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Cathodic Protection of Reinforced Concrete Slab with Zn-Mesh in Marine Environment (해양환경 중 Zn-mesh를 적용한 콘크리트 슬랩의 음극방식 특성)

  • Kim, Ki-Joon;Jeong, Jin-A;Lee, Woo-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1065-1068
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    • 2008
  • Marine bridges are readily deteriorated due to the exposure to marine environment. The concrete deterioration occurred by corrosion of steel in concrete is mainly relevant to chloride in seawater. Chloride ions penetrate through porous concrete, and then reach to the reinforcing steel, and finally corroded them. The corrosion by-products(rusts) increase the volume as much as 6 to 10 times of origin steel. this creates expanding pressure and tensile stress, which cause the structures cracking and spalling. Sometimes the rebar corrosion is accelerated, and then collapsed catastrophically. In order to prevent corrosion damage, it is important to understand well regarding the reason of concrete corrosion, the quantification of its damage, and protection method/system to stop or to mitigate the corrosion. In this study, slab specimens were fabricated to evaluate the effect of cathodic protection which was simulated to marine bridges, and/or port structures. Zn-mesh sacrificial anode has been applied as a chathodic protection system and accelerated test conditions, i.e. temperature and salt concentration have been used in this study.

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Preparation of Nano-sized Pt Powders by Solution-phase Reduction (액상환원법(液相還元法)에 의한 백금(白金) 나노분말(粉末) 제조(製造))

  • Kim, Chul-Joo;Yoon, Ho-Sung;Cho, Sung-Wook;Sohn, Jung-Soo
    • Resources Recycling
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    • v.16 no.5
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    • pp.36-40
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    • 2007
  • Platinum plays an important role in many applications because of its extraordinary physical and chemical properties. All these applications require the use of platinum in the finely divided state. Therefore the preparation of platinum nanoparticles by reducing platinum-surfactant salt with reducing agent in the solution was investigated in this study. The net interaction between C14TABr and $H_2[PtCl_6]$ in aqueous solution results in the formation of $[C14TA]_2[PtCl_6]$. The concentration of C14TABr and the concentration of $H_2[PtCl_6]$ has to be above cmc and 0.32 mM, respectively in order to obtain complex-micelle aggregation for mono dispersed Pt particles. Pt particle size increases with increasing $H_2[PtCl_6]$ and C14TABr concentration. And the shape of Pt particles was well controlled with increasing surfactant concentration.

Enantioselective Epoxide Synthesis on the Chiral Salen Catalyst having a Transitional Metal Salt (전이금속염 함유 키랄 살렌 촉매에 의한 광학선택적 에폭사이드의 합성)

  • Guo, Xiao-Feng;Kawthekar, Rahul B.;Kim, Geon-Joong
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.769-776
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    • 2008
  • The stereoselective synthesis of chiral terminal epoxide is of immense interest due to their utility as versatile starting materials as well as chiral intermediates. In this study, new chiral Co(salen) complexes bearing cobalt(II) chloride, iron(III) chloride and zinc(II) nitrate have been synthesized and characterized. The mass and EXAFS spectra provided the direct evidence of formation of complex. Their catalytic activity and selectivity have been demonstrated for the asymmetric ring opening of terminal epoxides such as styrene oxide and phenylglycidylether by hydrolytic kinetic resolution technology and for the synthesis of glycidyl buthylate. The easily prepared complexes exhibited very high enantioselectivity for the asymmetric ring opening of epoxides with $H_2O$ nucleophile, providing enantiomerically enriched terminal epoxides (>99% ee). The newly synthesized chiral salen showed remakablely enhanced reactivity with substantially low loadings. The system described in this work is very efficient for the sinthesis of chiral epoxide and 1,2-diol intermediates.

Development of EST-SSRs and Assessment of Genetic Diversity in Little Millet (Panicum sumatrense) Germplasm

