• Korean Journal of Food Science and Technology
• /
• v.42 no.4
• /
• pp.390-397
• /
• 2010

Residual solvents in foods are defined as organic volatile chemicals used or produced in manufacturing of extracts or additives, or functional foods. The solvents are not completely eliminated by practical manufacturing techniques and they also may become contaminated by solvents from packing, transportation or storage in warehouses. Because residual solvents have no nutritional value but may be hazardous to human health, there is a need to remove them from the final products or reduce their amounts to below acceptable levels. The purpose of this study was to develop and evaluate an analytical method for the screening of residual solvents in health functional foods. Furthermore, the aim of this study was to constitute a reasonable management system based on the current state of the market and case studies of foreign countries. Eleven volatile solvents such as MeOH, EtOH, trichloroethylene and hexane were separated depending on their column properties, temp. and time using Gas Chromatography (GC). After determining the GC conditions, a sample preparation method using HSS (Head Space Sampling) was developed. From the results, a method for analyzing residual solvents in health functional foods was developed considering matrix effect and interference from the sample obtained from the solution of solvents-free health functional foods spiked with 11 standards solutions. Validation test using the developed GC/HSS/MS (Mass Spectrometry) method was followed by tests for precision, accuracy, recovery, linearity and adequate sensitivity. Finally, examination of 104 samples grouped in suits was performed by the developed HSS/GC/MS for screening the solvents. The 11 solvents were isolated from health functional foods based on vapor pressure difference, and followed by separation within 15 minutes in a single run. The limt of detection (LOD), limit of quantification (LOQ), recovery and coefficient of variation (C.V.) of these compounds determined by the HSS/GC/MS were found to be 0.1 pg/mL, 0.1-125 pg/g, 51.0-104.6%, and less than 15%, respectively. Using the developed HSS/GC/MS method, residual solvent from 16 out of 104 health functional products were detected as a EtOH. This method therefore seems t o be a valuable extension ofanalytical method for the identification of residual solvents in health functional food.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2007.05a
• /
• pp.241-245
• /
• 2007

국내 홍수빈도 분포의 매개변수 추정에서 지점추정(at-site estimate) 방법은 유량 자료의 부족으로 발생하는 표본오차(sampling error)가 크기 때문에 충분한 유량 자료를 보유한 지점에 한하여 제한적으로 사용되고 있다. 대안으로 동질성을 가진 유역의 유량 자료를 모아 지역 매개변수를 추정하는 지수홍수법(Index Flood Method)이 제안되기도 하였으나, 이질성이 큰 우리나라의 유역특성 때문에 적용이 쉽지 않다. Stedinger와 Tasker가 1986년 제안한 GLS(Generalized Least Square) 기법은 유역을 동질지역으로 구분할 필요가 없으며 지점들간의 상관관계와 이분산성을 고려할 수 있어, 국내 홍수빈도 해석을 위해서 꼭 도입해야할 기법으로 생각된다. 본 연구에서는 기존의 GLS 기법의 단점을 보완한 Bayesian-GLS 기법을 이용하여, 국내 대유역에 골고루 위치하며 댐의 영향을 받지 않는 31개 지점의 연최대 일유량 시계열의 L-변동계수(L-moment coefficient variation)와 L-왜도계수(L-moment coefficient skewness)를 추정할 수 있는 회귀모형을 제안하였다. 위 회귀모형을 구성하기 위한 유역특성으로는 유역면적, 유역경사, 유역평균강우 등을 사용하였다. Bayesian-GLS (B-GLS) 적용 결과를 OLS(Ordinary Least Square) 및 Bayesian-GLS 기법에서 지점간의 상관관계를 고려하지 않는 Bayesian-WLS(Weighted Least Square)와 비교 평가하여 그 우수성을 입증하였다. 따라서 본 연구에서 제안된 B-GLS에 의한 지역회귀모형은 국내의 미계측유역이나 또는 관측 길이가 짧은 계측유역의 홍수빈도분석을 위해 매우 유용할 것으로 기대된다.년 홍수 피해가 발생하고 있지만, 다른 한편 인구밀도가 높고 1인당 가용 수자원이 상대적으로 적기 때문에 국지적 물 부족 문제를 경험하고 있다. 최근 국제적으로도 농업용수의 물 낭비 최소화와 절약 노력 및 타 분야 물 수요 증대에 대한 대응 능력 제고가 매우 중요한 과제로 부각되고 있다. 2006년 3월 멕시코에서 개최된 제4차 세계 물 포럼에서 국제 강 네트워크는 "세계 물 위기의 주범은 농경지", "농민들은 모든 물 위기 논의에서 핵심"이라고 주장하고, 전 프랑스 총리 미셀 로카르는 "...관개시설에 큰 문제점이 있고 덜 조방적 농업을 하도록 농민들을 설득해야 한다. 이는 전체 농경법을 바꾸는 문제..."(segye.com, 2006. 3. 19)라고 주장하는 등 세계 물 문제 해결을 위해서는 농업용수의 효율적 이용 관리가 중요함을 강조하였다. 본 연구는 이러한 국내외 여건 및 정책 환경 변화에 적극적으로 대처하고 물 분쟁에 따른 갈등해소 전략 수립과 효율적인 물 배분 및 이용을 위한 기초연구로서 농업용수 수리권과 관련된 법 및 제도를 분석하였다.. 삼요소의 시용 시험결과 그 적량은 10a당 질소 10kg, 인산 5kg, 및 가리 6kg 정도였으며 질소는 8kg 이상의 경우에는 분시할수록 비효가 높았으며 특히 벼의 후기 중점시비에 의하여 1수영화수와 결실율의 증대가 크게 이루어졌다. 3. 파종기와 파종량에 관한 시험결과는 공시품종선단의 파종적기는 4월 25일부터 5월 10일경까지 인데 이 기간중 일찍 파종하는 경우에 파종적량은 10a당 약 8${\ell}$이고 늦은 경우에는 12${\ell}$ 정도였다. 여기서 늦게 파종한 경우 감수의 가장 큰 원인은 1수영화수가 적어지기 때문이었다. 4. 건답직파에 대한 담수상태로 관수를 시작하는 적기는 파종후

