• Title/Summary/Keyword: salt in seawater

Search Result 169, Processing Time 0.019 seconds

A Study on the Characteristics of Fenton Oxidation of Bisphenol A and Nitrobenzene (비스페놀A와 니트로벤젠의 펜톤 산화분해 특성)

  • Bae, Su-Jin;Kwon, Hee-won;Kim, Ji-young;Hwang, In-Seong;Kim, Young-Hun
    • Journal of Environmental Science International
    • /
    • v.30 no.12
    • /
    • pp.1005-1014
    • /
    • 2021
  • Organic contaminants can be released into water environments due to chemical accidents and exist as dissolved and non-aqueous phase liquids (NAPL). Fenton oxidation was tested for bisphenol A and nitrobenzene as model organic contaminants in dissolved and NAPL states. Fenton oxidation was successfully applied for both of the dissolved and NAPL states of the two pollutants and the results indicated that a quick treatment was needed to reduce the risk from a chemical accidents instead of carrying out oxidation after the contaminants dissolve in water. A set of Fenton reactions were tested under seawater conditions because chemical accidents often occurs in the ocean. Chloride ions act as radical scavengers and inhibit Fenton oxidation. The reaction rate is inversely proportional to salt contents and the reduced reaction rate can be compensated by increasing the quantity of the oxidizing agents. The current study showes that Fenton oxidation could be applied as a quick treatments for organic contaminant in dissolved and NAPL state organic contaminants released as a result of leaks or chemical accidents.

A Study of the Strength and Durability Properties on Recycled Aggregate Concrete and Blain of Blast Furnace Slag (고로슬래그의 분말도 및 순환골재 치환율에 따른 콘크리트의 강도 및 내구적 특성에 관한 연구)

  • Lim, Myung-Kwan;Park, Moo-Young;Jung, Sang-Jin
    • Journal of the Korea Institute of Building Construction
    • /
    • v.7 no.4
    • /
    • pp.101-108
    • /
    • 2007
  • Furnace slag powder used currently in Korea needs to add special functions in response to the increase of large-scale projects. In addition, it is advantageous in that it has a lower hydration heat emission rate than ordinary Portland cement and improves properties such as the inhibition of alkali aggregate reaction, watertightness, salt proofness, seawater resistance and chemical resistance. However, furnace slag powder is not self -hardening, and requires activators such as alkali for hydration. Accordingly, if recycled fine aggregate, from which calcium hydroxide is generated, and furnace slag, which requires alkali stimulation, are used together they play mutually complementary roles, so we expect to use the mixture as a resource-recycling construction material. Thus the present study purposed to examine the properties and characteristics of furnace slag powder and recycled aggregate, to manufacture recycled fine aggregate concrete using furnace slag and analyze its performance based on the results of an experiment, to provide materials on concrete using furnace slag as a cement additive and recycled fine aggregate as a substitute of aggregate, and ultimately to provide basic materials on the manufacturing of resource-recycled construction materials using binder and fine aggregate as recycled resources.

A report of 20 unrecorded bacterial species isolated from island and coastal ecosystems in 2023

  • Da Som Kim;Seung Yeol Shin;Heeyoung Kang;Jae Ho Song;Song-Ih Han
    • Journal of Species Research
    • /
    • v.13 no.3
    • /
    • pp.310-317
    • /
    • 2024
  • Various samples from island and coastal ecosystems in South Korea were investigated to discover unrecorded bacterial species. Soils from these areas, along with seawater samples, were plated on marine agar and R2A agar (containing 3% sea salt). From these samples, approximately 1,070 bacterial strains were isolated as single colonies and identified using 16S rRNA gene sequences. A total of 20 strains, which exhibited at least 98.7% similarity in their 16S rRNA gene sequences to those of validly published bacterial species not yet reported in Korea, were identified as unrecorded bacterial species. These strains belonged to three phyla, six classes, 10 orders, 14 families, and 16 genera. These were assigned as follows: Thioclava, Breoghania, Acidovorax, Erythrobacter, Paracoccus, Jiella, Aurantimonas, and Qipengyuania within the class Alphaproteobacteria; Pseudomonas, Cobetia, and Rheinheimera within the class Gammaproteobacteria; Aequorivita, Leeuwenhoekiella, and Polaribacter within the class Flavobacteriia; Algoriphagus within the class Cytophagia; and Microbacterium within the class Actinobacteria. The unreported species underwent further taxonomic characterization, which included assessments of Gram reaction, colony and cell morphology, biochemical and phylogenetic characteristics.

Seawater Intrusion due to Ground Water Developments in Eastern and Central Cheju Watersheds (중-동 제주 수역의 지하수 개발로 인한 해수침투)

  • 박남식;이용두
    • Journal of the Korean Society of Groundwater Environment
    • /
    • v.4 no.1
    • /
    • pp.5-13
    • /
    • 1997
  • The Island of Cheju plans massive ground water development to meet predicted water demand. Effective management of ground water resources requires impact assessment study. Due to the nature of the island, effects of sea water must be considered. In this work, salt water intrusion, due to hypothetical ground water development in Eastern and Central Cheju Watersheds, is predicted using a sharp-interface model. The model considers simultaneously hydrodynamics of both freshwater and saltwater. The hypothetical ground water development was designed such that it follows closely the regional ground water development plan. The numerical model predicted that the saltwater wedge may intude over 1km depending on the location. This observation leaves doubt on impact assement studies based on freshwater-flow only modeling.

