• Title/Summary/Keyword: scrubbing

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The Effects of Surface Pretreatments on Adhesion Strength of TiN Films by DC Magnetron Sputtering (표면전처리가 반응성 스퍼터링법으로 제조한 TiN 코팅층의 밀착력에 미치는 영향)

  • 김흥윤;백운승;권식철;김규호
    • Journal of the Korean institute of surface engineering
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    • v.26 no.5
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    • pp.225-234
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    • 1993
  • Titanium nitride coatings were deposited onto SUS304 stainless steel substrates pretreated by mechanical scrubbing, chemical etching at 50% HCl solution and Ar ion etching. Adhesion strength were measured by scratch tester and confirmed by SEM with EDS. Adhesion strength of Ar ion etched substrate was 10 to 15 times higher than that of mechanical scrubbed or chemical etched substrate. Ar ion etching brought about an uniform and fine spherical shaped surface, while chemical etching gave rise to a rough and irregular surface on SEM micrograph. It was suggested that higher adhesion strength might be caused by anchoring effect of Ar ion etched surface prior to TiN deposition.

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A Study of Co-Combustion Characteristics of North Korean Anthracite and Bituminous Coal in 2 MWe CFBC Power Plant (2 MWe 순환유동층 발전 플랜트에서 유연탄과 북한 무연탄 혼소시험 특성 연구)

  • Han, Keun-hee;Hyun, Ju-soo;Choi, Won-kil;Lee, Jong-seop
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.580-586
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    • 2009
  • In this study, co-combustion characteristics of Chinese bituminous coal and North Korean anthracite were investigated using a 2 MWe scale circulating fluidized bed power plant. At first, the combustion efficiency of bituminous coal of China and Australia as a function of excess air ratio and temperature were observed. The results showed that the combustion efficiency was influenced by particle size and volatile content of coal, the combustion efficiency of Chinese bituminous coal was over 99.5%. The unburned carbon particles from fly ash and bottom ash were a content 5~7% and 0.3%, respectively. The combustion efficiency with the mixture ratio 20% of bituminous coal and anthracite decreased over 5% because of the increase of entrained particles by a small average particle size of anthracite in the combustor. However, the outlet concentration of $SO_2$ and $NO_x$ was not changed remarkably. The concentrations of the typical air pollutants such as $NO_x$ and $SO_2$ were 200~250 ppm($O_2$ 6%), 100~320 ppm($O_2$ 6%) respectively. The outlet concentration of $NO_x$ was decreased to 30~65% with $NH_3$ supplying rate of 2~13 l/min in SCR process. The $SO_x$ removal efficiency was up to 70% by in-furnace desulfurization using limestone with Ca/S molar of approximately 6.5. With wet scrubbing using $Mg(OH)_2$ as absorbent, the $SO_x$ removal efficiency reached 100% under near pH 5.0 of scrubbing liquid.

A Study of Oral Health Knowledge and Status of the Elderly in Ulju-gun (울주군 일부지역 노인의 주관적 구강건강인지 및 수준에 관한 조사)

  • Lee, Jung-Hwa;Seong, Mi-Gyung;Kang, Hyun-Kyung;Cho, Gab-Suk
    • Journal of dental hygiene science
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    • v.7 no.4
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    • pp.281-286
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    • 2007
  • The purpose of this research was to find out their perception of the dental hygiene and level of its knowledge by estimating status of senior adults' dental health management. First, questionnaires were distributed to the 256 target senior adults aged more than 60, who were going to school for senior adults located in Ulju Country and the survey was conducted by interview directly. The results were as follows; 1. As for tooth brushing method, scrubbing method was used in male and rolling method was used in female and the survey results statistically revealed that rolling method was the most used in aged from 60 to 70(68.1%) and scrubbing method was the most used in aged more than 70(80.4%)[p < 0.001]. 2. As for reason of visiting dental clinic, female respondents accounting for the highest said they visited dental clinic when they feel a pain in the teeth and as for frequence of dental clinic, male respondents visited dental clinic for a once per a year. there was no difference statistically according to age(47.9%). 3. As for the perception of the necessity of dental prosthetic treatment, there was higher positive response in the female than male, in the lower aged groups than higher aged group[p<0.05]. 4. As for the question of whether to use of denture or not now, the survey results was statistically that the higher aged group and male groups were higher used dentures [p < 0.001]. 5. As for maintenance of denture, female respondents said the highest that they keep it in cold water after cleaning(95.5%), there was no difference statistically according to age and educational background [p < 0.001].

