• Title/Summary/Keyword: saturation coefficient

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Fabrication, characterization, simulation and experimental studies of the ordinary concrete reinforced with micro and nano lead oxide particles against gamma radiation

  • Mokhtari, K.;Kheradmand Saadi, M.;Ahmadpanahi, H.;Jahanfarnia, Gh.
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.3051-3057
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    • 2021
  • The concrete is considered as an important radiation shielding material employed widely in nuclear reactors, particle accelerators, laboratory hot cells and other different radiation sources. The present research is dedicated to the shielding properties study of the ordinary concrete reinforced with different weight fractions of lead oxide micro/nano particles. Lead oxide particles were fabricated by chemical synthesis method and their properties including the average size, morphological structure, functional groups and thermal properties were characterized by XRD, FESEM-EDS, FTIR and TGA analysis. The gamma ray mass attenuation coefficient of concrete composites has been calculated and measured by means of the Monte Carlo simulation and experimental methods. The simulation process was based on the use of MCNP Monte Carlo code where the mass attenuation coefficient (μ/ρ) has been calculated as a function of different particle sizes and filler weight fractions. The simulation results showed that the employment of the lead oxide filler particles enhances the mass attenuation coefficient of the ordinary concrete, drastically. On the other hand, there are approximately no differences between micro and nano sized particles. The mass attenuation coefficient was increased by increasing the weight fraction of nanoparticles. However, a semi-saturation effect was observed at concentrations more than 10 wt%. The experimental process was based on the fabrication of concrete slabs filled by different weight fractions of nano lead oxide particles. The mass attenuation coefficients of these slabs were determined at different gamma ray energies using 22Na, 137Cs and 60Co sources and NaI (Tl) scintillation detector. The experimental results showed that the HVL parameter of the ordinary concrete reinforced with 5 wt% of nano PbO particles was reduced by 64% at 511 keV and 48% at 1332 keV. Reasonable agreement was obtained between simulation and experimental results and showed that the employment of nano PbO particles is more efficient at low gamma energies up to 1Mev. The proposed concrete is less toxic and could be prepared in block form instead of toxic lead blocks.

Effects of Temperature and Saturation on the Crystal Morphology of Aragonite (CaCO3) and the Distribution Coefficient of Strontium: Study on the Properties of Strontium Incorporation into Aragonite with respect to the Crystal Growth Rate (온도와 포화도가 아라고나이트(CaCO3)의 결정형상과 스트론튬(Sr)의 분배계수에 미치는 영향: 결정성장속도에 따른 아라고나이트 내 스트론튬 병합 특성 고찰)

  • Lee, Seon Yong;Chang, Bongsu;Kang, Sue A;Seo, Jieun;Lee, Young Jae
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.2
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    • pp.133-146
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    • 2021
  • Aragonite is one of common polymorphs of calcium carbonate (CaCO3) and formed via biological or physical processes through precipitation in many different environments including marine ecosystems. It is noted that aragonite formation and growth as well as the substitution of trace elements such as strontium (Sr) in the aragonite structure would be dependant on several key parameters such as concentrations of chemical species and temperature. In this study, properties of the incorporation of Sr into aragonite were investigated over a wide range of various saturation conditions and temperatures similar to the marine ecosystem. All pure aragonite samples were inorganically synthesized through a constant-addition method with varying concentrations of the reactive species ([Ca]=[CO3] 0.01-1 M), injection rates of the reaction solution (0.085-17 mL/min), and solution temperatures (5-40 ℃). Pure aragonite was also formed even under the Sr incorporation conditions (0.02-0.5 M, 15-40 ℃). When temperature and saturation index (SI) with respect to aragonite increased, the crystallinity and the crystal size of aragonite increased indicating the growth of aragonite crystal. However, it was difficult to interpret the crystal growth rate because the crystal growth rate calculated using BET-specific surface area was significantly influenced by the crystal morphology. The distribution coefficient of Sr (KSr) into aragonite decreased from 2.37 to 1.57 with increasing concentrations of species (Ca2+ and CO32-) at a range of 0.02-0.5 M. Similarly, it was also found that KSr decreased 1.90 to 1.54 at a range of 15-40 ℃. All KSr values are greater than 1, and the inverse correlation between the KSr and the crystal growth rate indicate that Sr incorporation into aragonite is in a compatible relationship.

