• Title/Summary/Keyword: saturated clay

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Geology of Athabasca Oil Sands in Canada (캐나다 아사바스카 오일샌드 지질특성)

  • Kwon, Yi-Kwon
    • The Korean Journal of Petroleum Geology
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    • v.14 no.1
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    • pp.1-11
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    • 2008
  • As conventional oil and gas reservoirs become depleted, interests for oil sands has rapidly increased in the last decade. Oil sands are mixture of bitumen, water, and host sediments of sand and clay. Most oil sand is unconsolidated sand that is held together by bitumen. Bitumen has hydrocarbon in situ viscosity of >10,000 centipoises (cP) at reservoir condition and has API gravity between $8-14^{\circ}$. The largest oil sand deposits are in Alberta and Saskatchewan, Canada. The reverves are approximated at 1.7 trillion barrels of initial oil-in-place and 173 billion barrels of remaining established reserves. Alberta has a number of oil sands deposits which are grouped into three oil sand development areas - the Athabasca, Cold Lake, and Peace River, with the largest current bitumen production from Athabasca. Principal oil sands deposits consist of the McMurray Fm and Wabiskaw Mbr in Athabasca area, the Gething and Bluesky formations in Peace River area, and relatively thin multi-reservoir deposits of McMurray, Clearwater, and Grand Rapid formations in Cold Lake area. The reservoir sediments were deposited in the foreland basin (Western Canada Sedimentary Basin) formed by collision between the Pacific and North America plates and the subsequent thrusting movements in the Mesozoic. The deposits are underlain by basement rocks of Paleozoic carbonates with highly variable topography. The oil sands deposits were formed during the Early Cretaceous transgression which occurred along the Cretaceous Interior Seaway in North America. The oil-sands-hosting McMurray and Wabiskaw deposits in the Athabasca area consist of the lower fluvial and the upper estuarine-offshore sediments, reflecting the broad and overall transgression. The deposits are characterized by facies heterogeneity of channelized reservoir sands and non-reservoir muds. Main reservoir bodies of the McMurray Formation are fluvial and estuarine channel-point bar complexes which are interbedded with fine-grained deposits formed in floodplain, tidal flat, and estuarine bay. The Wabiskaw deposits (basal member of the Clearwater Formation) commonly comprise sheet-shaped offshore muds and sands, but occasionally show deep-incision into the McMurray deposits, forming channelized reservoir sand bodies of oil sands. In Canada, bitumen of oil sands deposits is produced by surface mining or in-situ thermal recovery processes. Bitumen sands recovered by surface mining are changed into synthetic crude oil through extraction and upgrading processes. On the other hand, bitumen produced by in-situ thermal recovery is transported to refinery only through bitumen blending process. The in-situ thermal recovery technology is represented by Steam-Assisted Gravity Drainage and Cyclic Steam Stimulation. These technologies are based on steam injection into bitumen sand reservoirs for increase in reservoir in-situ temperature and in bitumen mobility. In oil sands reservoirs, efficiency for steam propagation is controlled mainly by reservoir geology. Accordingly, understanding of geological factors and characteristics of oil sands reservoir deposits is prerequisite for well-designed development planning and effective bitumen production. As significant geological factors and characteristics in oil sands reservoir deposits, this study suggests (1) pay of bitumen sands and connectivity, (2) bitumen content and saturation, (3) geologic structure, (4) distribution of mud baffles and plugs, (5) thickness and lateral continuity of mud interbeds, (6) distribution of water-saturated sands, (7) distribution of gas-saturated sands, (8) direction of lateral accretion of point bar, (9) distribution of diagenetic layers and nodules, and (10) texture and fabric change within reservoir sand body.

