• Title/Summary/Keyword: scanning measurements

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AN ELECTROCHEMICAL STUDY ON THE CORROSION RESISTANCE OF THE VARIOUS IMPLANT METALS (수종 임플랜트 금속의 내식성에 관한 전기화학적 연구)

  • Jeon Jin-Young;Kim Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.31 no.3
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    • pp.423-446
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    • 1993
  • Titanium and its alloys are finding increasing use in medical devices and dental implants. The strong selling point of titanium is its resistance to the highly corrosive body fluids in which an implant must survive. This corrosion resistance is due to a tenacious passive oxide or film which exists on the metal's surface and renders it passive. Potentiodynamic polarization measurement is one of the most commonly used electro-chemical methods that have been applied to measure corrosion rates. And the potentiodynamic polarization test supplies detailed information such as open circuit, rupture, and passivation potential. Furthermore, it indicates the passive range and sensitivity to pitting corrosion. This study was designed to compare the corrosion resistance of the commonly used dental implant materials such as CP Ti, Ti-6A1-4V, Co-Cr-Mo alloy, and 316L stainless steel. And the effects of galvanic couples between titanium and the dental alloys were assessed for their useful-ness-as. materials for superstructure. The working electrode is the specimen , the reference electrode is a saturated calomel electrode (SCE), and the counter electrode is made of carbon. In $N_2-saturated$ 0.9% NaCl solutions, the potential scanning was performed starting from -800mV (SCE) and the scan rate was 1 mV/sec. At least three different polarization measurements were carried out for each material on separate specimen. The galvanic corrosion measurements were conducted in the zero-shunt ammeter with an implant supraconstruction surface ratio of 1:1. The contact current density was recorded over a 24-hour period. The results were as follows : 1. In potential-time curve, all specimens became increasingly more noble after immersion in the test solution and reached between -70mV and 50mV (SCE) respectively after 12 hours. 2. The Ti and Ti alloy in the saline solution were most resistant to corrosion. They showed the typical passive behavior which was exhibited over the entire experimental range. Therefore no breakdown potentials were observed. 3. Comparing the rupture potentials, Ti and Ti alloy had the high(:st value (because their break-down potentials were not observed in this study potential range ) followed by Co-Cr-Mo alloy and stainless steel (316L). So , the corrosion resistance of titanium was cecellent, Co-Cr-Mo alloy slightly inferior and stainless steel (316L) much less. 4. The contact current density sinks faster than any other galvanic couple in the case of Ti/gold alloy. 5. Ag-Pd alloy coupled with Ti yielded high current density in the early stage. Furthermore, Ti became anodic. 6. Ti/Ni-Cr alloy showed a relatively high galvanic current and a tendency to increase.

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Characteristics of the Horizontal Stress and the Possibility of Stress Induced Brittle Failure in Chuncheon-Yanggu Mountainous Region by the In-situ Stress Measurements (현장 측정에 의한 춘천-양구 산악지역 내 수평응력 분포와 취성파괴 가능성에 관한 연구)

  • Bae Seongho;Jeon Seokwon
    • Tunnel and Underground Space
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    • v.15 no.2 s.55
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    • pp.157-167
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    • 2005
  • Current initial rock stress state is one of the key factors required to evaluate the stability and failure around an excavated opening and its importance increases as the construction depth become deeper and the scale of the rock structure become larger. In this paper, the study was performed to evaluate the characteristics of the regional stress state at Chuncheon-Yanggu mountainous region, the East-North part of Kyeonggi Massif. Forty nine field stress measurements in 9 boreholes were conducted at the depth from 20 m to 290 m by hydraulic fracturing method. The fracturing tracing works were carried out by acoustic televiewer scanning. The study results revealed that the different intial rock stress states presented at different formation rock type and the excessive horizontal stress state with stress ratio(K) close to 3.0 was measured at the depth of 200 m and deeper in the intrusive unite body of the study area. The results from the investigation of excessive horizontal stress and its effect on failure mode showed that there exist several points where the localized excessive horizontal stresses are big enough to potentially induce brittle failures around the future openings greater than 100 m in depth within the granite body of the study area.

