• Title/Summary/Keyword: saturated solution

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Manufacture and Properties of Gypsum-Wood (Gypsum-Wood의 제조와 성질)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.19 no.1
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    • pp.83-90
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    • 2008
  • Gypsum-wood composites were made by introducing inorganic substances into wood using calcium chloride, first treating solution, and sodium sulfate, secondary treating solution, by double diffusion process under atmospheric pressure at room temperature. The process conducted as follows: water saturated specimens were soaked in calcium chloride solutions at several concentration. Then the specimens were soaked further in saturated sodium sulfate solution, and they were leached in flowing tap water for 24h. To attain sufficient weight percent gain (WPG) values, the suitable concentration of calcium chloride and soaking time in saturated sodium sulfate solution were 20% and 48h, respectively. Inorganic substances were produced mainly in the lumina of tracheides. It was made sure that these substances were dihydrate gypsum($CaSO_4$ $2H_2O$) by X -ray microanalysis (SEM-EDX). The composites had good fire resistance due to low heat transfer rate of gypsum formed in wood. However, the composites had little decay resistances, because they showed high weight losses by test fungi attacks.

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Remediation of Diesel-Contaminated Soil by Fenton and Ozone Oxidation Process (펜톤과 오존산화공정을 이용한 디젤오염토양의 복원)

  • Choi, Hee-Chul;Lee, Kwan-Yong;Choi, Sang-Il;Lee, Tae-Jin
    • Journal of Soil and Groundwater Environment
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    • v.15 no.2
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    • pp.34-39
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    • 2010
  • In this study, the remediation of diesel contaminated soil was attempted with ozone treatment and Fenton reaction. About 10% of initial diesel concentration was removed by the ozone saturated solution. The pseudo-first order decomposition constant of diesel contaminated soil in the presence of 5% of hydrogen peroxide with 1.82, 2.82, 4.82, 6.82, and 11.82% of iron contents was 0.0228, 0.0308, 0.0482, 0.0471, and 0.0592 $min^{-1}$ respectively. The decomposition constant of the diesel was 0.0064 $min^{-1}$ with the addition of ozone saturated solution only. On the addition of ozone saturated solution in the presence of 5% hydrogen peroxide and 5% iron, the decomposition constant of the diesel was 0.0850 $min^{-1}$. These results indicated that the decomposition rate was 190% faster than without the addition of ozone saturated solution. Thus, the application of both ozone and the fenton reaction is promising for the remediation of the diesel contaminated soil.

Wave Propagation Characteristics in Saturated Porous Media I. Theoretical Solution (포화된 다공성매체에서 파동의 전파특성 I. 이론해의 유도)

  • Kim, Sun-Hoon;Kim, Kwang-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.20 no.2
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    • pp.95-103
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    • 2007
  • An analytical closed-form solution for wave propagation velocity and damping in saturated porous media is presented in this paper The fully coupled field model with compressible solid Brains and pore water were used to derive this solution. An engineering approach for the analysis of fully saturated porous media was adopted and closed-form solutions for one dimensional wave propagation in a homogeneous domain were derived. The solution is highly versatile in that it considers compression of the solid grains, compression of the pore water, deformation of the porous skeleton, and spatial damping and can be used to compute wavespeeds of first and second kind and damping coefficients in various geologic materials. This solution provides a means of analyzing the influence of material property variations on wavespeed and attenuation. In Part 2 of this work the theoretical solution is incorporated into the numerical code and the code is used in a parametric study on wave propagation velocity and damping.

Determination of moisture threshold for solution sampling in different soil texture (토양용액 채취를 위한 토성별 한계수분함량 설정)

  • Lee, Chang Hoon;Kim, Myung Sook;Kong, Myung Seok;Kim, Yoo Hak;Oh, Taek-Keun;Kang, Seong Soo
    • Korean Journal of Agricultural Science
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    • v.41 no.4
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    • pp.399-404
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    • 2014
  • Soil moisture is an important factor for the availability and circulation of nutrients in arable soil. The purpose of this study was to set thresholds moisture content on soil nitrate concentration in the solution for real-time diagnosis. Sandy loam, silt loam, and sandy loam was filled with $1.2g\;cm^{-3}$ at Wagner pots, 0, 100, and $200mg\;L^{-1}$ of $KNO_3$ was saturated. Nitrate in standard solution was recovered about 95% by passing the porous cup. Nitrate concentrations in sampling of soil solution were examined by using a porous cup. The soil solution was higher in accordance with sandy loam> silt loam> clay loam, limited water filled pore space for sampling soil solution was 33.7, 56.4, and 62.2%, respectively. Nitrate concentration in the soil solution was negligible at sandy loam and silt loam during sampling periods, which was decreased about 50~82% in clay loam compared to the initial $NO_3$-N concentration in the saturated $KNO_3$ solution. Over limitation of soil solution sampling, soil EC and $NO_3$-N content were increased with the saturated $NO_3$-N concentration, regardless of soil texture (p<0.05). Conclusively, soil solution by using a porous cup was possible, regardless of the soil texture, which was useful for the diagnosis in nitrate concentration of soil solution. However, because nitrate concentration of soil solution in a clay loam changes, it was necessary for careful attention in order to take advantage for the real-time diagnosis of nitrogen management in soil.

