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Synthesis of Highly Dispersed and Conductive Graphene Sheets by Exfoliation of Preheated Graphite in a Sealed Bath and its Applications to Polyimide Nanocomposites

  • Hossain, Muhammad Mohsin;Hahn, Jae Ryang;Ku, Bon-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2049-2056
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    • 2014
  • A simple method for exfoliating pristine graphite to yield mono-, bi-, and multi-layers of graphene sheets as a highly concentrated (5.25 mg/mL) and yielded solution in an organic solvent was developed. Pre-thermal treatment of pristine graphite at $900^{\circ}C$ in a sealed stainless steel bath under high pressures, followed by sonication in 1-methyl-2-pyrrolidinone solvent at elevated temperatures, produced a homogeneous, well-dispersed, and non-oxidized graphene solution with a low defect density. The electrical conductivities of the graphene sheets were very high, up to 848 S/cm. These graphene sheets were used to fabricate graphene-polyimide nanocomposites, which displayed a higher electrical conductivity (1.37 S/m) with an improved tensile strength (95 MPa). The synthesized graphene sheets and nanocomposites were characterized by transmission electron microscopy, scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy.

Containment Evaluation of the KN-12 Transport Cask

  • Chung, Sung-Hwan;Choi, Byung-Il;Lee, Heung-Young;Song, Myung-Jae
    • Journal of Radiation Protection and Research
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    • v.28 no.4
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    • pp.291-298
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    • 2003
  • The KN-12 transport cask has been designed to transport 12 PWR spent nuclear fuel assemblies and to comply with the regulatory requirements for a Type B(U) package. The containment boundary of the cask is defined by a cask body, a cask lid, lid bolts with nuts, O-ring seals and a bolted closure lid. The containment vessel for the cask consists of a forged thick-walled carbon steel cylindrical body with an integrally-welded carbon steel bottom and is closed by a lid made of stainless steel, which is fastened to the cask body by lid bolts with nuts and sealed by double elastomer O-rings. In the cask lid an opening is closed by a plug with an O-ring seal and covered by the bolted closure lid sealed with an O-ring. The cask must maintain a radioactivity release rate of not more than the regulatory limit for normal transport conditions and for hypothetical accident conditions, as required by the related regulations. The containment requirements of the cask are satisfied by maintaining a maximum air reference leak rate of $2.7{\times}10^{-4}ref.cm^3s^{-1}$ or a helium leak rate of $3.3{\times}10^{-4}cm^3s^{-1}$ for normal transport conditions and for hypothetical accident conditions.

Efficient MQL-based Drilling of Inconel 601 (인코넬 601의 효율적인 MQL드릴링 가공)

  • Park, Ki-Beom;Cho, Young-Tae;Jung, Yoon-Gyo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.4
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    • pp.1-8
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    • 2018
  • In drilling Inconel 601, which is used for compressor cases in aircraft engines, a lot of cutting oil must be supplied. This prevents tools from wear and fracture due to the heat buildup resulting from the high-temperature resistance and toughness of this alloy. However, the cutting oil supply has compromised the machining environment. This has caused attention to shift to an environmentally friendly cutting fluid supply system called the Minimum Quantity Lubrication(MQL) system. The aim of this study was to find a more efficient drill processing method using MQL and to verify its performance. To that end, the properties of Inconel that make it difficult -to -drill were studied by a comparison with the drilling of SM45C. Specific factors (i.e., cutting force and tool wear) were examined in relation to the conditions in the MQL-based drilling system. Based on these results, a sealed cover and step feed were proposed as measures to increase the effectiveness of the MQL system. The efficiency of the proposed method was established.

The Effects of Surface Oxidation Occurring during Delivery from an Annealing Furnace to a Water Bath on the Microstructure and Tensile Properties of TWIP Steel (소둔로에서 수욕으로 이송 중 발생한 표면 산화가 TWIP 강의 미세조직과 인장 성질에 미치는 영향)

  • Oh, Seon-Keun;Lee, Young-Kook
    • Journal of the Korean Society for Heat Treatment
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    • v.33 no.2
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    • pp.57-64
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    • 2020
  • In the present study, we investigated whether the surface oxidation of C-bearing TWIP steel ℃curs in the air during specimen delivery from an annealing furnace to a water bath and how the microstructure and tensile properties are influenced by surface oxidation. A cold-rolled Fe-18Mn-0.6 (wt%) steel was exposed in the air for 5 s after annealing at various temperatures (750℃, 850℃ and 1000℃) for 10 min in a vacuum, and then water-quenched. For comparison, another specimen, which had been quartz-sealed in a vacuum, was annealed at 1000℃ for 10 min and immediately water-quenched without exposure to air. The 750℃ and 850℃-annealed specimens and the quartz-sealed specimen showed a γ-austenite single phase in the entire specimen due to negligible surface oxidation. However, the 1000℃-annealed specimen exhibited a dual-phase microstructure consisting of ε-martensite and γ-austenite at the sub-surface due to decarburization. Whereas the specimens without decarburization revealed high elongations of 70-80%, the decarburized specimen exhibited a low elongation of ~40%, indicating premature failure due to cracking inside the decarburized layer with ε-martensite and γ-austenite.