  • Ali, Asjad;Choi, Yu-Mi;Hyun, Do-Yoon;Lee, Sukyeung;Kim, Jin-Hee;Oh, Sejong;Lee, Myung Chul
    • Korean Journal of Plant Resources
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    • v.30 no.3
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    • pp.287-297
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    • 2017
  • Little millet (Panicum sumatrense) is well known for its salt and drought stress tolerance and high nutritional value, but very limited knowledge of genetic variation and genomic information is available. In this study, a total of 779 primer pairs were designed from the 22,961 EST sequences of switchgrass (Pancium virgatum), of which 48 EST-SSR markers were developed based on the trials of transferability of these primers in little millet. The EST-SSR amplicons showed reproducible single band polymorphism and produced a total of 160 alleles with an average of 3.3 alleles per locus in 37 accessions of little millet. The average values of expected and observed heterozygosities were 0.266 and 0.123, respectively. The polymorphic information content (PIC) values were observed in range of 0.026 to 0.549 with an average of 0.240. The genetic relatedness among the little millet accessions was evaluated by neighbor-joining dendrogram, which grouped all accessions into two distinct groups. The validation thus demonstrated the utility of the switchgrass EST-SSR markers in assessing genomic relationships in little millet. The findings from this study could be useful for designing strategies for the identification of diverse germplasm for conservation and future molecular breeding programs for little millet.

Image Interpolation Using Linear Modeling for the Absolute Values of Wavelet Coefficients Across Scale (스케일간 웨이블릿 계수 절대치의 선형 모델링을 이용한 영상 보간)

  • Kim Sang-Soo;Eom Il-Kyu;Kim Yoo-Shin
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.42 no.6
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    • pp.19-26
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    • 2005
  • Image interpolation in the wavelet domain usually takes advantage of the probabilistic models for the intrascale statistics and the interscale dependency. In this paper, we adopt the linear model for the absolute values of wavelet coefficients of interpolated image across scale to estimate the variances of extrapolated bands. The proposed algorithm uses randomly generated wavelet coefficients based on the estimated parameters for probabilistic model. Random number generation according to the estimated probabilistic model may induce the 'salt and pepper' noise in subbands. We reduce the noise power by Wiener filtering. We observe that the proposed method generates the histogram of the subband coefficients similar to the that of original image. Experimental results show that our method outperforms the previous wavelet-domain interpolation method as well as the conventional bicubic method.

Study on Antioxidant and Anti-inflammatory Activities of Persicaria tinctoria (쪽의 항산화 및 항염증 활성에 대한 연구)

  • Kim, Soo-Jeung;Jang, Tae Won;Kim, Do-Wan;Park, Jae Ho
    • The Korea Journal of Herbology
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    • v.30 no.6
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    • pp.17-24
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    • 2015
  • Objectives : Persicaria tinctoria belongs to the Polygonaceae family and it has been used as the natural dye traditionally. Also, it is well known that the Persicaria tinctoria is used for treating the following symptoms such as fever, inflammation and edema. The purpose of this study is to investigate the effective source of antioxidants and anti-inflammatory agent from various parts of Persicaria tinctoria.Methods : We investigated the antioxidative and anti-inflammatory properties of the Persicaria tinctoria extracts. Antioxidant activities were measured by 1,1-diphenyl-2- picrylhydrazyl (DPPH), 2, 2'-Azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS) radical scavenging activity, Fe2+ chelating activity and Reducing power of Persicaria tinctoria extracts. And its inhibitory effect against oxidative DNA damage was evaluated in non-cellular system using φX-174 RF I plasmin DNA. The anti-inflammatory effect of Persicaria tinctoria was measured by using the inhibitory efficacy for the amount of nitric-oxide (NO) produced in LPS induced RAW264.7 cells.Results : The extracts from stem part showed better DPPH scavenging activity compared to those of the leaf and root extracts. Their IC50s were measured as 7.17, 144.40 and 165.07 ug/ml, respectively. These results were similar to that of ABTS radical scavenging assay and reducing power. Also, Persicaria tinctoria showed the protective effects of DNA damage against oxidative stress and anti-inflammatory effect by suppression of NO production in LPS induced RAW264.7 cells.Conclusions : These results showed that various parts of Persicaria tinctoria can be used as an effective source of antioxidants and anti-inflammatory agents via antioxidative activities and anti-inflammatory effect.