Optimization and kinetic modeling for bioconversion of cheese whey to Ganoderma lucidum in batch fermentations

  • Song, Min-Gyeong;Lee, Hwan-Yeong;Hwang, Seok-Hwan
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.381-384
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    • 2002
  • Response surface methodology (RSM) was successfully applied to optimize for the production of Ganoderma lucidum in batch fermentations using the whey (40,000 mg latose/L) as substrate. This study was performed according to the central composite design (CCD) with respect to pH and temperature, where the designed intervals were 3.3$22.9^{\circ}C$$37.1^{\circ}C$, respectively. A second-order factorial design of the experiments was used to build empirical models providing a quantitative interpretation of the relationships between the two variables. The optimum conditions to maximize the production of G. lucidum were pH 4.2 and $28.3^{\circ}C$. At optimum conditions, the mycelial dry weight (MDW) and residual soluble COD (SCOD) were simultaneously used to evaluate the biokinetic coefficients assocoated with substrate inhibition model by nonlinear least squares method with 95% confidence interval. The. maximum microbial growth rates (${\mu}m$), half saturation coefficient ($K_s$), and the inhibition substrate concentration ($K_{is}$) were determined to be 0.095 l/hr, 128,000 mg SCOD/L and 49,000 mg SCOD/L, respectively. And the microbial yield coefficient (Y), biomass decay rate coefficient ($K_d$), and the maintenance energy coefficient ($m_s$) were determined to be 0.37 mg MDW/mg SCOD, 0.001 1/hr, and 0.0015 1/hr, respectively.

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Theoretical Analysis of Heat Transport Limitation in a Screen Mesh Wick Heat Pipe

  • Lee, Ki-Woo;Park, Ki-Ho;Lee, Wook-Hyun;Rhi, Seok-Ho
    • International Journal of Air-Conditioning and Refrigeration
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    • v.12 no.1
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    • pp.1-9
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    • 2004
  • The purpose of the present study is to examine the heat transport limitations in a screen mesh heat pipe for electronic cooling by theoretical analysis. Diameter of pipe was 6mm, and mesh numbers were 50, 100, 150, 200 and 250, and water was investigated as working fluid. According to the change of mesh number, wick layer, inclination and saturation temperature, the maximum heat transport limitations by capillary, entraintment, sonic and boiling were analyzed by a theoretical design method of heat pipe, including capillary pressure, pumping pressure, liquid friction coefficient in wick, vapor friction coefficient, etc. Based on the results, the capillary limitation in a small diameter of heat pipe is largely affected by mesh number and wick layer. Mesh number of 250 is desirable not to be used in pipe diameter of 6 mm, because capillary heat transport limitation decreases by the abrupt increase of liquid friction pressure due to the small liquid flow area. For the heat transport of 15 watt in 6mm diameter pipe, mesh number of 100 and one layer is an optimum wick condition, which thermal resistance is the smallest.

Kinetic Analysis for Paper-mill Wastewater Treatment Using Pure Oxygen Activated Sludge Process (순산소 활성오니공정을 이용한 제지폐수처리의 동력학적 해석)