• Journal of Biosystems Engineering
• /
• v.29 no.3
• /
• pp.267-274
• /
• 2004

Using geo-statistical method, yield data of different fields were analyzed to examine their field variability according to examining year, analysis method. Semivariogram and Kriged maps of geo-statistical analysis were used to examine their spatial dependence within a filed. The results obtained were as follows. 1) Descriptive statistical results of the yield showed that the yield and the difference of yield ranged from 100 to 946kg/10a and from 272 to 653kg/10a, respectively within a field. The coefficient of variation also ranged from 5.9 to 22.4 %. 2) More than 90% of yield data were placed between 350 to 850kg/10a. e results indicated that the gram mass flow sensor should have the measuring range from 0.34 to 0.82kg/s considering the yields when 4 rows head-feeding combine with 0.8 m/s of working speed was utilized. 3) A high spatial dependence was found within paddy field. The Q values ranged from 0.20 to 0.97, and the range of spatial dependence was from 6.9 to 53.3m. From this result, the rational sampling interval for yield investigation was estimated 6.9m. 4) Yields within a field between observation years showed considerable variability even if the field was evenly cultivated and managed. To apply precision agriculture in a paddy field, the field test should be continued to build a solid data-base including meteorological data, blight damage and insect damage.

• Korean Journal of Environmental Biology
• /
• v.24 no.1 s.61
• /
• pp.7-18
• /
• 2006

Samples were collected from five stations monthly from October 2003 to September 2004 to investigate seasonal variation of size structure of phytoplankton and relationship between size-fractionated phytoplankton and environmental factors in the Asan Bay. The contribution of large cells (microphytoplankton, $>20\;{\mu}m$) to total concentrations of chlorophyll $\alpha$ was higher than small cells (nanophytoplankton, $3\sim20\;{\mu}m$; picophytoplankton, $<3\;{\mu}m$) during the sampling period. Especially, large cells contributed 80% to the total chlorophyll a from February, 2004 to April 2004 when chlorophyll $\alpha$ concentrations were high. The size structure of phytoplankton shifted from micro-size class to nano-size class and picophytoplankton rapidly increased when phytoplankton biomass decreased in May 2004. Microphytoplankton exhibited a high biomass in the upper region during winter-spring season whereas nano- and picophytoplankton showed two peaks in the middle-lower regions (Station 3,5) during spring and summer. Microphytoplankton are most likely controlled by water temperature and nutrient supply during the cold season whereas nano- and picophytoplankton may be affected by stratification, light exposure during the warm season.