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Hydrogeochemistry and Contamination of Meteoric Water at the Narim Mine Creek, Korea (나림광산 수계에 분포하는 순환수의 수문지구화학 및 오염)

  • 이찬희
    • Economic and Environmental Geology
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    • v.32 no.4
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    • pp.385-398
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    • 1999
  • The Narim gold mine is located approimately 200km southeast of Seoul within the Muju mineralized district of the Sobaegsan gneiss complex, Korea. Environmental geochemistry were undertaken for various kinds of water (surface, ground and mine water) collected of April, September and November in 1998 from the narim mine creek. Hydrogeochemical compositions of water samples are characterized by the relatively significant enrichment of Na+K, alkali ions, $HCO_{3}$, $NO_{3}$, Cl and F in groundwater, wheras the mine and surface waters are relatively enriched in Ca+Mg, hea표 metals and $SO_{4}$. Therefore, the groundwaters belong to the (Na+Ca)-( $HCO_{3}+SO_{4}$) type, respectively. The pH and EC values of the non-mining creek surfers are relatively lower compared with those of the surface water of the mine and ore dump area. The d values ($\delta$D-8$\delta^{18}$O) of all kinds of water from the Narim mine creek are 5.8 to 13.1 The range of $\delta$D and $\delta^{18}$O values (relative to SMOW) are shown in distinct two groups as follows: for the April waters of -64.8 to -67.8$\textperthousand$ and -9.6 to -10.0$\textperthousand$(d value=10.1 to 13.1), and for the November waters of -65.9 to -70.2$\textperthousand$ and -9.3 to -9.6$\textperthousand$ (d value=5.8 to 7.9), respectively. This range variation indicates that two group water were composed of distinct waters with seasonal difference. Geochemical modeling showed that mostly toxic metals (As, Fe, Mn, Ni, Pb, Zn) may exist largery in the from of metal $(M2^+)$ and metal-sulfate $(MSO_4\;^{2-$\mid$),\; and \;SO_4^{2-$\mid$}$ concentration influenced the speciation of heavy metals in the meteoric water. These metals in the groundwater could be formed of $CO_3 \;and \;(OH)_3$ complex ions. Using computer program, saturation index of albite, calcite, dolomite in meteoric water show undersaturated and progreddively evolved toward the saturation state, however, ground and mine water are nearly saturated. The gibbsited water-mineral reaction and stabilities suggest that the weathering of silicate minerals may be stable kaolinite, illite and Nasmectite. The clay minerals will be transformed to more stable kaolinite owing to the contiunous reaction.

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Investigation of Soil Physico-chemical Properties in Saemangeum Reclaimed Tidal Land in Korea

  • Ahn, Byung-Koo;Lim, Yeon-Yi;Ko, Do-Young;Lee, Chang-Kyu;Kim, Jin-Ho;Song, Young-Ju;Lee, Jin-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.4
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    • pp.347-354
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    • 2016
  • This study was conducted to investigate the physical and chemical properties of soils in Saemangeum reclaimed lands. The investigated areas were total 5,020 ha which included 220 ha for Agricultural Life site, 2,450 ha for Tourism & Leisure site, 1,130 ha for Industrial & Research site, 820 ha for Bioenergy crop production site, and 400 ha for Rural City site. Soil samples consisting of the upper 20 cm from the surface were collected in every $200m{\times}500m$ of the each site in March and September, 2015. Particle size distribution of soils in the reclaimed land was 83.2% sand, 8.6% silt and 8.2% clay in average. Soil texture was distributed as 40.8% sandy soil, 35.5% loamy sand, and 19.7% sandy loam. Based on the investigation of soil chemical properties conducted in March, 2015, soil pH, electrical conductivity of a saturated soil paste extract (ECe), and exchangeable (Exch.) $K^+$ and $Mg^{2+}$ concentrations were higher than those of the optimum levels for upland soil, whereas soil organic matter content, available (Avail.) phosphate concentration, and Exch. $Ca^{2+}$ concentration were lower than those of the optimum ranges. Depending on the results of the soil chemical properties measured in September, 2015, soil pH, ECe, and Exch. $K^+$ concentration were higher than those of the optimum levels, but soil organic matter, Avail. phosphate, and Exch. $Ca^{2+}$ concentration were lower than the optimum ranges. In addition, distribution of sodic soil ranged between 41.4% and 50.0%, and saline soils were from 16.4 to 31.8%. Soils with pH values above 7.0 increased from 15.3% in March to 35.2% in September. Soils with ECe values over $4.8dS\;m^{-1}$ increased from 45.6% to 50.7%, whereas soils with the values below $2.0dS\;m^{-1}$ decreased from 42.8% to 36.9%.

