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The Processing control of NiCuZn Ferrite (I) - Mixing and Size Reduction of Raw Materials by Wet Ball Milling. (NiCuZn Ferrite의 제조공정 제어 (제1보) - 습식 볼밀링에 의한 다성분 원료의 혼합 및 분쇄 공정의 고찰)

  • 류병환;김선희;최경숙;고재천
    • Journal of the Korean Magnetics Society
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    • v.5 no.6
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    • pp.928-936
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    • 1995
  • In this research, the processing control of NiCuZn Ferrite has been developed. The mixing and the size reduction of raw materials have been proceeded. In order to produce NiCuZn Ferrite, highly concentrated slurry with fixed ratio and wet ball milling were used. First, the dispersion behavior of raw mixture at the region of pH4~pH11 has been studied. Using wet ball milling operation, the best conditions of mixing and size reduction have been determined. Further more, the most suitable conditions, such as, dispersant kind, dispersant amount, milling time, and slurry concentration have been studied. The poly acrylic ammonium salt (PAN) was chosen as a suitable dispersant to have effective dispersion in basic region. The slurry of raw mixture without dispersant, showed high viscosity and poor grindability. As 0.7 wt% of PAN was added, the concentrated slurry (up to 55 vol%) was possible, and showed well grindability. After 18 h ball milling of 30 vol% of mixture slurry with 0.7 wt% of PAN, the average particle size and specific surface area of raw mixture were $0.54\mu\textrm{m}$ and $12.92m^{2}/cc$, respectively. The ball milled raw mixture, calcined at $700^{\circ}C$ for 3h, was totally changed into NiCuZn Ferrite with spinel phase.

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(Technical note) Pollen and dinoflagellate cyst assemblages from the surface sediments of the lower reach of the Jujin Stream ((기술노트) 주진천 하류역의 퇴적물에서 산출되는 화분과 와편모조류 군집 특성)

  • Sangheon Yi;Jin-Young Lee;Min Han;Jaesoo Lim;Chang-Pyo Jun
    • The Korean Journal of Quaternary Research
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    • v.33 no.1_2
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    • pp.59-68
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    • 2021
  • The maximum upper limit of seawater inflow can be recognized by the acid-resistant dinoflagellate cysts and salt-marsh pollen encountered from surface samples in the lower reach of Jujin Stream facing Gomso Bay. Based on their relative yield ratio, the downstream area of Jujin Stream could be further subdivided into coastal marine, brackish-upper limit brackish, and freshwater environments. The abundance of dinoflagellate cysts from JJR-41 to JJR-36 sites reflects that this area is a coastal marine. In the section between JJR-35 and JJR-5 sites, dinoflagellate cysts associated with pollen derived from riparian or salt-marsh (e.g., reeds and sedges) appear to reflect the brackish environments. It may be indicated that dinoflagellate cysts appear up to the JJR-4 site, which is the maximum upper limit where seawater flows up to this point at high tide. This analysis is relatively well corresponding to the hypothetical inundation map showing the maximum flooding area where seawater can flow at high tide.

Characterization of Arsenic Sorption on Manganese Slag (망간슬래그의 비소에 대한 수착특성 연구)

  • Seol, Jeong Woo;Kim, Seong Hee;Lee, Woo Chun;Cho, Hyeon Goo;Kim, Soon-Oh
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.4
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    • pp.229-244
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    • 2013
  • Arsenic contamination may be brought about by a variety of natural and anthropogenic causes. Among diverse naturally-occurring chemical speciations of arsenic, trivalent (As(III), arsenite) and pentavalent (As(V), arsenate) forms have been reported to be the most predominant ones. It has been well known that the behavior of arsenic is chiefly affected by aluminum, iron, and manganese oxides. For this reason, this study was initiated to evaluate the applicability of manganese slag (Mn-slag) containing high level of Mn, Si, and Ca as an efficient sorbent of arsenic. The main properties of Mn-slag as a sorbent were investigated and the sorption of each arsenic species onto Mn-slag was characterized from the aspects of equilibrium as well as kinetics. The specific surface area and point of zero salt effect (PZSE) of Mn-slag were measured to be $4.04m^2/g$ and 7.73, respectively. The results of equilibrium experiments conducted at pH 4, 7 and 10 suggest that the sorbed amount of As(V) was relatively higher than that of As(III), indicating the higher affinity of As(V) onto Mn-slag. As a result of combined effect of pH-dependent chemical speciations of arsenic as well as charge characteristics of Mn-slag surface, the sorption maxima were observed at pH 4 for As(V) and pH 7 for As(III). The sorption of both arsenic species reached equilibrium within 3 h and fitting of the experimental results to various kinetic models shows that the pseudo-second-order and parabolic models are most appropriate to simulate the system of this study.