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Dry cleaning for metallic contaminants removal after the chemical mechanical polishing (CMP) process (Chemical Mechnical Polishing(CMP) 공정후의 금속오염의 제거를 위한 건식세정)

  • 전부용;이종무
    • Journal of the Korean Vacuum Society
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    • v.9 no.2
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    • pp.102-109
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    • 2000
  • It is difficult to meet the cleanliness requirement of $10^{10}/\textrm{cm}^2$ for the giga level device fabrication with mechanical cleaning techniques like scrubbing which is widely used to remove the particles generated during Chemical Mechanical Polishing (CMP) processes. Therefore, the second cleaning process is needed to remove metallic contaminants which were not completely removed during the mechanical cleaning process. In this paper the experimental results for the removal of the metallic contaminants existing on the wafer surface using remote plasma $H_2$ cleaning and UV/$O_3$ cleaning techniques are reported. In the remote plasma $H_2$ cleaning the efficiency of contaminants removal increases with decreasing the plasma exposure time and increasing the rf-power. Also the optimum process conditions for the removal of K, Fe and Cu impurities which are easily found on the wafer surface after CMP processes are the plasma exposure time of 1min and the rf-power of 100 W. The surface roughness decreased by 30-50 % after remote plasma $H_2$ cleaning. On the other hand, the highest efficiency of K, Fe and Cu impurities removal was achieved for the UV exposure time of 30 sec. The removal mechanism of the metallic contaminants like K, Fe and Cu in the remote plasma $H_2$ and the UV/$O_3$ cleaning processes is as follows: the metal atoms are lifted off by $SiO^*$ when the $SiO^*$is evaporated after the chemical $SiO_2$ formed under the metal atoms reacts with $H^+ \; and\; e^-$ to form $SiO^*$.

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CFD Analysis on the Effect of the Nozzle Arrays and Spray Types in the Hydrogen Peroxide Mixing Quencher to Improve the Mixing Efficiency (과산화수소 혼합냉각기 내의 노즐배치 및 가스분사 방식 변화에 따른 혼합율 개선에 대한 전산해석적 연구)

  • Koo, Seongmo;Chang, Hyuksang
    • Clean Technology
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    • v.23 no.1
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    • pp.42-53
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    • 2017
  • Numerical analysis was done to evaluate the fluid distribution inside of the mixing quencher to increase the reaction efficiency of the aqueous hydrogen peroxide solution in the scrubbing column which is used for simultaneous desulfurization and denitrification. Effective injection of the aqueous hydrogen peroxide ($H_2O_2$) solution in the mixing quencher has major effects for improving the reaction efficiency in the scrubbing column by enhancing the mixing of the aqueous $H_2O_2$ solution with the exhaust gas. The current study is to optimize the array of nozzles and the spray angles of the aqueous $H_2O_2$ solution in the mixing quencher by using the computational method. Main concerns of the analysis are how to enhance the uniformity of the $H_2O_2$ concentration distribution in the internal flow. Numerical analysis was done to check the distribution of the internal flow in the mixing quencher in terms of RMS values of the $H_2O_2$ concentration at the end of quencher. The concentration distribution of $H_2O_2$ at the end of is evaluated with respect to the different array of the nozzle pipes and the nozzle tip angles, and we also analyzed the turbulence formation and fluid mixing in the zone. The effect of the spray angle was evaluated with respect to the mixing efficiency in different flow directions. The optimized mixing quencher had the nozzle array at location of 0.3 m from the inlet duct surface and the spray angle is $15^{\circ}$ with the co-current flow. The RMS value of the $H_2O_2$ concentration at the end of the mixing quencher was 12.4%.

Solvent Extraction of Light (Pr, Nd) and Medium (Tb, Dy) Rare Earth Elements with PC88A of Rare Earth Chloride Solution from Waste Permanent Magnet (폐 영구자석으로부터 회수한 염화희토류용액에서 PC88A를 이용한 경희토류(Pr, Nd)/중희토류(Tb, Dy) 용매추출)

  • Jeon, Su-Byung;Son, InJoon;Lim, Byung-Chul;Kim, Jeong-Mo;Kim, Yeon-Jin;Ha, Tae-Gyu;Yoon, Ho-Sung;Kim, Chul-Joo;Chung, Kyeong-Woo
    • Resources Recycling
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    • v.27 no.3
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    • pp.8-15
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    • 2018
  • Solvent extraction behavior of light rare earth elements (Pr, Nd) and medium rare erath elements (Tb, Dy) in the HCl-PC88A-kerosene extraction system was investigated in order to separate high-purity light rare earths (Pr, Nd) and medium rare earths (Tb, Dy) in the mixed rare earth chloride solution. In the batch test step, it was confirmed that the separation efficiency was good when the extractant concentration (PC88A) was 0.5 M, the equilibrium pH after extraction was 0.8 to 1.0 (initial pH 1.3 of the feed), the concentrations of hydrochloric acid in scrubbing solution was set as 0.1 M, the concentrations of hydrochloric acid in stripping solution was set as 2.0 M or more. Based on the experimental data obtained from the batch test, the mixer-settler was composed as follows; 4 stages of extraction, 8 stages of scrubbing, 4 stages of stripping, and 3 stages of pickling organic solution. The Mixer-settler was operated for 180 hours, and the operating conditions were continuously adjusted to obtain the high-purity light/medium rare earths. Finally, the purity of light (Pr, Nd) and medium rare earth elements (Tb, Dy) was reached as 3 N class.