Physical Property Factors Controlling the Electrical Resistivity of Subsurface (지반의 전기비저항을 좌우하는 물성요인)

  • Park Sam-Gyu
    • Geophysics and Geophysical Exploration
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    • v.7 no.2
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    • pp.130-135
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    • 2004
  • This paper describes the physical properties of the factors controlling the electrical resistivity of the subsurface. Resistivities of various types of soil and rock samples saturated with sodium chloride solutions having nine different concentrations were measured, and the measured resistivities of these samples were compared with calculated resistivities obtained using the conventional empirical formulas. From the results obtained, we observed that the resistivity of the soil and rock samples increases with increasing in pore-fluids resistivity regardless of the media type. However, between 20 and 200 ohm-m, which is the normal range of resistivity of groundwater, the resistivity of the pore-fluids have little or no effect on the resistivities of the samples used. Below 10 ohm-m, the resistivities of the samples are mainly controlled by the pore-fluids, whereas, in the normal range of resistivity of groundwater, the sample resistivities are controlled by their intrinsic matrix resistivity more than by the pore-fluids resistivity. Also, the measured resistivity of rock and soil samples having more than $20\%$ clay contents showed a good agreement with the calculated resistivity using the parallel resistance model whereas, the calculated resistivities of glass beads correlate with that obtained using Archie's formula. When the pore-fluid resistivity is high, the computation of the resistivity values of the samples using the Archie's formula could not be carried out. Through this study, we were able to confirm that the tests are only applicable to the parallel resistance model considering the intrinsic matrix resistivity within the normal resistivity range of groundwater in the subsurface.

Mineralogical Characteristics of Tachylite occurring in Basic Dike, Basaltic Agglomerate Formation, Ulleung Island and Its Implications of Volcanic Activity (울릉도의 하부층 현무암질 집괴암 층내 염기성 암맥에서 산출되는 타킬라이트의 광물학적 특성과 화산학적 의미)

  • Bae, Su-Gyeong;Choo, Chang-Oh;Jang, Yun-Deuk
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.63-76
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    • 2012
  • Tachylite, black basaltic glass formed by the rapid cooling of molten basalt, locally occurs at the Basaltic Agglomerate Formation (BAF), the lowest formation of Ulleung Island. The purposes of this study are to characterize the occurrence and mineralogy of tachylite and to elucidate its formation condition, with emphasis on its fracture pattern, which can serve as implications for the early volcanic activity of Ulleung Island. To this end, we investigated the occurrence pattern of tachylite in the field and carried out mineralogical analyses using optical microscope, XRD, EPMA, and SEM. Tachylite occurs at the chilled margin of basic dikes which are distributed in Naesujeon, Dodong and Jeodong seasides, Turtle Rock, and Yaerimwon, whose widths vary from several cm to 10 cm. It is evident that the outer surface of tachylite is dense and smooth, whereas the inner surface, if fractured, is characterized by conchoidal fracture. The matrix of tachylite consists of amorphous, glass and some fine-grained phenocrysts present in tachylite include biotite, anorthoclase, sanidine, plagioclase, hornblende, and Fe-Ti oxides. The fracture patterns characteristic of tachylite are subrounded, oval, or less commonly polygonal, bounded by joints to form globule or lump. Taking into account texture and mineralogy, tachylite is interpreted to have undergone little subsequent alteration at low temperature via hydration or hydrolysis that could form clay minerals after it was formed. Because tachylite with peculiar fractures occurs as dikes in a close association with BAF, its presence is considered as reliable evidence that when tachylite formed, the most part of BAF was still under subaqueous conditions, or at least saturated with seawater.