Analysis of Strength Characteristic for Bottom Ash Mixtures as Mixing Ratio and Curing Methods (Bottom Ash와 혼합재료의 혼합비 및 양생방법에 따른 강도특성 분석)

  • Choi, Woo-Seok;Son, Young-Hwan;Park, Jae-Sung;Noh, Soo-Kack;Bong, Tae-Ho
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.3
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    • pp.129-140
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    • 2013
  • Bottom Ash is industrial by-product from a thermoelectric power plant. An immense quantities of bottom ash have increased each year, but most of them is reclaimed in ash landfill. In this study, in order to raise recycling rate of Bottom Ash, it is suggested to cure Bottom Ash (BA) mixtures mixed with cement, lime, Fly Ash (FA), and oyster shell (OS). Mixtures of 5~20 % mixing ratio had been cured for 1, 3, 7, 14, and 28 days using sealed curing and air-dry curing method. Unconfined compressive strength test was conducted to determine strength and deformation modulus ($E_{50}$) change for mixtures as mixing ratio and curing day, water contents of mixtures were measured after test. As a result, strength and $E_{50}$ were increased as mixing ratio and curing days, but values and tendencies of them appeared in different as kind of mixture, mixing ratio, curing method, and curing days. The results showed the addition of cement, lime, Fly Ash, and oyster soil in Bottom Ash could improved strength and $E_{50}$ and enlarge its field of being used.

Development of a Time-temperature Indicator for Managing the Distribution Temperature of Frozen Mackerel Scomber japonicus (냉동 고등어(Scomber japonicus)의 유통 온도 관리를 위한 Time-temperature Indicator 개발)

  • Choi, Jeong-Wook;Lee, Min-Kyeong;Choi, Jae-Hyuk;Jang, Myung-Kee;Ahn, Dong-Hyun;Nam, Taek-Jeong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.51 no.5
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    • pp.590-594
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    • 2018
  • We developed a time-temperature indicator (TTI) that rapidly determines whether frozen mackerel Scomber japonicus has thawed during its distribution. Our TTI was made from filter paper capable of absorbing mackerel exudate that was soaked in a 20% citric acid solution at pH 4.0 and then dried. The dried absorbent paper was cut and attached to blue litmus paper with a 2 mm overhang. The fixed litmus paper was covered with a polypropylene film and sealed. The indicator was placed inside a polyvinyl vacuum package containing the mackerel sample. The vacuum-sealed packaged was frozen at $-20^{\circ}C$ for 24 h. After freezing, the color change and time dependence of the indicator were observed at room temperature ($25^{\circ}C$) and demonstrated the utility of this TTI for rapidly determining whether frozen mackerel underwent thawing during distribution.

Development of Hybrid Sol-Gel Coating to Prevent Corrosion of Magnesium Alloys (마그네슘 합금의 방청을 위한 하이브리드 졸-겔 코팅제의 개발)

  • Lee, Dong Uk;Kim, Young Hoon;Moon, Myung Jun
    • Corrosion Science and Technology
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    • v.17 no.1
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    • pp.30-36
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    • 2018
  • The high rate of corrosion of magnesium alloys makes it limited for industrial applications. Therefore, surface treatment is required to enhance their corrosion resistance. In our study, a chemical conversion coating for protecting the corrosion of the magnesium alloy, AZ31B, was prepared by using a phosphate-permanganate solution. The chemical conversion coating had a limited protection ability due to defects arising from cracks and pores in the coating layer. The sol-gel coating was prepared by using trimethoxymethylsilane (MTMS) and 3-glycidoxypropyltrimethoxysilane (GPTMS) as precursors, and aluminum acetyl acetonate as a ring opening agent. The corrosion protection properties of sol-gel and conversion coatings in 0.35wt% NaCl solution were measured by the electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization test. The EIS results indicated that the resistance of the chemical conversion coating with the sol-gel coating was significantly improved through the sol-gel sealed phosphate-permanganate conversion coating. The results of the potentiodynamic polarization test revealed that the sol-gel coating decreased the corrosion current density ($I_{corr}$). The SEM image showed that the sol-gel coating sealed conversion coating and improved corrosion protection.

