• Title/Summary/Keyword: sampling variation

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Effect of Ambient Temperature on the Distribution of Atmospheric Concentrations of Polycyclic Aromatic Hydrocarbons in the Vapor and Particulate Phases (대기 중 다환방향족탄화수소의 기체-입자상 농도분포에 미치는 주변 온도의 영향)

  • 백성옥;최진수
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.117-132
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    • 1998
  • The main purposes of this study are to investigate the distributional characteristics of polycyclic aromatic hydrocarbons (PAH) in the vapor and particulate phases in the ambient atmosphere, and to evaluate the effect of ambient temperature on the vapor-particle partitioning during the sampling period. A total of 64 samples were collected during a period of 1995 to 1996, using a medium-volume sampler with XAD-2 adsorbents and quartz fiber filters. Analyses of PAH were carried out using HPLC with UV and Fluorescence detections. In this study, a significant seasonal variation in the distributions was observed, reflecting the effect of ambient temperature on the vapor-particle partitioning of PAH. The relationship between the vapor-particle distributions of the 3 to 5 rings PAH and ambient temperature is considered to be well described using the Langmuir adsorption concept. The estimated empirical constants for each PAH in the relationship, particularly for the more volatile compounds, were also comparable with results from other studies. However, it is still difficult to accurately estimate the initial vapor-particle distribution of PAH in the ambient air, since it is not known to what extent the trapped vapours originated from the particles laden in the filter by being volatilized or from the air samples initially present in the vapour phase. The distribution factors for volatile PAH with 3 to 4 rings appeared to be comparable with those in the literature. It should be noted, however, that these distribution factors give information only about the distribution of PAH between the two phases under a specific sampling condition, and hence may provide only semi -quantitative information on the vapor-particle distributions in the atmosphere.

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Evaluation of a Diffusive Sampler for the Measurement of Formaldehyde using Colorimetric Method (흡광광도법을 이용한 포름알데히드 확산측정기의 평가)

  • Yim, Bong-Been;Kim, Sun-Kyu;Jung, Eui-Suk;Kim, Sun-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.606-613
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    • 2005
  • The badge-type diffusive sampler for the measurement of formaldehyde in indoor air using three types of colorimetric methods such as chromotrophic acid(CTA), 3-methyl-2-benzothiazolinone hydrazone(MBTH), and 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole(AHMT) method. The washing of the collection filter with several cleaning solution was effected with satisfactory results, regardless of the types of cleaning solutions. The concentrations of absorbance solution in each colorimetric method were experimentally determined by considering the sampling rates. The variation blank values in each colorimetric method was below 15%. As compared with CTA and AHMT methods, the reproducibility of MBTH method was excellent and was below 10% relative standard deviation. The collected formaldehyde mass and time-weighted concentration had a good correlation (correlation coefficient > 0.93). The limit of detection and limit of quantitation, and minimum sampling time were closely correlated to the sampling rates for the measurement of formaldehyde in each method.

Concentration Distribution of Volatile Organic Compounds in the Ambient Air of an Industrial Shipbuilding Complex : A Case Study (조선소 밀집지역의 휘발성유기화합물 농도분포 특성에 관한 사례 연구)

  • Lee, Myoung-Eun;Park, Eun-Ok;Chung, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.6
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    • pp.380-386
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    • 2015
  • In this study, the spatial and temporal distribution of volatile organic compounds (VOCs) in an industrial shipbuilding complex was monitored, and the local characteristics estimated. The major VOC component measured at all of the sampling sites were almost the same as those found at an indoor painting facility, indicating that painting works conducted in the shipyards were a significant source of VOCs in the vicinity of shipbuilding areas. The main parameters affecting the VOCs distribution were the distance between the sampling site and painting work place, and the intensity of the painting works. A quite broad range of VOC concentrations were observed in all of the sampling sites, depending on the intensity of painting works in nearby areas suppressing the typical seasonal and temporal variation trends in VOCs observed in urban areas.

A new high-order response surface method for structural reliability analysis

  • Li, Hong-Shuang;Lu, Zhen-Zhou;Qiao, Hong-Wei
    • Structural Engineering and Mechanics
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    • v.34 no.6
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    • pp.779-799
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    • 2010
  • In order to consider high-order effects on the actual limit state function, a new response surface method is proposed for structural reliability analysis by the use of high-order approximation concept in this study. Hermite polynomials are used to determine the highest orders of input random variables, and the sampling points for the determination of highest orders are located on Gaussian points of Gauss-Hermite integration. The cross terms between two random variables, only in case that their corresponding percent contributions to the total variation of limit state function are significant, will be added to the response surface function to improve the approximation accuracy. As a result, significant reduction in computational cost is achieved with this strategy. Due to the addition of cross terms, the additional sampling points, laid on two-dimensional Gaussian points off axis on the plane of two significant variables, are required to determine the coefficients of the approximated limit state function. All available sampling points are employed to construct the final response surface function. Then, Monte Carlo Simulation is carried out on the final approximation response surface function to estimate the failure probability. Due to the use of high order polynomial, the proposed method is more accurate than the traditional second-order or linear response surface method. It also provides much more efficient solutions than the available high-order response surface method with less loss in accuracy. The efficiency and the accuracy of the proposed method compared with those of various response surface methods available are illustrated by five numerical examples.