Synthesis of Pressure-sensitive Acrylic Adhesives with Photoreactive Groups and Their Application to Semiconductor Dicing Tapes (광 반응성기를 갖는 아크릴 점착제의 합성과 반도체 다이싱 테이프로의 적용 연구)

  • Hee-Woong Park;Nam-Gyu Jang;Kiok Kwon;Seunghan Shin
    • Applied Chemistry for Engineering
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    • v.34 no.5
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    • pp.522-528
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    • 2023
  • In this work, adhesive tapes were prepared for the dicing process in semiconductor manufacturing. Compounds with different numbers of photoreactive groups (f = 1 to 3) were synthesized and incorporated into acrylic copolymers to formulate UV-curable acrylic adhesives. Structural confirmation of the synthesized photoreactive compounds (f = 2 or 3) was performed using nuclear magnetic resonance (NMR) spectroscopy. The introduction of the photoreactive compounds into the acrylic adhesive was accomplished by urethane reactions, and the successful synthesis of the UV-curable acrylic adhesive was verified by Fourier transform infrared (FT-IR) measurements. To evaluate the performance of the adhesive, the peel strength was evaluated before and after UV irradiation using a silicon wafer as a substrate. The adhesive exhibited high peel strength (~2000 gf/25 mm) before UV exposure, which was significantly reduced (~5 gf/25 mm) after UV exposure. Interestingly, the adhesive containing multifunctional photoreactive compounds showed the most significant reduction in peel strength. In addition, surface residue measurements by field emission scanning electron microscopy (FE-SEM) showed minimal surface residue (~0.2%) after UV exposure. Overall, these results contribute to the understanding of the behavior of UV-curable acrylic adhesives and pave the way for potential applications in semiconductor manufacturing processes.

Effects of Modifiers on the Supercritical $CO_{2}$ Extraction of Glycyrrhizin from Licorice and the Morphology of Licorice Tissue after Extraction

  • Kim Hyun Seok;Lee Sang Yun;Kim Byung Yong;Lee Eun Kyu;Ryu Jong Hoon;Lim Gio Bin
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.9 no.6
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    • pp.447-453
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    • 2004
  • Optimal conditions for the supercritical carbon dioxide $(scCO_{2})$ extraction of glycyr­rhizin from licorice (Glycyrrhiza glabra) were investigated, with an emphasis on the types and levels of modifiers. The morphology of the licorice tissue remaining after the $scCO_{2} $ extraction of glycyrrhizin was examined by scanning electron microscopy, coupled with measurements of ab­solute density. Conventional organic solvent extraction was also carried out for purpose of quantitative comparison. At 50 MPa and $60^{circ}C$ glycyrrhizin could not be extracted with pure $scCO_{2}$, while a considerable amount of glycyrrhizin was extracted when water was added to $scCO_{2}$ as a modifier. The highest recovery was found to be about $97\%$ when $70\%$ aqueous methanol was added to $scCO_{2}$ at a concentration of $15\%$. The optimal pressure and temperature for the supercritical fluid extraction of glycyrrhizin were observed to be 30 M Pa and $60^{circ}C$, respectively. Under these conditions, the percentage recovery of glycyrrhizin attained a maximum value of 102.67\pm$ $1.13\%$ within 60 min. Furthermore, in the case of $scCO_{2}$ modified with $70\%$ aqueous methanol, the licorice tissue obtained after extraction was found to be severely de­graded by excessive swelling, and the absolute density of the licorice residues was observed to be the highest.