A STUDY OF THE EFFECTS OF AUCUBIN ON THE PULP TISSUE AFTER PULPOTOMY IN DOGS (치수절단 후 Aucubin이 잔존치수조직에 미치는 영향에 관한 연구)

  • Baek, Seung-Ho;Lee, Sung-Woo
    • Restorative Dentistry and Endodontics
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    • v.24 no.4
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    • pp.554-559
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    • 1999
  • Aucubin, an iridoid glucoside isolated from Aucuba japonica, has pharmacological effects such as antimicrobial effect, liver protective function and inhibition of liver RNA and protein biosynthesis, etc. This study was performed to observe the effect of aucubin on the pulp tissue after pulpotomy. Aucubin was converted to aucubinogenin as an active form by ${\beta}$-glucosidase. In 3 Mongrel dogs, the pulps were mechanically exposed with a sterile round bur and excised with sterile excavator. After bleeding control, aucubin was applied on remaining pulp tissues and then they were sealed with IRM in experimental group. In control group, $Ca(OH)_2$ powder was applied on remaining pulp tissues and then they were sealed with IRM. After interval of 1 and 12 weeks, the dogs were sacrificed. The teeth were prepared for histologic evaluation and examined by light microscope. Aucubin 1 week group showed that mild inflammation and vascular congestion in most of the specimen. More various degree of inflammation was found in experimental group than in control group. Premature calcified mass were found in the both 1 weeks groups. Continuous well-formed dentin bridge was found in both 12 weeks groups. Collectively, this study suggests that the possibility of aucubin as a medicament after pulpotomy.

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Preparation and Evaluation of Sustained Release Aspirin Microcapsules Using Eudragit $RS^{\circledR}$ Polymer (Eudragit $RS^{\circledR}$를 이용한 지속 방출형 아스피린 마이크로캅셀의 제조 및 평가)

  • Chun, In-Koo;Shin, Dong-Won
    • YAKHAK HOEJI
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    • v.32 no.1
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    • pp.26-39
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    • 1988
  • Eudragit $RS^{\circledR}$ polymer was used as a wall material for the microencapsulation of aspirin by a phase separation method from chloroform-cyclohexane system with 5% polyisobutylene (PIB) in cyclohexane, and microcapsules obtained were evaluated by particle size analysis, scanning electron microscopy (SEM), drug release and drug stability test. With PIB as a coacervation inducing agent, smooth and tight microcapsules with less aggregation were obtained. Below 1 : 0.3 core-wall ratio, it was possible to coat individual particle. Variation of production conditions showed that increasing the proportion of wall material, particle size and wall thickness of microcapsules and the concentration of paraffin wax in cyclohexane as a sealant sustained drug release rates effectively. SEM confirmed that larger microcapsules after drug release did not rupture into smaller particles but contained a few small pores on the surface. Aspirin release from Eudragit $RS^{\circledR}$ coated microcapsules was independent of the pH of medium, and the mechanism of drug release from non-sealed and sealed microcapsules appeared to fit Higuchi matrix model kinetics. Aspirin in the mixture of aspirin microcapsules and sodium bicarbonate was by far more stable than that in the mixture of pure aspirin and sodium bicarbonate.

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The Theory of Auctions and Competitive Bidding : A Survey (경매 및 경쟁입찰에 관한 이론적 고찰;-문헌연구를 중심으로 -)

  • 정형찬
    • The Journal of Fisheries Business Administration
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    • v.25 no.2
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    • pp.89-102
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    • 1994
  • This paper is to survey the major results of the game-theoretic models and recent research directions of the literature on auctions and competitive biddings. This paper classifies the auctions and competitive biddings into the following four major types:(i) English auction, (ii) Dutch auction, (iii) the first-price sealed-bid auction, (iv) the second-price sealed-bid auction. In order to survey the major ideas related to auctions and competitive biddings, we use two representative theoretical models developed under the game-theoretic framework : (i) the independent private value model are summarized as follows ; (1) The Dutch auction and the first-price auction are strategically equivalent, and so are the English auction and the second-price auction. (2) At the symmetric equilibria, the expected selling price is the same for all four types of auction. Meanwhile, the major results of the general model are as follows ; (1) When bidders are uncertain about their value extimate, the English and second-price auctions are not equivalent, but the dutch and the first-price auctions are still strategically equivalent. (2) The English auction generates the higher expected prices than the second-price auction. Also, when bidders are risk-neutral, the second-price auction generated higher average prices than the Dutch and the first-price auctions.

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