Effect of Chloride-deicers on Growth of Wheat, Barley and Spinach (염화물계 제설제의 밀, 보리, 시금치 생육에 미치는 영향)

  • Kim, Soon-Il;Lee, Dae-Weon
    • Korean Journal of Environmental Agriculture
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    • v.33 no.4
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    • pp.350-357
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    • 2014
  • BACKGROUND: Deicers such as calcium chloride ($CaCl_2$) and sodium chloride (NaCl) in Korea have been commonly used to reduce traffic accidents as well as injuries. However there have been adverse effects of deciders such as pollution of water and soil, and reduced productivity of agriculture as well as forest. This study aimed to investigate biological effects of the deicers against wheat, barley, and spinach. METHODS AND RESULTS: The germination of tested crop seeds exposed to chloride-deicers, $CaCl_2$ and NaCl was significantly reduced at over 3% concentration of chloride-deicers compared to the control. In spraying deicers to the seedlings of the crops, there was no symptom such as inhibition of growth rate or leaf elongation. However the germination of tested crop seeds was affected at 2% concentration of deicers when they were exposed continuously to deicers in soils. The growth of the shoot against $CaCl_2$ and NaCl treatments was very similar in wheat and barley whereas the shoot of spinach was the most susceptible. Based on these results, the sensitivity of the crops to the tested deicers was as follows: NaCl > $CaCl_2$ > mixture ($CaCl_2$ + NaCl). The length of shoots and roots of the seedlings grown in 1% treated soil was decreased. The biomass of all the seedlings decreased 1.5 to 4 times at 1%. CONCLUSION: These results indicate that the effects of salt deicers by inputting into soil against growing tested crops are more severe in germination and growth inhibition as well as biomass decrease.

Comparison of antioxidant, ${\alpha}$-glucosidase inhibition and anti-inflammatory activities of the leaf and root extracts of Smilax china L. (청미래덩굴 잎 및 뿌리 추출물의 항산화, ${\alpha}$-Glucosidase 억제 및 항염증 활성비교)

  • Kim, Kyoung Kon;Kang, Yun Hwan;Kim, Dae Jung;Kim, Tae Woo;Choe, Myeon
    • Journal of Nutrition and Health
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    • v.46 no.4
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    • pp.315-323
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    • 2013
  • This study was conducted in order to compare the biological activities of leaf and root water extracts of Smilax china L. (SC) by measuring the total polyphenol and flavonoid contents, anti-oxidant activity, inhibitory effect on ${\alpha}$-glucosidase, and anti-inflammatory gene expression. The total polyphenol and flavonoid contents of SC leaf (SCLE) and root (SCRE) water extracts were 127.93 mg GAE/g and 39.50 mg GAE/g and 41.99 mg QE/g and 1.25 mg QE/g, respectively. The anti-oxidative activities of SCLE and SCRE were measured using the 1,1-diphenyl-2-picrylhydrazyl (DPPH) and 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS) radical scavenging activity assay and reducing power assay. Both SCLE and SCRE scavenged radicals in a concentration-dependent manner, and SCLE showed stronger radical scavenging activity and reducing power than SCRE; however, both SCLE and SCRE exhibited lower activities than ascorbic acid. Compared to the anti-diabetic drug acarbose, which was used as a positive control, SCLE and SCRE exhibited low ${\alpha}$-glucosidase inhibition activities; nevertheless, the activity of SCLE was 3.7 fold higher than that of SCRE. Finally, SCLE caused significantly decreased expression of the LPS-induced cytokines, iNOS, and COX-2 mRNA in RAW264.7 cells, indicating anti-inflammatory activity. These results indicate that SCLE might be a potential candidate as an anti-oxidant, anti-diabetic, and anti-inflammatory agent.

