factorization Model (PMF를 응용한 구미시 PM-10 오염원의 정량적 기여도 추정연구)

  • Hwang, In-Jo;Cho, Young-Hyuck;Choi, Woo-Gun;Lee, Hye-Moon;Kim, Tae-Oh
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.24 no.1
    • /
    • pp.100-107
    • /
    • 2008
  • The objective of this study was to quantitatively estimate PM-10 source contribution in Gumi City, Korea. Ambient PM-10 samples were collected by a high volume air sampler, which operated for 84 different days with a 24-h sampling basis, from June 14,2001 though May 19, 2003. The filter samples were analyzed for determining 13 inorganic elements, 3 anions, and a total carbon. The study has intensively applied a receptor model, the PMF (Positive Matrix Factorization) model. The results from PMF modeling indicated that a total of seven sources were independently identified and each source was contributed to the ambient Gumi City from secondary sulfate (34%), motor vehicle (26%), soil relation (5%), field burning (3%), industrial relation (3%), secondary nitrate (22%), and incinration (7%) in terms of PM-10 mass, respectively.

Technology for the Recovery of Os and Ru from Primary/Secondary Resources (1차(次)/2차(次) 자원(資源)으로부터 Os과 Ru 회수기술(回收技術))

  • Sun, Pan-Pan;Lee, Man-Seung
    • Resources Recycling
    • /
    • v.21 no.6
    • /
    • pp.3-11
    • /
    • 2012
  • Some methods used for the recovery of osmium and ruthenium from primary/secondary sources are reviewed. Both Ru and Os could form volatile oxides which enable their separation from the other PGMs by distillation as a traditional method. In hydrochloric acid solution, they also form chloro-complexes with different valence states. Amines or amine based mixture have been used to extract Ru. Solvating extractants are employed to separate Ru and Os. The detailed extraction and stripping conditions of several solvent extraction processes have been reviewed. As an alternative to solvent extraction, solid-liquid method can be applied to recover trace amount of these metals.

Crystallization Behavior and Electrochemical Properties of Si50Al30Fe20 Amorphous Alloys as Anode for Lithium Secondary Batteries Prepared by Rapidly Solidification Process (액체급랭응고법으로 제조된 리튬 이차전지 음극활물질용 Si50Al30Fe20 비정질 합금의 결정화 거동 및 전기화학적 특성)

  • Seo, Deok-Ho;Kim, Hyang-Yeon;Kim, Sung-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.32 no.4
    • /
    • pp.341-348
    • /
    • 2019
  • This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as $Fe_2Al_3Si_3$, $FeSi_2$, and $Fe_{0.42}Si_{2.67}$, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately $700mAh^{g-1}$, and exhibited a high Coulombic efficiency of 99.0~99.6% from the $2^{nd}$ to $70^{th}$ cycles.