  • Kim, Sung Soon;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.2
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    • pp.157-163
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    • 2000
  • An experimental study was conducted to evaluate the treatment efficiency of paper-mill wastewater using pure oxygen activated sludge process. Effects of hydraulic retention time (HRT) and organic loading on process performance and kinetics were investigated. The raw paper-mill wastewater(BOD concentration ${\leq}500mg/L$) and the effluent from dissolved air flotation(DAF) treatment(BOD concentration ${\geq}500mg/L$) were used as influent for pure oxygen activated sludge process. Average BOD removal efficiencies were above 89.3% under 6hours or longer of HRT, while under 3hours of HRT they decreased to about 82%. With the effluent from DAF process, the half saturation constants($K_S$) and the maximum specific substrate removal rate($K_{max}$) were 85 mg/L and 2.25 L/day, respectively. However, with the raw paper-mill wastewater, both $K_S$ and $K_{max}$ increased to 156 mg/L and 3.84 L/day, respectively. The microbial yield coefficient(Y) and the decay coefficient($K_d$) were 0.46 gVSS/gBOD and 0.03 L/day, respectively, with effluent from DAF process. While, Y and $K_d$ were 0.24 gVSS/gBOD and 0.035 L/day, respectively, with the raw paper-mill wastewater.

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A Study on the Improement of Condensation and Boiling Heat Transfer on Horizontal Tube by Fin Effect(ll)-Shellside Condensation- (수평 원형전열관의 핀효과에 의한 응축 및 비등 열전달촉진에 관한 연구 (2)-튜브외부 응축-)

  • 한규일;조동현
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.5
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    • pp.1275-1287
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    • 1994
  • Heat transfer performance improvement by fin and grooves is studied for condensation of R-11 on integral-fin tubes. Eight tubes with trapezoidal shaped integral-fins having fin densities from 748 to 1654 fpm and 10, 30 grooves are tested. A plain tube having the same diameter as the finned tubes is also tested for comparison. R-11 condenses at saturation state of $32^{\circ}C$ on the outside tube surface cooled by inside water flow. All of test data ate taken at steady state. Beatty and Katz's, Rudy's and Webb's theoretical models are used to predict the R-11 condensation coefficient of tubes having 748, 1024 and 1299 fpm. The predicted value by Betty and Katz's model is within 10% of experimental values in this study at fpm<1024 and Rudy's model predicted the experimental data at fpm>1024 within 15%. The tube having fin density of 1299 fpm and 30 grooves has the best overall heat transfer performance. This tube shows the overall heat transfer coefficient of 11500 $W/m^{2}K$,/TEX> at coolant velocity of 3.0m/s.

Treatment of Wastewater from Acetaldehyde Plant by Activated Sludge Process (활성슬러지 공정에 의한 Acetaldehyde 제조 공장 폐수의 처리)

  • Suh, Seung-Kyu;Kim, Jung-Ho;Kim, Young-Ho
    • Journal of Environmental Science International
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    • v.6 no.3
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    • pp.259-265
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    • 1997
  • This study was conducted to Investigate the treatment of wastewater from acetaldehyde manufacturing plant by activated sludge process with Micrococcus roseus AW-6, Micrococcus roseus AW-22, Microbacterium lacticum AW-38 and Mlcrobacterium nae- vaniformans AW-41. The $COD_{Mn}$ and $BOD_5$ of the wastewater were 5, 260mg/L and 6, 452mg/L, respectively. pH was 1.85. The main organic component in the wastewater was acetic acrid which was contained 67, 600mg/L. Optimum dilution time for activated sludge process was shown 10 times. The specific substrate removal rate(BL) was 1.95day-1 and the nonbiodegradable matters(Sn) were 23.2mg/L. Saturation constant (Ks) and mainmum specific growth rate(qmax) were 1, 640mg/L and 2.33day-1, respectively. Sludge yield coefficient(Y) and endogenous respiration coefficient(kd) were 0.28mg MLVSS/mgCOD and 0.02day-1, respectively. $COD_{cr}$ removal efficiency was 91% for 1.95day of hydraulic retention time.