Recovery of the Vanadium and Tungsten from Spent SCR Catalyst Leach Solutions by Hydrometallurgical Methods (SCR 폐촉매 침출액으로부터 습식제련법에 의한 바나듐, 텅스텐의 회수)

  • Choi, In-Hyeok;Moon, Gyeonghye;Jeon, Jong-Hyuk;Lee, Jin-Young;Jyothi, Rajesh Kumar
    • Resources Recycling
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    • v.29 no.2
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    • pp.62-68
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    • 2020
  • In new millennium, wide-reaching demands for selective catalytic reduction (SCR) catalyst have been increased gradually in new millennium. SCR catalyst can prevent the NOx emission to protect the environment. In SCR catalyst the main composition of the catalyst is typically TiO2 (70~80%), WO3 (7~10%), V2O5 (~1%) and others. When the SCR catalysts are used up and disposed to landfills, it is problematic that those should exist in the landfill site permanently due to their extremely low degradability. A new advanced technology needs to be developed primarily to protect environment and then recover the valuable metals. Hydrometallurgical techniques such as leaching and liquid-liquid extraction was designed and developed for the spent SCR catalyst processing. In a first stage, V and W selectively leached from spent SCR catalyst, then both the metals were processed by liquid-liquid extraction process. Various commercial extractants such as D2EHPA, PC 88A, TBP, Cyanex 272, Aliquat 336 were tested for selective extraction of title metals. Scrubbing and stripping studies were tested and optimized for vanadium and tungsten extraction and possible separation. 3rd phase studies were optimized by using iso-decanol reagent.

Recent Development in Metal Oxides for Carbon Dioxide Capture and Storage (금속 산화물을 기반으로 한 이산화탄소 포집과 저장에 대한 최근 기술)

  • Oh, Hyunyoung;Patel, Rajkumar
    • Membrane Journal
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    • v.30 no.2
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    • pp.97-110
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    • 2020
  • CO2 capture and storage (CCS) is one of the promising technologies that can mitigate ever-growing emission of anthropogenic carbon dioxide and resultant climate change. Among them, chemical looping combustion (CLC) and calcium looping (CaL) are getting increasing attention recently as the prospective alternatives to the existing amine scrubbing. Both methods use metal oxides in the process and consist of cyclic reactions. Yet, due to their cyclic nature, they both need to resolve sintering-induced cyclic stability deterioration. Moreover, the structure of the metal oxides needs to be optimized to enhance the overall performance of CO2 capture and storage. Deposition of thin film coating on the metal oxide is another way to get rid of wear and tear during the sintering process. Chemical vapor deposition or atomic layer deposition are the well-known, established methods to form thin film membranes, which will be discussed in this review. Various effective recent developments on structural modification of metal oxide and incorporation of stabilizers for cyclic stability are also discussed.

Recovery of Co and Ni from Strong Acidic Solution by Cyanex 301 (강산성용액에서 Cyanex 301에 의한 Co 및 Ni 회수 연구)

  • Cho, Yeon-Chul;Kim, Ki-Hun;Ahn, Jae-Woo
    • Resources Recycling
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    • v.30 no.6
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    • pp.28-35
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    • 2021
  • An experiment was conducted to separate or recover Co and Ni using Cyanex 301 from process by-products and waste resources containing Co and Ni. To separate and recover Co and Ni from simulated leaching solutions, 10 v/v% Cyanex 301 was used as an extractant in this study; Li was not extracted. At equilibrium pH 1.5 and a phase ratio (A/O) of 1.0, 0.44% of Mg and 11.57% of Mn were extracted, and more than 99% of Co and Ni were extracted. McCabe-Thiele diagram analysis confirmed that more than 99.9% of Co and Ni could be extracted simultaneously through two-stage extraction with an extraction phase ratio (A/O) of 2. It was possible to extract Mg and Mn simultaneously through the scrubbing process. In the scrubbing process, more than 99% of Mg and 87% of Mn were scrubbed using 0.05 M of H2SO4, and 99.9% of Mg and more than 80% of Mn were scrubbed using 0.05 M of HCl. In the stripping process, 93% of Co and 5% of Ni were stripped selectively by 3.0 M of H2SO4. However, when 8.0 M of HCl was used as a stripping solution, more than 99.9% of Co and more than 90% of Ni were stripped simultaneously.

Data Quality Management: Operators and a Matching Algorithm with a CRM Example (데이터 품질 관리 : CRM을 사례로 연산자와 매칭기법 중심)

  • 심준호
    • The Journal of Society for e-Business Studies
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    • v.8 no.3
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    • pp.117-130
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    • 2003
  • It is not unusual to observe that there Is a great amount of redundant or inconsistent data even within an e-business system such as CRM(Customer Relationship Management) system. This problem becomes aggravate when we construct a system of which information are gathered from different sources. Data quality management is indeed needed to avoid any possible redundant or inconsistent data in such information system. A data quality process, in general, consists of three phases: data cleaning (scrubbing), matching, and integration phase. In this paper, we introduce and categorize data quality operators for each phase. Then, we describe our distance function used in the matching phase, and present a matching algorithm PRIMAL (a PRactical Matching Algorithm). And finally, we present a related work and future research.

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