• Bulletin of the Korean Chemical Society
• /
• v.32 no.6
• /
• pp.2003-2007
• /
• 2011

We report a highly sensitive surface-enhanced Raman scattering (SERS) platform for the selective trace analysis of mercury (II) ions in drinkable water using aptamer-conjugated silver nanoparticles. Here, an aptamer designed to specifically bind to $Hg^{2+}$ ions in aqueous solution was labelled with a TAMRA moiety at the 5' end and used as a Raman reporter. Polyamine spermine tetrahydrochloride (spermine) was used to promote surface adsorption of the aptamer probes onto the silver nanoparticles. When $Hg^{2+}$ ions are added to the system, binding of $Hg^{2+}$ with T-T pairs results in a conformational rearrangement of the aptamer to form a hairpin structure. As a result of the reduced of electrostatic repulsion between silver nanoparticles, aggregation of silver nanoparticles occurs, and the SERS signal is significantly increased upon the addition of $Hg^{2+}$ ions. Under optimized assay conditions, the concentration limit of detection was estimated to be 5 nM, and this satisfies a limit of detection below the EPA defined limit of 10 nM in drinkable water.

• Structural Engineering and Mechanics
• /
• v.68 no.4
• /
• pp.443-457
• /
• 2018

In this article, a comparative study has been made to investigate the scattering behaviour of three layered structure model on torsional surface wave. For such model intermediate layer is taken as fiber reinforced composite, resting over a dry sandy Gibson substratum and underlying by different anelastic media. We consider two distinct mediums for topmost layer. In the first case, topmost layer has been taken as fluid saturated homogeneous porous layer, while in the second case the fluid saturated porous layer has been replaced by a transversely isotropic layer. Simple form expression for the secular equation of torsional surface wave has been worked out in both the cases by executing specific boundary conditions, which comprises Whittaker's function and its derivative, for imminent result that have been elaborated asymptotically. Some special cases have been constituted which are in excellent compliance with recorded literatures. For the sake of comparative study, numerical estimation and graphical illustration have been accomplished to identify the effects of the width ratio of the layers, Biot's gravity parameter, sandy parameter, porosity parameter and other heterogeneity parameters corresponding to the layers and half spaces, horizontal compressive and tensile initial stress on the phase velocity of torsional surface wave.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.19 no.3
• /
• pp.806-819
• /
• 1995

A study of radiative heat heat transfer has been done in the non-orthogonal coordinate system utilizing the finite volume method and the P.1 approximation. Radiation of absorbing, emitting and scattering media in a concentric annulus has been solved using the non-orthogonal coordinate and the calculations were compared with the existing results. The results obtained from the analysis using the finite volume method are in good agreement with the existing calculations for all optical thicknesses. It was also shown that for only optically thick cases, P-1 approximation can be used in a non-orthogonal coordinate. Convective heat transfer analysis has been carried out to obtain the temperature fields in a cross flow around a circular cylinder and the finite volume method was applied in the non-orthogonal coordinate system to analyze radiative heat transfer. Effects of the optical thickness, the ratio of the surface temperature of the cylinder tot he free stream temperature, and the scattering albedo on radiation have been presented.

• Proceedings of the Korean Vacuum Society Conference
• /
• 1998.02a
• /
• pp.41-41
• /
• 1998

Rare earth metal films have been used as a buffer layer for growing ferroelectric t thin film or a seed layer for magnetic multilayer. But when it was deposited on s semiconductor substrates for the application of magneto-optic (MO) storage media, it i is difficult to exactly measure magnetic cons떠nts due to shunting current, and so it n needs to grow metal films on insulator substrate to reduce such effect. Recently, it w was reported that ultra-thin Pt layer were epitaxially grown on A12O:J by ion beam s sputtering in 비떠 high vacuum and it can be used as a seed layer for the growth of C Co-contained magnetic multilayer. In this stu$\phi$, Pt thin film were epi떠xially grown on AI2D3 ($\alpha$)OJ) by RF magnetron s sputtering. The crystalline structure was analyzed by transmission electron microscope ( (TEM) and Rutherford Back Scattering (RBS)/Ion Channeling. In TEM study, Pt was b believed to be twinned on AI잉3($\alpha$)01) su$\pi$ace about Pt(ll1) plane.Moreover, RBS c channeling spectra showed that minimum scattering yield of Pt(111)/AI2O:J(1$\alpha$)OJ) was 4 4% and Pt(11J)/AI2D3($\alpha$)OJ) had 3-fold symmetry.

• Korean Journal of Optics and Photonics
• /
• v.1 no.2
• /
• pp.142-148
• /
• 1990

Surface-enhanced Raman scattering (SERS) experiment of pyridine (CsHsN) has been performed at silverpyridine interface by use of long range surface plasmon (LRSP) which is generated in the Sarid-type attenuated total reflection (A TR) structure consisting of prism. dielectric. metal and dielectric media. Generation of LRSP has ben confirmed by observing the propagation of the LRSP. Raman signal of pyridine adsorbed on a silver surface in the above layered structure has been observed and compared with the bulk Raman signal and SERS signal from the chemically adsorbed pyridine. SERS experiment by use of LRSP has not yet reported to the best of our knowledge.wledge.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.21 no.2
• /
• pp.235-251
• /
• 1997

A numerical simulation on the combined natural convection and radiation is carried out in a partially open rectangular enclosure with a heater by using the finite volume and the S-8 discrete ordinate methods. The fluid inside the enclosure is considered as an absorbing, emitting and anisotropic scattering media. The heater causes a natural circulation of the fluid (10$^{5}$ $^{9}$ ) which results in significant in-flow of the ambient cold fluid through the partially open wall. Comparing the results of pure convection with those of the combined convection- radiation, the combined heat transfer results with small Planck numbers (P$_{l}$ <1.0) show much stronger circulation than those of the pure convection, and the fluid circulation is more evident for larger Rayleigh numbers. When one of three radiative properties - the medium absorption coefficient, the wall reflectivity, and the scattering albedo - increases, the fluid circulation and the heat transfer in the enclosure are reduced. The location of the heater and the open ratio of the right wall are also shown to affect the fluid circulation and heat transfer significantly. However, the anisotropy of the scattering phase function is shown to be unimportant for the fluid circulation and heat transfer within the enclosure considered in this study.

