• Title/Summary/Keyword: scanning measurements

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Elastic and Superhydrophobic Monolithic Methyltrimethoxysilane-based Silica Aerogels by Two-step Sol-gel Process

  • Mahadik, D.B.;Jung, Hae-Noo-Ree;Lee, Yoon Kwang;Lee, Kyu-Yeon;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.1
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    • pp.35-39
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    • 2016
  • The flexible and superhydrophobic properties of silica aerogels are extremely important material for thermal insulation and oil spill cleanup applications for their long-term use. Flexible silica aerogels were synthesized by using a two-step sol-gel process with precursors, methyltrimethoxysilane (MTMS) followed by supercritical drying. Silica aerogels were prepared at different molar ratio of methanol to MTMS (M). It was observed that the silica aerogels prepared at M=28 were monolithic but inelastic in nature, however, for M=35, the obtained aerogels were monolithic, elastic in nature with less shrinkage. The microstructural studies were carried out using scanning electron microscopy and surface area measurements. The hydrophobicity was confirmed by Fourier transform Infrared spectroscopy and water contact angle measurements. The detailed insight mechanism for flexible nature of silica aerogels and hydrophobic behavior were studied.

Photoelectrochemical Studies of Nanocrystalline TiO₂Film Electrodes

  • Lee, Myoung-Soon;Cheon, Ik-Chan;Kim, Yeong-Il
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1155-1162
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    • 2003
  • Nanocrystalline semiconductor film electrodes have been prepared by sintering three different sizes of TiO₂ nanoparticle sols on conducting indium-tin-oxide (ITO) glass substrate. The electrochemical and photoelectrochemical properties of the prepared electrodes were comparatively investigated. The particle sizes, surface morphologies and crystallinities of the films were studied by scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. Cyclic voltammetry and capacitance measurements in the dark implies the formation of depletion layer in the semiconductor films which was usually neglected in the previous studies and shows that flat band potential ($E_{fb}$

Test of a Multilayer Dose-Verification Gaseous Detector with Raster-Scan-Mode Proton Beams

  • Lee, Kyong Sei;Ahn, Sung Hwan;Han, Youngyih;Hong, Byungsik;Kim, Sang Yeol;Park, Sung Keun
    • IEIE Transactions on Smart Processing and Computing
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    • v.4 no.5
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    • pp.297-304
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    • 2015
  • A multilayer gaseous detector has been developed for fast dose-verification measurements of raster-scan-mode therapeutic beams in particle therapy. The detector, which was constructed with eight thin parallel-plate ionization chambers (PPICs) and polymethyl methacrylate (PMMA) absorber plates, is closely tissue-equivalent in a beam's eye view. The gas-electron signals, collected on the strips and pad arrays of each PPIC, were amplified and processed with a continuous charge.integration mode. The detector was tested with 190-MeV raster-scan-mode beams that were provided by the Proton Therapy Facility at Samsung Medical Center, Seoul, South Korea. The detector responses of the PPICs for a 190-MeV raster-scan-mode proton beam agreed well with the dose data, measured using a 2D ionization chamber array (Octavius model, PTW). Furthermore, in this study it was confirmed that the detector simultaneously tracked the doses induced at the PPICs by the fast-oscillating beam, with a scanning speed of 2 m s-1. Thus, it is anticipated that the present detector, composed of thin PPICs and operating in charge.integration mode, will allow medical scientists to perform reliable fast dose-verification measurements for typical dynamic mode therapeutic beams.