• The Journal of Engineering Geology
• /
• v.15 no.1
• /
• pp.29-39
• /
• 2005

For detecting a ground contamination survey, soil sampling method have been used a drilling or coring technique in general. However these methods are very difficult to systematically real-time monitoring of variation of contamination degree in field. ]'n this research frequency Domain Reflectometry (FDR) system was suggested and carried out to experimental approaches for determination of oil contamination on surface and underground. Experimental method using FDR method was discussed with feasibility of measurement in the laboratory column test. It is determined to degree of oil contamination due to response of dielectric constant re-lated with volumetric water content(θ/sub w/) and volumetric oil content( θ/sub al/ ) of saturated and unsaturated soil media. And physical properties such as effective porosity and oil residual ratio of saturated soil media were also measured through real-time monitoring works using installed FDR measurement sensors, which are defected characteristics of oil movement in the saturated soil media under the soil column tests. In the results of these experiments, a range of effective porosity was estimated to about 0.35 compared with initial porosity 0.40 of manufactured saturated soil media, which is also calculated to about 87.5% to the ratio of initial porosity to effective porosity. Finally oil residual ratio which is compared with volumetric water content and volumetric oil content was calculated about 62.5%.

• Korean Journal of Ecology and Environment
• /
• v.43 no.2
• /
• pp.255-262
• /
• 2010

This study was conducted at 5 sites of Bocheong Stream basin in May and September 2009 for the evaluate of fish assemblage and chemical water quality. For the study, the models of Index of Biological Integrity (IBI) and Qualitative Habitat Evaluation Index (QHEI) were modified as 8 and 11 metric attributes, respectively. We also analyzed patterns of chemical water quality at the sampling site over the period of 2005~2009, using the water chemistry dataset, obtained from the Ministry of Environment, Korea. The survey showed that total sampled fishes were 34 species and the most dominant species was Zacco platypus (24.3%). In Bocheong Stream basin, values of IBI averaged 28 (n=5), which is judged as a "Good". IBI score at B1, B4 and B5 indicating a "Good" condition whereas, B2 and B3 were as 21 and 22, indicating "Fair" condition, respectively. QHEI was 152 (n=5), judged as "Fair" habitat condition. Values of BOD and COD averaged 1.0 $mgL^{-1}$ (scope: 0.3~4.0 $mgL^{-1}$) and 2.3 $mgL^{-1}$ (scope: 0.3~18.7 $mgL^{-1}$), respectively. Total nitrogen (TN), total phosphorus (TP) and suspended solid (SS) were distinct spatial variation. Based on the IBI, QHEI and chemical water quality dataset, ecological health of Bocheong Stream basin was evaluated that generally good.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.47 no.6
• /
• pp.935-944
• /
• 2014

To elucidate the variation of species composition, biomass and size distribution of fishery resource in the Uljin marine ranching area was investigated at the 4 stations from 2009 to 2010 based on the dredge sampling. During the survey period, a total of 41 fishery resource species were sampled with a mean density of $2,554,633\;ind./km^2$ and mean biomass was $32,946kg/km^2$. A total 36 fishery resource species were sampled with a mean density of $3,198,793\;ind./km^2$ and mean biomass $41,177kg/km^2$ in 2009 and it were sampled a total 31 species, mean $1,910,473kg/km^2$ and $24,716kg/km^2$ in 2010. The major individual-dominant species, occupying over 1% of total individuals, were Gomphina veneriformis (2,491,818 ind., 82.2%), Umbonium costatum (221,973 ind., 8.7%), Mactra chinensis (49,879 ind., 2.0%), Glossaulax didyma hayashii (49,879 ind., 1.9%), Blepharipoda liberate (37,714 ind., 1.5%) and Paguridae spp. (27,266 ind., 1.1%). The major biomass-dominant species, occupying over 1% of total biomass, were G. veneriformis (25,124 kg, 76.3%), G. didyma hayashii (2,596 kg, 7.9%), M. chinensis (2,024 kg, 6.1%), Ovalipes punctatus (921 kg, 2.8%) and Glossaulax didyma didyma (567 kg, 1.7%). From the cluster analysis based on Bray-Curtis similarity matrix of fourth root transformed data of species number and individuals was divided into 2 different groups of the fishery resource community (Group A-St.1, Group B-Sts. 2, 3, 4). The 2009 and 2010 mean Shell length (mm) of G. veneriformis was 37.73 mm, 29.76 mm and M. chinensis was 62.03 mm, 44.94 mm, respectively.