Modelling of chloride diffusion in saturated concrete

  • Tsao, Wen-Hu;Huang, Nai-Ming;Liang, Ming-Te
    • Computers and Concrete
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    • v.15 no.1
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    • pp.127-140
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    • 2015
  • The process of chloride ingress in saturated concrete was presented by a previous study that used a mathematical model for the same as that concrete. This model is to be studied chloride ion diffusion which is considered as a chemical phenomenon and is to be represented the chloride diffusion process to be a nonlinear partial differential equation (PDE). In this paper, this nonlinear PDE is solved by the Kirchhoff transformation to render into a linear PDE. This linear PDE associated with initial and boundary conditions is also solved by the Laplace transformation to obtain an analytical solution. To verify the serviceability and reliability of this proposed method, the practical application should be supplied. The input parameters were cited from the previous study. The free chloride concentration profiles obtained by the analytical solution of mathematical model for saturated concretes after 24 and 120 hrs of exposure were compared with the previous study. The predicted results obtained from proposed method have a tendency with experimental results obtained by the previous study and trend toward numerical results approximated by finite difference technique.

Coupled Finite Element Analysis for Semi-implicit Linear and Fully-implicit Nonlinear Scheme in Partially Saturated Porous Medium

  • Kim, Jae-Hong;Regueiro, Richard A.
    • Land and Housing Review
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    • v.1 no.1
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    • pp.59-65
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    • 2010
  • The paper presents a comparison between a semi-implicit time integration linear finite element implementation and fully-implicit nonlinear Newton-Raphson finite element implementation of a triphasic small strain mixture formulation of an elastic partially saturated porous medium. The pore air phase pressure pa is assumed atmospheric, i.e., $p_a$ = 0, although the formulation and implementation are general to handle increase in pore air pressure as a result of loading, if needed. The solid skeleton phase is assumed linear isotropic elastic and partially saturated 'consolidation' in the presence of surface infiltration and traction is simulated. The verification of the implementation against an analytical solution for partially saturated pore water flow (no deformation) and comparison between the two implementations is presented and the important of the porosity-dependent nature of the partially saturated permeability is assessed on comparison with a commercial code for the partially saturated flow with deformation. As a result, the response of partially saturated permeability subjected to the porosity influences on the saturation of a soil, and the different behaviors of the partially saturated soil between staggered and monolithic coupled programs is worth of attention because the negative pore water pressure in the partially saturated soil depends on the difference.

Synthesis of Fibrous Gypsum from By-Product Gypsum fo Phosphoric Acid Process (인산 석고로부터 섬유상 반수석고의 생성)

  • 배동식;이구종;최상흘
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.577-582
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    • 1990
  • The synthesis conditions of fibrous calcium sulfate hemihydrate were investigated by using phosphogypsum and calcium sulfate hemihydrate. The unstable organogel was deposited by adding methanol to the saturated solution with gypsum at ageing temperature, and it was crystallized to fibrous gypsum hemihydrate while methanol was removed by rapid filtrating. In case of using calcium sulfate hemihydrate, fibrous $\beta$-calcium sulfate hemihydrate was formed by adding methanol of 67% to saturated solution at 6$0^{\circ}C$ and ageing for 5 minutes and filtering with suction. Minor components in phosphogypsum did not affect the reaction.

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Photolysis of Aqueous Ammonia in the Absence and the Presence of O₂

  • 박형련;김희정;성아영
    • Bulletin of the Korean Chemical Society
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    • v.17 no.9
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    • pp.798-802
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    • 1996
  • The photochemical decomposition of aqueous ammonia in the absence (saturated with argon) and the presence of O2 (saturated with air or oxygen) has been investigated using 184.9 nm UV light. The decomposition of ammonia depended on the concentration of oxygen in the solution. With increasing the concentration of oxygen, the decomposition of ammonia diminishes. Hydrazine is found the major product from the irradiation. In the presence of oxygen, hydrogenperoxide was also produced. The product yields depended also on the concentration of oxygen in the solution. The initial quantum yield of the products and of the ammonia decomposed were determined. Probable reaction mechanisms for the reaction were presented from the products analysis.

Heat Transfer Analysis of Freezing Processes Including Thermal Resistance of Mold(I) - One - dimensional Analysis of Saturated Liquid - (용기를 고려한 응고과정의 열전달 해석(I) - 포화액의 일차원 해석 -)

  • Yoo, Jai Suk
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.4
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    • pp.377-381
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    • 1988
  • Effects of thermal resistance of mold during freezing processes have been investigated. Saturated liquid is chosen to present one-dimensional quasi-steady solution and this solution is compared with numerical solutions. Front tracking finite element method has been applied for the numerical solutions. Results show that mold should be considered as well as phase change material except the cases when the very thin mold with relatively high thermal conductivity is used.

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Dicyanoanthracene and Biphenyl Co-sensitized Photooxygenation of 1,1-Diphenyl-2-vinylcyclopropane

  • Shim, Sang-Chul;Song, Jeong-Sup
    • Bulletin of the Korean Chemical Society
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    • v.7 no.2
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    • pp.150-153
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    • 1986
  • Co-sensitized photooxygenation of 1,1-diphenyl-2-vinylcyclopropane (VCP-DPh) with 9,10-dicyanoanthracene and biphenyl in oxygen-saturated acetonitrile solution produced 3,3-diphenyl-5-vinyl-1,2-dioxolane as the major product. The same photoproduct was obtained by acetone sensitized photooxygenation in oxygen-saturated acetone solution. However, VCP-DPh remained intact when directly irradiated with DCA or irradiated with Rose Bengal to generate singlet oxygen. A mechanism involving a cosensitizer radical cation and sensitizer radical anion is proposed.