Determination of the Optimum Condition in Preparing Gulbi (salted and semi-dried Yellow croaker, Larimichthys polyactis) by Brine Salting with Onion Peel Extract (양파껍질 추출물이 함유된 물간법으로 굴비 제조의 최적 조건 확립)

  • Shin, Mee-Jin;Kang, Seong-Gook;Kim, Seon-Jae;Kim, Jeong-Mok
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.8
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    • pp.1385-1389
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    • 2004
  • For the development of better Gulbi processing, brine salting method was applied for the Yellow croaker (Larimichthys polyactis). The changes of moisture contents, salt contents, and total microbial numbers in Yellow croaker were measured following different brine concentration (20, 30%), temperature (5, 25, 35$^{\circ}C$), and soaking time (1, 6, 12, 24 hours) by brine salting method. Rate of salt penetration into Yellow croaker muscle increased as higher brine concentration and higher dipping temperature. When compared to commercial products of Gulbi by dry-salting method, the moisture and salt contents in Yellow croaker showed similar values after treated with 20% brine at $25^{\circ}C$ for 1 hour. The weight of Yellow croaker increased about 4% when immersed it in 20% brine at 5$^{\circ}C$ for 24 hours. There was no weight change at $25^{\circ}C$ dipping temperature and reduced 7% of weight at 35$^{\circ}C$ dipping temperature. At 30% brine concentration, the weight of Yellow croaker reduced 1%, 9%, and 13% on weight at 5$^{\circ}C$, $25^{\circ}C$, and 35$^{\circ}C$, respectively. Total microbial counts in Yellow croaker muscle soaked at 30% brine showed 1 log lower numbers than 20%. The muscles had about 1 log higher microbial numbers than the treated brine solution. An ethanol extract of onion peel added to brine for giving better color and for preventing oxidation on Gulbi lipid. The treated group showed higher Land b values on Gulbi surface as well as antioxidant effect on the extracted oil.

Snow Influence on the Chemical Characteristics of Winter Precipitation (강설이 겨울철 강수의 화학적 특성에 미치는 영향)

  • Kang, Gong-Unn;Kim, Nam-Song;Oh, Gyung-Jae;Shin, Dae-Yewn;Yu, Du-Cheol;Kim, Sang-Baek
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.1
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    • pp.113-125
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    • 2007
  • To know the differences in ionic compositions in rain and snow as well as snow influence on the chemical characteristics of winter precipitation, precipitation samples were collected by the wet-only automatic precipitation sample, in winter(November-February) in the Iksan located in the northwest of Chonbuk from 1995 to 2000. The samples were analyzed for concentrations of water-soluble ion species, in addition to pH and electrical conductivity. The mean pH of winter precipitation was 4.72. According to the type of winter precipitation, the mean pH of rain was 4.67 and lower than 5.05 in snow. The frequencies of pH below 5.0 in rain were about 73%, while those in snow were about 30%. Snow contained 3 times higher concentrations of sea salt ion components originated from seawater than did rain in winter, mainly $Cl^-,\;Na^+$, and $Mg^{2+}$. Neglecting sea salt ion components, $nss-SO_4^{2-}$ and $NO_3^-$ were important anions and $NH_4^+$ and $nss-Ca^{2+}$ were important cations in both of rain and snow. Concentrations of $nss-SO_4^{2-}$ was 1.3 times higher in rain than in snow, while those of $nss-Ca^{2+}$ and $NO_3^-$ were 1.5 and 1.3 times higher in snow, respectively. The mean equivalent concentration ratio of $nss-SO_4^{2-}/NO_3^-$ in winter precipitation were 2.4, which implied that the relative contribution of sulfuric and nitric acids to the precipitation acidity was 71% and 29%, respectively. The ratio in rain was 2.7 and higher than 1.5 in snow. These results suggest that the difference of $NO_3^-$ in rain and snow could be due to the more effective scavenging of $HNO_3$ vapor than particulate sulfate or nitrate by snow. The lower ratio in snow than rain is consistent with the measurement results of foreign other investigators and with scavenging theory of atmospheric aerosols. Although substantial $nss-SO_4^{2-}$ and $NO_3^-$ were observed in both of rain and snow, the corresponding presence of $NH_4^+,\;nss-Ca^{2+},\;nss-K^+$ suggested the significant neutralization of rain and snow. Differences in chemical composition of non-sea salt ions and neutralizing rapacity of $NH_4^+,\;nss-Ca^{2+}$, and $nss-K^+$ between rain and snow could explain the acidity difference of rain and snow. Snow affected that winter precipitation could be less acidic due to its higher neutralizing rapacity.