Sample Design in Korea Housing Survey (주거 실태 및 수요조사 표본설계)

  • Byun, Jong-Seok;Choi, Jae-Hyuk
    • Survey Research
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    • v.11 no.1
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    • pp.123-144
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    • 2010
  • In new sample design for Korea Housing Survey to research about housing policy, total strata are forty five because individual results of sixteen regions are estimated. The sample size is determined by sample errors of several variables which are the living area, family income, householder income, and living expenses. The sample size of each region is determined by relative standard error of existing result, and the strata sample size is to use the square root proportion allocation. Enumeration districts are sampled by the probability proportion to size systematic sampling in proportion to the enumeration district size, and the systemic sampling to use assortment characteristics. We considered a new apartment complex because of variation reflections which are rebuilder and redevelopment of houses. To get estimators of mean and variance, we used the design weighting, non-response adjusting, and post-stratification. In order to consider estimation efficiency, we calculate the design effect using estimators of variance.

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Assessment of Coarse Woody Debris in Gallery Forest in the Bombo-Lumene Reserve (Democratic Republic of Congo)

  • Rusaati, Butoto Imani wa;Joo, Sung-Hyun;Yun, Gi-Yun;Park, Joowon;Cephas, Masumbuko Ndabaga;Kang, Jun-Won
    • Journal of Forest and Environmental Science
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    • v.35 no.3
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    • pp.205-211
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    • 2019
  • The objective of this research was to assess the amount of carbon stock of coarse woody debris (CWD) in Bombo-Lumene Reserve. Data on lying CWD was collected on 35 circular sampling plots using Line Intersect Sampling (LIS) method. A total of 230 samples CWD (${\geq}10cm$ diameter) were inventoried. The mean carbon stocks of CWD was $29.48Mg\;C\;ha^{-1}$, ranging from 4.32 to $73.54Mg\;C\;ha^{-1}$. The CWD carbon stocks displayed a wide range of variation in decay states. The allocation of CWD among the decay class of all the CWD samples reveals that the most important classes were class 1 and class 3 with 323.66 and $321.96Mg\;C\;ha^{-1}$, followed by class 4 with 264.56 and the last one was class 2 with $121.72Mg\;C\;ha^{-1}$. The results suggested that the dead wood component is important in carbon sequestration and should be taken into consideration for quantification of carbon stocks not only in Bombo-Lumene Reserve, but in all forest ecosystems in the Democratic Republic of Congo.

A Study on Building Identification from the Three-dimensional Point Cloud by using Monte Carlo Integration Method (몬테카를로 적분을 통한 3차원 점군의 건물 식별기법 연구)

  • YI, Chaeyeon;AN, Seung-Man
    • Journal of the Korean Association of Geographic Information Studies
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    • v.23 no.4
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    • pp.16-41
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    • 2020
  • Geospatial input setting to represent the reality of spatial distribution or quantitative property within model has become a major interest in earth system simulation. Many studies showed the variation of grid resolution could lead to drastic changes of spatial model results because of insufficient surface property estimations. Hence, in this paper, the authors proposed Monte Carlo Integration (MCI) to apply spatial probability (SP) in a spatial-sampling framework using a three-dimensional point cloud (3DPC) to keep the optimized spatial distribution and area/volume property of buildings in urban area. Three different decision rule based building identification results were compared : SP threshold, cell size, and 3DPC density. Results shows the identified building area property tend to increase according to the spatial sampling grid area enlargement. Hence, areal building property manipulation in the sampling frameworks by using decision rules is strongly recommended to increase reliability of geospatial modeling and analysis results. Proposed method will support the modeling needs to keep quantitative building properties in both finer and coarser grids.