Characteristics Analysis of Mudstone Weathered Soils in the landslide Area using Statistical Technique (통계기법에 의한 산사태발생지역 이암 풍화토층의 토질특성 분석)

  • Hwang, Eui-Soon;Chung, Dae-Seouk;Kim, Kyeong-Su;Lee, Moon-Se;Song, Young-Suk
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.3
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    • pp.31-41
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    • 2013
  • In this study, the properties of mudstone weathered soils related to landslides were analyzed at the area of landslide induced by heavy rainfall in Pohang. The soil tests were carried out to the soils obtained from landslide and non landslide sites, and the soil properties were investigated. The correlation between soil properties and landslides were analyzed using statistical technique, and then the soil factors were extracted from the correlation analysis. The correlation equation which can calculate the coefficient of permeability influenced on landslides was proposed using the soil factors. As the result of analysis, the porosity and unit weight of soils from the landslide area is smaller than those of soils from the non landslide area. The soils with poor grain size distribution and loose unit weight are prone to landslides because the soils have a large void ratio and a low unit weight. The permeability of soils from the landslide area is larger than that of soils from the non landslide area. According to the result of correlation analysis, the effective grain size, the saturated unit weight and silt and clay contents are evaluated as the influence factors. These factors were considered to estimate the coefficient of permeability of mudstone weathered soils.

Effects of Kaolinite (Macsumsuk) and Herb Mixtures on the Quality and Physicochemical Properties of Pork

  • Kim, Byung Ki;Hwang, Eun Gyeong;Jung, Dae Jin;Ha, Jae Jung;Oh, Dong Yep;Choi, Chang Bon
    • Food Science of Animal Resources
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    • v.34 no.3
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    • pp.395-402
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    • 2014
  • The current study was conducted to identify technology for the production of high quality pork, based on the meat consumption habits of consumers. Macsumsuk, a type of kaolinite (a clay mineral), and/or a mixture of herbs (Mori Folium, Sophorae Radix, Glycyrrhizae Radix, Citri Leiocarpae Exocarpium, and Pogostemi Herba) were added to the diets of fattening pigs. Sixty barrow pigs (4 kinds of treatment ${\times}5$ pigs/treatment ${\times}3$ replicates) were randomly assigned to either the Control (no additives), T1 (3% Macsumsuk), T2 (3% Herb mixtures), or T3 (3% Macsumsuk + 3% Herb mixtures) groups, and were fed the diets for 60 d. Dressed weights were in the order of T1 ($93.40{\pm}4.68kg$) > T2 ($91.40{\pm}6.52kg$) > Control ($88.80{\pm}1.57kg$) > T3 ($86.80{\pm}2.01kg$). Back-fat thickness of the Control animals ($23.2{\pm}1.03mm$) was significantly greater than that of the various treatment groups (p<0.01). Numeric values representing the carcass yield and quality grade were higher for all the treated groups than the Control group, thought the difference was not statistically significant. Crude fat content was significantly higher in the Control group ($2.23{\pm}0.34%$) than in the treated groups (p<0.05). The addition of both Macsumsuk and herb mixtures into the diets of the pigs significantly reduced cooking loss of the pork compared to the Control (p<0.05). No statistically significant changes were observed in the shear force (average $5.87{\pm}0.54kg/cm^2$), water holding capacity (average $54.59{\pm}3.16%$), or CIE values of the pork, whereas cholesterol levels significantly decreased (p<0.01) in those fed Macsumsuk and/or the herb mixtures. No significant changes in fatty acid composition, total saturated fatty acid (SFA), total unsaturated fatty acid (UFA), or UFA/SFA ratios were observed by any of the treatments. In conclusion, the results obtained from this study suggest that the addition of Macsumsuk and/or herb mixtures into the diets of growing and fattening pigs improves the pork quality by reducing cooking loss, decreasing cholesterol content, and enhancing sensory characteristics.