Evaluation of interfacial tension for poly(methyl methacrylate) and polystyrene by rheological measurements and interaction parameter of the two polymers

  • Sung, Y.T.;Seo, W.J.;Kim, Y.H.;Lee, H.S.;Kim, W.N.
    • Korea-Australia Rheology Journal
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    • v.16 no.3
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    • pp.135-140
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    • 2004
  • Morphological and rheological properties of the poly(methyl methacrylate) (PMMA) and polystyrene (PS) blends were studied by scanning electron microscopy (SEM) and advanced rheometric expansion system (ARES). From the SEM results, the PMMA-PS blends showed dispersed morphology and the particle size of the dispersed phase was quite small (0.1~0.6 $\mu\textrm{m}$ compared with other immiscible polymer blends. Values of the interfacial tension of the PMMA-PS blend were obtained from the Choi-Schowalter and the Palierne emulsion models using the storage modulus of the PMMA and PS, and found to be 1.0 and 2.0 mN/m, respectively. The interfacial tension between the PMMA and PS was also calculated from the Flory-Huggins polymer-polymer interaction parameter ($\chi$) and found to be from 0.98 to 1.86 mN/m depending on the molecular weight and composition. Comparing the values of the interfacial tension from the Flory-Huggins polymer-polymer interaction parameter and the values measured by oscillatory rheometer, it is suggested that the interfacial tension of the PMMA-PS blend obtained from the polymer-polymer interaction parameter are in good agreement with the values obtained by rheological measurements.

Effect of Fabric Properties used for the Loop Type Decorative Elements on the 3-dimensional Shape

  • Ko, Youngmin;Kim, Jongjun
    • Journal of Fashion Business
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    • v.17 no.3
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    • pp.30-47
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    • 2013
  • In the modern fashion industry, efficiency has been increasing thanks to development of computer graphics, IT technology, and digitalization. Unlike the past when fashion design heavily depended on handwork, digitalization of fashion industry makes fabrication time shorter and enables designers to adopt comprehensive expression, generating high value-added product. The Apparel CAD, an example of the digitalized fashion industry, has been developed from 2D system into a system providing 3D simulation. Digital clothing can be determined as an activity of designers using the tool in order to fabricate pattern and simulate its designed clothes in the virtual space of computer. In this study, physical properties of eight materials, which can be utilized on a par with current fashion trend, have been specified. For more sophisticated investigation, external appearance of the material was investigated by 3D scanning. In order to examine the physical properties of fabric specimens, KES(Kawabata Evaluation System) measurements and other physical property measurements were made. With the results, virtual material and clothes were simulated via CLO 3D, one of 3D apparel CAD systems. Then, virtual fabrics and clothes of similar types were generated and analyzed.

Morphology and Rheology on the Blends of PLA/CMPS

  • Shin, Boo-Young;Jo, Gyu-Soon;Kang, Kyoung-Su;Lee, Tae-Jin;Kim, Bong-Shik;Lee, Sang-Il;Song, Jeong-Sup
    • Macromolecular Research
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    • v.15 no.4
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    • pp.291-301
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    • 2007
  • The rheological behaviors and morphologies of polylactide (PLA) and chemically modified plasticized starch (CMPS) blends were investigated. For this study, oscillatory shear flow measurements of the PLA, CMPS and their blends were performed. A scanning electron microscope (SEM) study was also conducted on the extracted extrudates of the blends. The morphology of the blend changed in relation to the composition: sphere-shaped CMPS disperse/continuous PLA, rod-like deformed CMPS phase/continuous PLA, a co-continuous structure with bridged CMPS long rods and PLA dispersed/continuous CMPS. The composition of the phase inversion could be estimated and closely coincided from the observed morphology experimental results. The rheological behavior of the blends, from oscillatory measurements, was found to vary in relation to the composition, and reflected the morphologies of the blends. PLA showed Newtonian flow behavior, while CMPS showed strong shear thinning behavior. The relationships between the morphology and rheological properties were observed in detail.