An optimized condition for corrosion protection of Type 304 Films prepared by unbalanced magnetron sputtering in 3.5% NaCl solution

  • Yoo, Ji-Hong;Ahn, Seung-Ho;Kim, Jung-Gu;Lee, Sang-Yul
    • Journal of Surface Science and Engineering
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    • v.34 no.5
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    • pp.465-474
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    • 2001
  • Type 304SS coatings were performed at 200$\square$ onto AISI 1045 carbon steel substrate using unbalanced magnetron sputtering (UBMS) with an austenitic AISI 304 stainless steel (SS) target of 100mm diameter. The total deposition pressure in the active Ar gas was 2$\times$10$^{-3}$ Torr. Coatings were done at various target power densities and bias voltages. Chemical compositions of metallic elements of the coatings were measured by energy dispersive X-rays spectroscopy (EDS). The structure and the morphology of Type 304SS coatings were investigated by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). Corrosion properties of the coated specimens were examined using electrochemical polarization measurements and electrochemical impedance spectroscopy in a deaerated 3.5% NaCl solution. The porosity rate was obtained from a comparison of the dc polarization resistance of the uncoated and coated substrates. Scratch adhesion testing was used to compare the critical loads for different coatings. XRD results showed that the sputtered films exhibit a ferritic b.c.c. $\alpha$-phase. Potentiodynamic polarization curves indicated that all samples had much higher corrosion potential and better corrosion resistance than the bare steel substrate. The corrosion performance increased with increasing power density and the adhesion was enhanced at the bias voltage of -50V. An improvement in the corrosion resistance can be obtained with a better coating adhesion. Finally, an optimized deposition condition for corrosion protection was found as $40W/cm^2$ and -50V.

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Adsorption Characteristics of H2S on Adsorbent Made by Sewage Sludge in Fixed Bed Adsorption Column (하수슬러지를 활용하여 제조한 흡착제의 고정흡착층에서의 H2S 흡착특성)

  • Park, Chun-Dong;Youn, Ju-Young;Park, Yeong-Seong
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.718-722
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    • 2012
  • $H_2S$ adsorption characteristics of adsorbent made by sewage sludge were investigated. For analyses of the manufactured adsorbent, various methods such as Iodine adsorptivity, scanning electron microscope (SEM), and measurements of BET surface area and pore volume were adopted. As the major adsorption characteristic, breakthrough curve was measured by using a continuous fixed bed adsorption column for operating variables such as adsorption temperature ($25{\sim}45^{\circ}C$), aspect ratio (L/D)(3~9), gas flow rate (0.1~2.0 liter/min) and $H_2S$ gas concentration (50~200 ppm). The experimental result showed that the carbonization and activation of sewage sludge are very important for the improvement in $H_2S$ adsorption capacity.

Photocatalytic Performance of ZnS and TiO2 Supported on AC Under Visible Light Irradiation

  • Meng, Ze-Da;Cho, Sun-Bok;Ghosh, Trisha;Zhu, Lei;Choi, Jong-Geun;Park, Chong-Yeon;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.91-96
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    • 2012
  • AC and ZnS modified $TiO_2$ composites (AC/ZnS/$TiO_2$) were prepared using a sol-gel method. The composite obtained was characterized by Brunauer-Emmett-Teller (BET) surface area measurements, X-ray diffraction (XRD), energy dispersive X-ray (EDX) analysis, scanning electron microscope (SEM) analysis, and according to the UV-vis absorption spectra (UV-vis). XRD patterns of the composites showed that the AC/ZnS/$TiO_2$ composites contain a typical single and clear anatase phase. The surface properties as observed by SEM present the characterization of the texture of the AC/ZnS/$TiO_2$ composites, showing a homogenous composition in the particles showing the micro-surface structures and morphology of the composites. The EDX spectra of the elemental identification showed the presence of C and Ti with Zn and S peaks for the AC/ZnS/$TiO_2$ composite. UV-vis patterns of the composites showed that these composites had greater photocatalytic activity under visible light irradiation. A rhodamine B (Rh.B) solution under visible light irradiation was used to determine the photocatalytic activity. The degradation of Rh.B was determined using UV/Vis spectrophotometry. An increase in the photocatalytic activity was observed. From the photocatalytic results, the excellent activity of the Y-fullerene/$TiO_2$ composites for the degradation of methylene blue under visible irradiation could be attributed to an increase in the photo-absorption effect caused by the ZnS and to the cooperative effect of the AC.