The Long-term Variations of Water Qualities in the Saemangeum Salt-Water Lake after the Sea-dike Construction (방조제 체절이후 새만금호의 장기적인 수질변화)

  • Jeong, Yong Hoon;Yang, Jae Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.2
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    • pp.51-63
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    • 2015
  • In order to investigation long-term variations of water qualities in the Saemangeum Salt-Water Lake formed after the sea-dike construction, the survey has carried out over 40 time from 2002 to 2010. The decreased salinity in surface water immediately after the dike construction has maintained on equal terms for years. After the dike construction, the early concentration of SPM in surface water has decreased but then it showed the tendency to move up and down due to the changes of water level in the lake. The elevated concentration of Chl-a in surface water initially after the dike construction was kept at the same conditions for years. The concentration of DIN in surface water has not changed before and shortly after the dike construction. However, the concentration of $NH_4-N$ in surface water has increased steadily after the dike construction. Consequently the concentration of DIN in the lake water after years has raised compared to pre-dike construction. The reduced concentration of DIP in surface water soon after the dike construction has increased after years as well as $NH_4-N$ due to the accumulation of organic matter to inside lake. Unlike with the unvaried $NO_3-N$, the concentration of DISi in surface water after the dike construction has immediately increased and maintained the enhanced level indicating the supply from other sources except the freshwater. Since the dike construction, the spatial characteristics of water quality was divided river sides and rest of the lake markedly. Stratification of river sides was more strong than the dike sides. In the warm seasons, hypoxia causing the release of nutrients and metals from sediment was observed downward about 1 m from surface of river sides. We strongly suggest to make some urgent measure to prevent low dissolved oxygen condition in the bottom layer of the river sides.

Effects of Compressed Expansion Rice Hull Application and Drip Irrigation on the Alleviation of Salt Accumulation in the Plastic Film House Soil (팽화왕겨 처리와 점적관개에 의한 염류집적 시설재배지 염류경감 효과)

  • Cho, Kwang-Rae;Kang, Chang-Sung;Won, Tae-Jin;Park, Kyeong-Yeol
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.372-379
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    • 2006
  • This study was carried out to improve chemical properties of salt-accumulated plastic film house soil. Compressed expansion rice hull was applied at 0, 2.5, 5.0, $7.5Mg\;ha^{-1}$, and drip irrigation was initiated at -33 kilopascals (kPa) of soil water potential and ceased adjusted up to -10 kPa. Another treatment was the application of inflated rice hull at $5.0Mg\;ha^{-1}$ with drip irrigation starting at soil water potential -20 kPa and adjusted to -10 kPa. Lettuce(Lactuca sativa L.) was cultivated at sandy loam soil with $5.1dS\;m^{-1}$ of electrical conductivity (EC). $EC_w$(1:5) of plots treated with $5.0Mg\;ha^{-1}$ of inflated rice hull and irrigated at the point of -20 kPa and -33 kPa of soil water potential was reduced by 26% and 24% less than untreated control plot, respectively. Soil $EC_w$(1:5) has close relationship with $Cl^-$ as well as $NO_3{^-}-N$ and $SO{_4}^{2-}$ in the soil. Total nitrogen in leaf of lettuce was deficient in the earlier growth stage. The yield of lettuce increased by 6% by the application of inflated rice hull of $5.0Mg\;ha^{-1}$ with drip irrigation starting at -33 kPa of soil water potential. It decreased 4% when the drip irrigation was stated at -20 kPa of soil water potential. The amount of water used for irrigation was reduced with the increasing application of inflated rice hull. The watering initiated at the point of -33 kPa was more economical compared with starting at -20 kPa.

Factors affecting the formation of bound 3-monochloropropane-1,2-diol in a fried snack model (유탕 과자 모델에서 결합형 3-monochloropropane-1,2-diol 생성에 영향을 미치는 요인)

  • Kang, Jun-Hyuk;Joung, Woo-Young;Rho, Hoi-Jin;Baek, Hyung-Hee
    • Korean Journal of Food Science and Technology
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    • v.52 no.6
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    • pp.565-572
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    • 2020
  • The 3-monochloropropane-1,2-diol (3-MCPD) is a contaminant that occurs in foodstuffs in its free form as well as in its bound form. The objective of this study was to evaluate the effects of emulsifier, frying temperature, and the amounts of salt and oil on the formation of bound 3-MCPD in a fried snack model. Emulsifier affected the formation of bound 3-MCPD; furthermore, it was observed that the largest amount of bound 3-MCPD was detected in the fried snack model when glycerin esters of fatty acids were used as emulsifiers. Frying temperature also affected the formation of bound 3-MCPD, which increased significantly as the frying temperature increased from 145 to 190℃. In addition, salt affected the formation of bound 3-MCPD. As the amount of salt increased, the amount of bound 3-MCPD also increased significantly. Moreover, it was observed that the amount of oil did not affect the formation of bound 3-MCPD. These results will aid in the reduction of bound 3-MCPD in fried snacks.