Electrochemical Properties of Carbon Nano-Tube Electrode (탄소나노튜브 전극의 전기화학적 특성)

  • Lee Dong-Yoon;Koo Bo-Kun;Lee Won-Jae;Song Jae-Sung;Kim Hyun-Ju
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.4
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    • pp.139-143
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    • 2005
  • For application of carbon nano-tube (CNT) as a counter electrode materials of dye-sensitized solar cell (DSSC), the electrochemical behavior of CNT electrode was studied, employing cyclic-voltammetry (C-V) and impedance spectroscopy. Fabrication of CNT-paste and formation of CNT-counter electrode for characteristic measurement have been carried out using ball-milling and doctor blade process, respectively. Unit cell for measurements was assembled using Pt electrode, CNT electrode, and iodine-embedded electrolyte. Field emission-scanning electron microscopy (FE-SEM) was used for structural investigation of CNT powder and electrode. Sheet resistance of electrode was measured with 4-point probe method. Electrochemical properties of electrode, C-V and impedance spectrum, were studied, employing potentiogalvanostat (EG&G 273A) and lock in amplifier (EG&G 5210). As a results, the sheet resistance of CNT electrode is almost similar to that of F-doped SnO2 (FTO) coated glass substrate as approximately 10 ohm/sq. From C-V and impedance spectroscopy measurements, it was found that CNT electrode has high reaction rate and low interface reaction resistance between CNT surface and electrolyte. These results provides that CNT electrode were superior to that of conventional Pt electrode. Particularly, the reaction rate in the CNT electrode is about thrice high than Pt electrode. Therefore. CNT electrode is to be good candidate material for counter electrode in DSSC.

Field Measurements to Predict the Wind Gust under Train at the Speed-up of Conventional Railway Lines (기존선 고속화 시 열차 하부 열차풍 예측을 위한 현장 측정 시험)

  • Kwon, Hyeok-Bin;Nam, Seong-Won;Ko, Tae-Hwan;Jeon, Byung-Kill;Kim, Man-Cheol
    • Journal of the Korean Society for Railway
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    • v.13 no.4
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    • pp.376-381
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    • 2010
  • In this study, field measurements on KTX, Nuriro and TTX train have been conducted at Kyeongbu and Honam line to predict the wind gust under train at the speed-up of major conventional railway lines using Kiel-probe array and multi-channel pressure scanning system. The results show that the average wind velocity during train passage normalized by train speed is independent to train speed, thus the wind gust for a given train type at the speed-up condition could be predicted. The relationship between the shape of underbody and the characteristics of the underbody wind gust has been discussed.

The effect of phosphate corrosion inhibitor on steel in synthetic concrete solutions

  • Sail, L.;Ghomari, F.;Khelidj, A.;Bezzar, A.;Benali, O.
    • Advances in materials Research
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    • v.2 no.3
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    • pp.155-172
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    • 2013
  • The study of the corrosion inhibition of armatures made of steel conceived for reinforced concrete by sodium phosphate is the aim object of our experimental tests. Gravimetric and electrochemical measurements were carried in three different Mediums contaminated by chlorides (3% NaCl) with addition of increasing concentrations of sodium phosphate. Inhibitory efficiency reached 80% at an optimal concentration of $7,5{\times}10^{-3}M$, the results obtained using the gravimetric measurements are in good agreement with those obtained by electrochemical methods. However, the monitoring of the pH evolution after 24h shows in the three studied environments, that the pH decreases slightly at 24 hours from the initial pH at $t_0$, due to the presence of corrosion products which change the state of the final solution. Also, scanning electron microscopy revealed the existence of layers of apatite on the metal surface previously treated with the sodium phosphate which confirms the formation of a protective film around the surface of the metal.

The Enhancement of Antenna Near-Field Measurements Using Near-Field to Far-Field Transform Algorithms Based on the Lorentz Reciprocity Theorem (로렌츠 상호작용 원리와 근역장-원역장 변환 공식을 이용한 안테나 근역장 측정 알고리즘 개선)

  • Cho, Yong-Heui
    • The Journal of the Korea Contents Association
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    • v.6 no.2
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    • pp.51-58
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    • 2006
  • The enhancement of antenna near-field measurements is obtained using a general probe compensation equation based on the Lorentz reciprocity theorem and reciprocity notation. The probe compensation is an essential process of the near-field to far-field transformations. Applying the equation proposed in this paper to a planar scanning for a rectangular horn antenna shows that our near-field radiation pattern is similar to that of a far-field and our theory is very simple to use and suitable for most practical applications.

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