Numerical Modelling of One Dimensional Gas Injection Experiment using Mechanical Damage Model: DECOVALEX-2019 Task A Stage 1A (역학손상모델을 이용한 1차원 기체 주입 시험 모델링: 국제공동연구 DECOVALEX-2019 Task A Stage 1A)

  • Lee, Jaewon;Lee, Changsoo;Kim, Geon Young
    • Tunnel and Underground Space
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    • v.29 no.4
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    • pp.262-279
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    • 2019
  • In the engineering barriers of high-level radioactive waste disposal, gases could be generated through a number of processes. If the gas production rate exceeds the gas diffusion rate, the pressure of the gas increases and gases could migrate through the bentonite buffer. Because people and the environment can be exposed to radioactivity, it is very important to clarify gas migration in terms of long-term integrity of the engineered barrier system. In particular, it is necessary to identify the hydro-mechanical mechanism for the dilation flow, which is a very important gas flow phenomenon only in medium containing large amounts of clay materials such as bentonite buffer, and to develop and validate new numerical approach for the quantitative evaluation of the gas migration phenomenon. Therefore, in this study, we developed a two-phase flow model considering the mechanical damage model in order to simulate the gas migration in the engineered barrier system, and validated with 1D gas flow modelling through saturated bentonite under constant volume boundary conditions. As a result of numerical analysis, the rapid increase in pore water pressure, stress, and gas outflow could be simulated when the dilation flow was occurred.

Introduction to Researches on the Characteristics of Gas Migration Behavior in Bentonite Buffer (벤토나이트 완충재 내 기체 이동의 거동 특성 관련 연구 동향 소개)

  • Kang, Sinhang;Kim, Jung-Tae;Lee, Changsoo;Kim, Jin-Seoup
    • Tunnel and Underground Space
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    • v.31 no.5
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    • pp.333-359
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    • 2021
  • Gases such as hydrogen and radon can be generated around the canister in high-level radioactive waste disposal systems due to several reasons including the corrosion of metal materials. When the gas generation rate exceeds the gas diffusion rate in the low-permeability bentonite buffer, the gas phase will form and accumulate in the engineered barrier system. If the gas pressure exceeds the gas entry pressure, gas can migrate into the bentonite buffer, resulting in pathway dilation flow and advective flow. Because a sudden occurrence of dilation flow can cause radionuclide leakage out of the engineered barrier of the radioactive waste disposal system, it is necessary to understand the gas migration behavior in the bentonite buffer to quantitatively evaluate the long-term safety of the engineered barrier. Experimental research investigating the characteristics of gas migration in saturated bentonite and research developing numerical models capable of simulating such behaviors are being actively conducted worldwide. In this technical note, previous gas injection experiments and the numerical models proposed to verify such behaviors are introduced, and the future challenges necessary for the investigation of gas migration are summarized.

Effect of Water on the Lightweight Air-Mixed Soil Containing Silt Used for Road Embankment (도로성토체로 사용된 실트질 계열의 경랑기포혼합토에 대한 물의 영향)

  • Hwang, Joong-Ho;Ahn, Young-Kyun;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.26 no.2
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    • pp.23-32
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    • 2010
  • This study was especially conducted to find out the characteristics of the lightweight air-mixed soil (slurry density 10 kN/$m^3$) containing silt related to water. Compression strength, permeability, and capillary height of the lightweight air-mixed soil were studied, and also to support these studies, the structure of that soil was analyzed in detail. Air bubbles of various sizes are inside the lightweight air-mixed soil, and its distribution in a location is almost constant. A numerous tiny pores are inside the air bubbles so that the lightweight air-mixed soil can be saturated with water. Porosity is also estimated through the image analysis. Peak strength of the lightweight air-mixed soil is not dependent on water, but behavior of stress-strain is affected by the water. Permeability is about $4.857{\times}10^{-6}cm/sec$, which is a little bit higher than the clay's permeability. Capillary rise occurs rapidly at the beginning of the test until the lapse of 100 minutes and then its increase rate becomes slow. The capillary rise causes the increase of the density of the lightweight air-mixed soil, and thus it is required to pay attention to this phenomenon during structure design and maintenance of the lightweight air-mixed soil.