• Journal of Environmental Health Sciences
• /
• v.45 no.6
• /
• pp.668-674
• /
• 2019

Objectives: Modern people spend most of their day indoors. As the health impact of radon becomes an issue, public interest also has been growing. The primary route of potential human exposure to radon is inhalation. Long-term exposure to high levels of radon increases the risk of developing lung cancer. Radon exposure is known to be the second-leading cause of lung cancer, following tobacco smoke. This study measures the indoor radon concentrations in detached houses in area A of Chungcheongbuk-do Province considering the construction year, cracks in the houses, the location of installed detectors, and seasonal effects. Methods: The survey was conducted from September 2017 to April 2018 on 1,872 private households located in selected areas in northern Chungcheongbuk-do Province to figure out the year of building construction and the location of detector installed and identify the factors which affect radon concentrations in the air within the building. Radon was measured using a manual alpha track detector (Raduet, Hungary) with a sampling period of longer than 90 days. Results: Indoor radon concentrations in winter within area A was surveyed to be 168.3±193.3 Bq/㎥. There was more than a 2.3 times difference between buildings built before 1979 and those built after 2010. The concentration reached 195.4±221.9 Bq/㎥ for buildings with fractures and 167.2±192.4 Bq/㎥ for buildings without fractures. It was found that detectors installed in household areas with windows exhibited a lower concentration than those installed in concealed spaces. Conclusion: High concentrations of indoor radon were shown when there was a crack in the house. Also, ventilation seems to significantly affect radon concentrations because when the location of the detector in the installed site was near windows compared to an enclosed area, radon concentration variation increased. Therefore, it is considered that radon concentration is lower in summer because natural ventilation occurs more often than in winter.

• Journal of the Korean Institute of Landscape Architecture
• /
• v.30 no.3
• /
• pp.12-24
• /
• 2002

The purpose of this paper is to decompose the effect of resources of natural parks(NP) on user's satisfaction to answer the research question: What are the causal effects of resources of natural parks on user\ulcorner After reviewing the literature, classification of resources of NP, various approaches and analysis methods employed, we constructed the conceptual framework and have formulated the hypothesis of this research. We had obtained data through a questionnaire, which surveyed 414 visitors at 6 of the 73 NP in Korea in 2001, based on a stratified sampling method. We have analyzed the data using descriptive statistical methods, Pearson's correlation analysis, and a path analysis method. We found that 1) While the indirect effect of topographical feature and valley(TFV), socio-cultural resources(SCR), and climate, sound, and scent(CSS) turned out to be 2.75, 1.20, and 2.00 times higher than that of wild animal and plant(WAP), the direct effect of TFV, SCR, and landscape turned out to be 2.95, 2.88, and 2.64 times higher than that of CSS, 2) The magnitude of causal effects of the three exogeneous variables of TFV, WAP, and SCR and two intervening variables of CSS and landscape on User's satisfaction turned out to be 0.403, 0.048, 0.323, 0.188, and 0.243, respectively, 3) Total direct effect of the exogeneous and intervening variables on user's satisfaction is 0.871, while that of indirect effect is 0.334, and 4) Causal effect of tangible resources is 1.80 times higher than that of intangible while total effect of tangible resources are 1.36 times higher than that of intangible. The research results suggest that 1) Criteria for designation and maintenances of NP and results of previous studies on resources turned out to be unreliable and distorted, 2) In the criteria of planning and maintenance of NP, intangible resources must be included, 3) Remedial directions to increase user's satisfaction should be focused on maintenance of TFV and landscape in NP, and 4) The approach and path analysis adopted by this research is valid and highly useful for other resource based recreation area. It is recommended that more empirical study on seasonal variation of resources in NP based user's preference be performed in the future.

• Journal of Korean Society of Forest Science
• /
• v.106 no.1
• /
• pp.100-109
• /
• 2017

This study was conducted for preliminary survey and management support for Pine Wood Nematode (PWN) suppression. We took areal photographs of 6 areas for a total of 2,284 ha during 2 weeks period from 15/02/2016, and produced 6 ortho-images with a high resolution of 12 cm GSD (Ground Sample Distance). Initially we classified 423 trees suspected for PWN infection based on the ortho-images. However, low accuracy was observed due to the problems of seasonal characteristics of aerial photographing and variation of forest stands. Therefore, we narrowed down 231 trees out of the 423 trees based on the initial classification, snap photos, and flight information; produced thematic maps; conducted field survey using GNSS; and detected 23 trees for PWN infection that was confirmed by ground sampling and laboratory analysis. The infected trees consisted of 14 broad-leaf trees, 5 pine trees (2 Pinus rigida), and 4 other conifers, showing PWN infection occurred regardless of tree species. It took 6 days for 2.3 men from to start taking areal photos using UAV (Unmanned Aerial Vehicle) to finish detecting PNW (Pine Wood Nematode) infected tress for over 2,200 ha, indicating relatively high efficacy.