Patterns of Mercury Concentrations in Blood and Urine After High Mercury Exposure (고농도 수은 노출자의 혈 중 및 뇨 중 수은 농도 변화에 관한 연구)

  • 윤충식;임상혁;하권철
    • Journal of Environmental Health Sciences
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    • v.27 no.3
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    • pp.71-80
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    • 2001
  • Blood and urine mercury level of three workers were monitored during 60~80 days after high exposure to mercury at the silver refining plant. Mercury was used to form silver-mercury amalgam from plating sludge. Workers were exposed to mercury about 70 days at the several processes, such as hand held weaving, vibration table, and heating from the furnace. mercury was analysed by atomic absorption spectroscopy-vapor generation technique. Recovery from the biological sample was 95.51% and pooled standard deviation was 0.033. At the time of study, there was no work at the workplace. So, airborne mercury concentration was measured with area sampling 5 days after the work, ranged from 0.1459 to 1.2351 mg/㎥(Arithmatic mean 0.4711 mg/㎥, Geometric mean 0.3566 mg/㎥) at the inside of the plant, that is far above the ACGIH's TLV(0.025 mg/㎥) and ranged from 0.0073 to 0.0330 mg/㎥ at the outdoor. Blood mercury levels at the beginning of the monitoring were 4~14 times greater than the American Conference of Governmental Industrial Hygienists Biological Exposure Index(ACGIH BEI, 15 ug/L). Blood mercury levels were decreased logarithmically, that is, rapidly at the high level and slowly at the low level but sustained above the level of the ACGIH BEI 60~80 days after the work. Urine mercury levels at the beginning of the monitoring were 8~16 times greater than the ACGIH BEI(35 ug/g creatinine). Urine mercury levels were decreased logarithmically, but correlation between urine level and off-days were lower than those of blood. Decreasing pattern of blood mercury levels were little affected than that of urine levels when the chelating agent, D-penicillamine, was administered. There was correlation between blood mercury level and urine mercury level(0.81~0.83) but it didn\`t mean that the highest blood mercury level corresponded the highest urine mercury level. In our study, Case 1 always shows the highest level in urine but case 3 always shows the highest level in blood. Creatinine correction represented better correlations between urine mercury levels and blood levels, and between urine levels and off-days rather than by urine volume. Spot urine sampling had a wide variation than that of whole day urine sampling. So, We recommend spot urine sampling for screening and whole day urine sampling for exact diagnosis.

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Temporal and Spatial Variation in Fish Larvae in Gamak Bay and Yeoja Bay, South Sea of Korea

  • Ryu, Jung-Hwa;Kim, Jeong-Bae;Kim, Jin-Koo
    • Fisheries and Aquatic Sciences
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    • v.14 no.1
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    • pp.55-61
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    • 2011
  • Fish larvae were collected monthly with an ichthyoplankton net from 18 stations (including four stations located in eelgrass beds) in Gamak Bay and Yeoja Bay, southern Korea, in 2007. In total, 33 species of fish larvae were collected, of which Engraulis japonicus (48.5%), Tridentiger trigonocephalus (21.5%), and Omobranchus elegans (9.2%) were dominant. Dominant species varied seasonally: Hexagrammos otakii during December and January, Pholis nebulosa during January and March, Acanthogobius flavimanus in April, T. trigonocephalus in May, E. japonicus during June, July, September, and November, and Sillago japonica in August. Dominant species also differed between sites inside and outside the bays. Leiognathus nuchalis, O. elegans, and T. trigonocephalus were more abundant inside, while H. otakii was more abundant outside. From cluster analysis, three groups were identified according to sampling months (January-April, May-September, and October-December) and two groups according to station (inside and outside bays). The occurrence of small larvae of almost all major fish species indicated that the bays were used as spawning and nursery grounds. An exception was Lateolabrax japonicus, whose specimens were relatively large (>19 mm TL), suggesting that this fish may spawn offshore, with its juveniles approaching the bays with growth.

Nitrogen Dioxide Measurement with Diffusive Passive Samplers at the Curbside Points in Daejeon (확산측정기를 이용한 대전시 도로변에서의 이산화질소 측정)

  • Yim, Bong-Been;Kim, Sun-Tae;Yang, Heung-Mo
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.2
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    • pp.143-152
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    • 2008
  • This study investigates the variation and spatial distribution of nitrogen dioxide($NO_2$) concentrations measured with passive diffusive samplers at 40 curbside points in Daejeon. Average $NO_2$ concentration was $39.8{\pm}18.0\;ppb$ (n=1,127) and the significant difference in concentrations by regional groups (Dong-gu, Jung-gu, Seo-gu, Daedeok-gu, Yuseong-gu) was not observed. The frequency distribution of $NO_2$ concentration was found to be a normal distribution with the high frequency in the concentration range of 30 to 40 ppb (20 to 25%). Average $NO_2$ concentration measured during the rainy periods was lower than that measured during the non-rainy periods and the decrease of concentration by rainfall was about 16% (7 ppb). The variation of $NO_2$ concentrations measured by passive diffusive samplers during the sampling period was similar to that continuously measured at the air quality monitoring station.