The Cause Analysis of Pitting Corrosion on the Waterjet Impeller (물분사 추진기 임펠러 부식에 대한 원인분석)

  • Lee, Hyeong-Sin;Jung, Un-Hwa
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.545-551
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    • 2020
  • Cause analysis of surface pitting crack on a waterjet impeller was conducted. The waterjet impeller was made from stainless steel duplex 2205, which is more resistant to corrosion and local corrosion than typical stainless steel 316L and 317L, and has high mechanical strength, making it a useful material in various marine structures and seawater desalination facilities. The measurements were taken by scanning electron microscopy (SEM) and molecular ecological detection. The chemical composition of S was examined by SEM in the area of pitting corrosion. The dsrAB gene was detected on the sample of the pitting corrosion of the impeller through molecular ecological detection. Therefore, pitting corrosion on the surface of a waterjet impeller was caused by sulphite-reducing bacteria (SRB). To prevent the spread of SRB, management is required through high temperature treatments (over 65℃), pH management, or the insulation of a hull and waterjet.

Corrosion Inhibitive and Adsorption Properties of a Flavonoid compound for Mild Steel in Acidic Medium (산성 조건에서 부드러운 강철용 부식억제제로 사용되는 플라보노이드계 화합물의 부식억제성질과 흡착성질)

  • Ezhilarasi, J. Christy;Nagarajan, Prabavathy
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.495-501
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    • 2011
  • The corrosion inhibitive nature of a flavonoid compound, 3-Hydroxy-7-methoxy-2-phenylchromen-4-one (HMPC), the synergistic effect between HMPC and n-Tetrabutylammonium bromide (TBAB) and their adsorption behavior on mild steel in hydrochloric acid solution were studied by weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The results of weight loss study at different temperatures revealed that the inhibition efficiency increases with inhibitor concentration and decreases with increase in the temperature of the system. The electrochemical studies showed that the inhibitor acts through mixed mode of inhibition and the inhibitor molecules adsorb on the metal - solution interface forming a protective layer. The adsorption of the inhibitor molecules over the metal surface was supported by the obeyed Langmuir's adsorption isotherm, Scanning Electron Microscopic analysis (SEM) and Fourier Transform Infrared (FT-IR) spectroscopic studies.

Facile Synthesis of Co3O4/Mildly Oxidized Multiwalled Carbon Nanotubes/Reduced Mildly Oxidized Graphene Oxide Ternary Composite as the Material for Supercapacitors

  • Lv, Mei-Yu;Liu, Kai-Yu;Li, Yan;Wei, Lai;Zhong, Jian-Jian;Su, Geng
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1349-1355
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    • 2014
  • A three-dimensional (3D) $Co_3O_4$/mildly oxidized multiwalled carbon nanotubes (moCNTs)/reduced mildly oxidized graphene oxide (rmGO) ternary composite was prepared via a simple and green hydrolysishydrothermal approach by mixing $Co(Ac)_2{\cdot}4H_2O$ with moCNTs and mGO suspension in mixed ethanol/$H_2O$. As characterized by scanning electron microscopy and transmission electron microscopy, $Co_3O_4$ nanoparticles with size of 20-100 nm and moCNTs are effectively anchored in mGO. Cyclic voltammetry and galvanostatic charge-discharge measurements were adopted to investigate the electrochemical properties of $Co_3O_4$/moCNTs/rmGO ternary composite in 6 M KOH solution. In a potential window of 0-0.6 V vs. Hg/HgO, the composite delivers an initial specific capacitance of 492 $Fg^{-1}$ at 0.5 $Ag^{-1}$ and the capacitance remains 592 $Fg^{-1}$ after 2000 cycles, while the pure $Co_3O_4$ shows obviously capacitance fading, indicating that rmGO and moCNTs greatly enhance the electrochemical performance of $Co_3O_4$.