Study on the Sodium Intake Knowledge and Practices for Reducing Sodium Intake in Soldiers (군인의 나트륨 섭취와 나트륨 줄이기 관련 지식 및 실천에 관한 연구)

  • Hwang, Ji Min;Min, Sung Hee;Lee, Min June
    • Journal of the East Asian Society of Dietary Life
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    • v.26 no.6
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    • pp.550-558
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    • 2016
  • This study was conducted to provide guideline data for future instructional materials and practice guidelines on reforming the dietary life of military personnel in terms of lowering sodium intake. A total of 264 persons were surveyed to obtain basic data on sodium intake and understanding of sodium. The study also examined the practice that is carried forward in this endeavor. The subjects liked 'kimchi' and 'rice with topping', and these could be the reason for higher salt intake. Career soldiers scored higher in terms of nutrition knowledge than enlisted soldiers (p<0.01). Nutrition education concerning sodium intake was statistically insignificant between the two, whereas career soldiers showed a higher experience rate at these nutrition educational events. Career soldiers also had with higher sodium intake than enlisted soldiers, and this difference was statistically significant (p<0.01). In terms of practice, officers were more likely to experience difficulty in putting the theory of less sodium into practice than their enlisted soldiers counterparts (p<0.05), and the main reason behind this difficulty was that they did not feel the need to lower their sodium intake. Soldiers should be well educated about sodium and healthy diet during their service. Education should focus on lowering sodium intake and changing their attitudes and awareness of this issue in order to elicit behavioral changes.

Specification Scheme of Pig Liquid Manure as Organic Agricultural Substances Used for Organic Farming

  • Seo, Il-Hwan;Lee, Kyo-Suk;Rhie, Ja-Hyun;Min, Se-Won;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.462-471
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    • 2017
  • A more efficient use of nutrients from organic sources can benefit both farmers and water quality in agriculture. In this paper we reviewed information related to the regulations and guidelines of a swine liquid fertilizer to propose an establishment scheme for the official standards of swine manure slurry as a liquid fertilizer for organic farming. According to the law of establishment and designation of official standard of fertilizers, the liquid fertilizer made with pig liquid manure belongs to the byproduct fertilizer as of one of organic fertilizer. However, the official standards for byproduct fertilizers including the liquid fertilizer set by the Rural Development Administration (RDA), especially for a liquid swine manure fertilizer, should be revised to meet the goals of laws pursuing the environmentally sound agriculture, especially for organic farming because the terms and relevant standards need additional specific standards alike the standards such as impurities and parameter for declaration in EU. Therefore, it is suggested that official standards for byproduct fertilizers should be revised with respect to nutrient, salt content as of SAR and Na content instead of NaCl. Also we need to develop the maximum limit of heavy metals in soil to which the liquid fertilizer can be applied, as well as application rate depending on EC of the liquid fertilizer.

A Study on the Physical Properties of Compound of Pyrazine with Cromium Trioxide (Pyrazine의 Cr$O_3$ 화합물의 물성에 관한 연구)

  • Jung Sung Yang
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.11-17
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    • 1989
  • Pyrazinium chlorochromate and dipyrazinium trichromate which are pyrazinium salts were prepared by the each reaction of pyrazine with chromium trioxide under the presence of HCl and $CH_2Cl_2$. These compounds wese nonhygroscopic and were solved in water very well. Physical properties such as solubility, pH, electrical conductivity, and melting point were measured. These compounds were considered to be ionic ; $C_4H_4N_2H^+$, $CrO_3Cl^-$, $Cr_3O^{2-}_{10}$ by the measurement of electrical conductivity. It was found that CrO$_3$ was formed in the first decomposition process of salts and it was changed into $Cr_2O_3$ in the second process as its weight is decreased. It was also found that especially under the same condition dipyrazinium salt was in the form of isopoly ($Cr_2O^{2-}_{10}$)anion which has been thought to be in the form of $Cr_2O^{2-}_{7}$ obtained from pyridine.

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Preparation and Characterization of Chemical Gel Based on [Epoxy/PEG/PVdF-HFP] Blend for Lithium Polymer Battery Applications ([Epoxy/PEG/PVdF-HFP] 복합체를 이용한 리튬고분자전지용 화학겔의 제조 및 분석)

  • Kim, Joo-Sung;Seo, Jeong-In;Bae, Jin-Young
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.544-550
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    • 2009
  • In this study, we have designed [Epoxy/PEG] polymer gel electrolyte systems by thermal curing the mixtures of epoxy, PEG, imidazole catalyst, and a plasticizer of 1:1 ethylene carbonate and propylene carbonate in the presence of $LiPF_6$ salt. In order to enhance the poor mechanical property of the Corresponding [Epoxy/PEG] gel electrolyte PVdF-HFP was incorporated into the system. The ionic conductivities of the polymer gel electrolytes were related to the amount of PVdF-HFP in blends as well as the amount of liquid electrolyte. The optimized gel system showed room-temperature conductivities of $2.56\times10^{-3}S/cm$.