• Journal of The Korean Astronomical Society
• /
• v.51 no.1
• /
• pp.5-16
• /
• 2018

We investigate the escape of $Ly{\beta}$ from emission nebulae with a significant population of excited hydrogen atoms in the level n = 2, rendering them optically thick in $H{\alpha}$. The transfer of $Ly{\beta}$ line photons in these optically thick regions is complicated by the presence of another scattering channel leading to re-emission of $H{\alpha}$, alternating their identities between $Ly{\beta}$ and $H{\alpha}$. In this work, we develop a Monte Carlo code to simulate the transfer of $Ly{\beta}$ line photons incorporating the scattering channel into $H{\alpha}$. Both $H{\alpha}$ and $Ly{\beta}$ lines are formed through diffusion in frequency space, where a line photon enters the wing regime after a fairly large number of resonance scatterings with hydrogen atoms. Various line profiles of $H{\alpha}$ and $Ly{\beta}$ emergent from our model nebulae are presented. It is argued that the electron temperature is a critical parameter which controls the flux ratio of emergent $Ly{\beta}$ and $H{\alpha}$. Specifically for $T\;=\;3{\times}10^4\;K$ and $H{\alpha}$ line center optical depth $\tau{\alpha}\;=\;10$, the number flux ratio of emergent $Ly{\beta}$ and $H{\alpha}$ is ~ 49 percent, which is quite significant. We propose that the leaking $Ly{\beta}$ can be an interesting source for the formation of $H{\alpha}$ wings observed in many symbiotic stars and active galactic nuclei. Similar broad $H{\alpha}$ wings are also expected in $Ly{\alpha}$ emitting halos found in the early universe, which can be potentially probed by the James Webb Telescope in the future.

• The Proceeding of the Korean Institute of Electromagnetic Engineering and Science
• /
• v.4 no.1
• /
• pp.38-43
• /
• 1993

A Hybrid Finite Element Method(HFEM) is applied to solve the electrormagnetic scattering from multi-layered dielectric cylinders. An unbounde region is divided into local boundary regions where a practical differential equation solution is obtained, with the remaining unbounded region represented by a boundary integral equation. If sources, media inhomogeneities, and anisotropies are local, a surgace may be defined to enclose them. Therefore the integral region so defined is bounded, and differential techniques may be used there. Also, in the re- maining unbounded region a boundary integral equation may be formulated using only a simple free - space green's function. Therefore, The local boundary is represented by a boundary - value problem with boundary conditions and solved by the finite element method. The advantage of the proposed method is simple and efficient in the work of electromagnetic scattering. The validity of the results have been verified by comparing results of other method(boundary element method). Examples has been presented to calculate the scattered fields of lossy dielectric cylinders of arbitray cross section.

• Progress in Medical Physics
• /
• v.12 no.1
• /
• pp.79-94
• /
• 2001

The fluorescence emanating from a biological tissue contains information about scattering, absorption and the intrinsic fluorescence (fluorescence only due to fluorophores). Becaue fluorescence spectra of biological tissue are often significantly affected by the presence of tissue absorbers and scatterers, the measured tissue fluorescence cannot be interpreted as a linear combination of intrinsic fluorescence spectra of different tissue biochemical. We conducted experiments to examine the influence of scattering and absorption on the experimentally measured fluorescence of a turbid medium such as biological tissue. Therefore, we acquired fluorescence and reflectance spectra of tissue phantoms with a wide range of scatterer and absorber concentrations. By applying a photon migration model, which uses the scattering and absorption information contained in reflectance spectra to remove their distortion also present in fluorescence spectra, we extract the intrinsic fluorescence of these tissue models. We achieved excellent agreement between modeled and actual intrinsic fluorescence spectra. The motivation for this research is that intrinsic fluorescence spectra are expected to change with progression of disease in human tissue, due to changes in the tissue biochemical composition. It is not possible to distinguish the two tissue types by using only the measured fluorescence, however clear separation can be achieved with the intrinsic fluorescence in real time optical biopsy.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.359.1-359.1
• /
• 2016

The electromagnetic (EM) properties of media, such as propagation, focusing and scattering, strongly rely on the electric permittivity and the magnetic permeability of media. Recently, artificially-created metamaterials (MMs) composed of periodically-arranged unit cells with tailored electric permittivity and magnetic permeability have drawn wide interest due to their capability of adjusting the EM response. MM absorbers using the conventional sandwich structures usually have very high absorption at a certain frequency, and the absorption properties of MMs can be adjusted simply by changing the geometrical parameters of unit cell. In this work, we suggested an incident-angle-independent broadband perfect absorber based on resistive layers. We analyze the absorption mechanism based on the impedance matching with the free space and the distribution of surface currents at specific frequencies. From the simulation, the absorption was expected to be higher than 96% in 1.4-6.0 GHz. The corresponding experimental absorption was found to be higher than 96% in 1.4-4.0 GHz, and the absorption turned out to be slightly lower than 96% in 4.0-6.0 GHz owing to the irregularity in the thickness of resistive layers.