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A Study on Finned Tube Used in Turbo Refrigerator(II) - on boiling heat transfer - (터보 냉동기용 핀 튜브에 관한 연구(II) - 비등 열전달에 관하여 -)

  • Han, Kyu-Il;Kim, Si-Young;Cho, Dong-Hyun
    • Journal of Fisheries and Marine Sciences Education
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    • v.5 no.2
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    • pp.119-127
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    • 1993
  • This work studies for heat transfer and pressure drop performance of integral inner and outer fin tubes, designed to enhance the heat transfer performance of smooth tubes for in recipro and turbo refrigerator or high performance compact heat exchangers. Eight different inner spiral fin copper tubes with integral fin at outside surfaces were employed to improve boiling heat transfer coeffcient. For comparison, tests were made using a plain tube having the inside diameter and an outside diameter equal to that at the root of the fins for the finned tubes. Pool boiling heat transfer is investigated experimentally and theoretically on single tube arrangement. The refrigerant evaporates at a saturation state of 1 bar on the outside tube surface heated by hot water. The refrigerant R11 ($CFCl_3$) was used at a pressure of $P_s=1bar$ as a convenient test fluid with a boiling temperature of $T_s=23.6^{\circ}C$. The observed heat transfer enhancement of boiling for finned tubes significantly exceeded that to be expected on grounds of increased area. The maximum Vapor - side enhancement(i.e., vapor - side heat transfer coefficient of finned tube/vapor - side coefficient for plain tube) was found to be around 4 at 1299fpm - 30grooves tube.

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A Study on the Characteristics of the MgO Thin Film Deposited by the Hollow Cathode Discharge Ion Plating Method (HCD 이온 플레이팅법에 의해 증착된 MgO박막의 특성에 관한 연구)

  • Chung, Woo-Joon;Jeong, Heui-Seob;Whang, Ki-Woong
    • Proceedings of the KIEE Conference
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    • 1996.11a
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    • pp.200-202
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    • 1996
  • MgO film was deposited on the glass substrate by the hollow cathode discharge ion plating method and the characteristics of the MgO thin film such as deposition rate, crystalline orientation, surface morphology and secondary electron coefficient were investigated. The deposition rate of MgO thin films were $430^{\sim}1270{\AA}$/min at various temperatures and biases. The crystalline orientation of the MgO thin film changed from (200) to (220) upon increasing the HCD current from 100A to 200A. These results indicated that the crystallin orientation of the MgO thin film was determined by the super-saturation ratio. The (200) peak decreased and the (220) peak increased as the substrate bias increased, while both peaks increased as the substrate temperature increased. The grain size increased as the substrate bias increased and the secondary electron emission coefficient increased as the substrate bias increased.

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Kinetic Studies on Submerged Acetic Acid Fermentation of Acetobacter aceti (Acetobacter aceti균의 심부배양에 의한 초산발효의 동력학적 연구)

  • KIM Sang-Moo;LEE Keun-Tai
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.25 no.4
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    • pp.301-306
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    • 1992
  • In order to determine the optimal conditions for the process of acetic acid fermentation, the kinetics of Acetobacter aceti fermentation in submerged batch cultures were studied at different agitation speeds and air flow rates. The maximum cell concentration was noted after about 48 hr fermentation and the time course of Acetobactey aceti fermentation showed a distinct feature of growth-associated product formation. At agitation speeds 700, 500, and 300 rpm fixed on air flow rate 1 v/v/M, specific grow rates were $3.97\times10^{-2},\;3.82\times10^{-2},\;and\;2.04\times10^{-2\} \;hr^{-1}$, saturation constants were 61.4, 64.6, and 69.4mg/ml. and volumetric oxygen transfer coefficients were 0.9337, 0.4468, and 0.1701 $min^{-1},$ respectively. At air flow rates 1.25, 1.00, and 0.75 v/v/M fixed on agitation speed 500 rpm, specific growth rates were $3.90\times10^{-2},\;3.82\times10^{-2},\;and\;2.37\times10^{-2}\;hr^{-1}$, saturation constants were 63.4, 64.6, and 64.9 mg/ml, and volumetric oxygen transfer coefficient were 0.4923, 0.4468, and 0.3509 $min^{-1},$ respectively.

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