  • PDF

Bioremediation of Phenolic Compounds Having Endocrine-disrupting Activity Using Ozone Oxidation and Activated Sludge Treatment

  • Nakamura, Yoshitoshi;Daidai, Masakazu;Kobayashi, Fumihisa
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • v.9 no.3
    • /
    • pp.151-155
    • /
    • 2004
  • The bioremediation of water system contaminated with phenolic compounds having endocrine-disrupting activity, i.e. 2,4-dichlorophenol, 2,4-dichlorophenoxy acetic acid (2,4-D), and 2,4,5-trichlorophenoxy acetic acid (2,4,5-T), was investigated by using ozone oxidation and activated sludge treatment. Ozone oxidation (ozonation time: 30 min) followed by activated sludge treatment (incubation time: 5 days) was an efficient treatment method for the conversion of phenolic compounds in water into carbon dioxide and decreased the value of total organic carbon (TOC) up to about 10% of initial value. Furthermore, 2,4-D was dissolved in water containing salt, i.e. artificial seawater (ASW), and this water was used as model coastal water contaminated with phenolic compounds. The activated sludge treatment (incubation time: 5 days) could consume significantly organic acids produced from 2,4-D in the model costal water by the ozone oxidation (ozonation time: 30min) and decrease the value of TOC up to about 35% of initial value.

Material Budgets in the Youngsan River Estuary with Simple Box Model (영산강 하구해역에서의 단순 박스모델에 의한 물질수지)

  • Lee, Kyeong-Sig;Jun, Sue-Kyung
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.12 no.4
    • /
    • pp.248-254
    • /
    • 2009
  • Budgets of fresh water, salt, DIP and DIN in the Youngsan river estuary were estimated seasonally in order to clarify the characteristics of material cycling and flux of nutrients with a simple box model. Inflow volumes of freshwater into system was approximately $36.481{\times}10^6{\sim}663.634{\times}10^6m^3/month$ and existing water mass of freshwater in system calculated by salt budget was approximately $2.515{\times}10^6{\sim}5.812{\times}10^6m^3$. Mean residence time of freshwater was calculated to be about 0.26~2.03 day. water exchange $1,248{\times}10^6{\sim}9,489{\times}10^6m^3/month$ assumed with salinity between estuary and adjacent ocean. Inflow mass of DIN and DIN were approximately 76.63~1,149.91 ton/month and 2.91~61.22 ton/month, respectively. Residence times of DIP and DIN were calculated to be 0.45~1.10 day and 0.28~1.92 day, respectively. The ratio of water residence time versus DIP, DIN residence time was calculated that freshwater residence time was longer than DIP, DIN residence time except for summer season. Thus, We assume that circulation of Nutrients in the system will happen rapidly except for summer season. Specially DIP in Winter could assume to outer input source existence because of seawater inflow in system and high DIP concentration in open sea.

  • PDF

Experimental Study for Evaluation of Chloride Ion Diffusion Characteristics of Concrete Mix for Nuclear Power Plant Water Distribution Structures (원전 취배수 구조물 콘크리트 배합의 염소이온 확산특성 평가를 위한 실험적 연구)

  • Lee, Ho-Jae;Seo, Eun-A
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.26 no.5
    • /
    • pp.112-118
    • /
    • 2022
  • In this study, the diffusion characteristics were evaluated using the concrete mix design of nuclear safety-related structures. Among the concrete structures related to nuclear power safety, we selected the composition of intake and drainage structures that are immersed in seawater or located on the tidal platform and evaluated the chloride ion permeation resistance by compressive strength and electrical conductivity and the diffusion characteristics by immersion in salt water. analyzed. Compressive strength was measured on the 1st, 7th, 14th, 28th, 56th, and 91st days until the 91st day, which is the design standard strength of the nuclear power plant concrete structure, and chloride ion permeation resistance was evaluated on the 28th and 91st. After immersing the 28-day concrete specimens in salt water for 28 days, the diffusion coefficient was derived by collecting samples at different depths and analyzing the amount of chloride. As a result, it was found that after 28 days, the long-term strength enhancement effect of the nuclear power plant concrete mix with 20% fly ash replacement was higher than that of concrete using 100% ordinary Portland cement. It was also found that the nuclear power plant concrete mix has higher chloride ion permeation resistance, lower diffusion coefficient, and higher resistance to salt damage than the concrete mix using 100% ordinary Portland cement.

Fabrication of Reverse Osmosis Membrane with Enhanced Boron Rejection Using Surface Modification (표면개질을 이용하여 붕소 제거율이 향상된 역삼투막의 제조)

  • Lee, Deok-Ro;Kim, Jong Hak;Kwon, Sei;Lee, Hye-Jin;Kim, In-Chul
    • Membrane Journal
    • /
    • v.28 no.2
    • /
    • pp.96-104
    • /
    • 2018
  • With the rapid increase in seawater desalination, the importance of boron rejection is rising. This study was conducted to investigate the effect of hydrophilic compounds on surface modification to maximize water flux and increase boron rejection. First, polyamide active layer was fabricated by interfacial polymerization of polysulfone ultrafiltration membrane with M-phenylenediamine (MPD) and trimesoyl chloride (TMC) to obtain Control polyamide membrane. Next, D-gluconic acid (DGCA) and D-gluconic acid sodium salt (DGCA-Na) were synthesized with glutaraldehyde (GA) and hydrochloric acid (HCl) by modifying the surface of Control polyamide membrane. XPS analysis was carried out for the surface analysis of the synthesized membrane, and it was confirmed that the reaction of surface with DGCA and DGCA-Na compounds was performed. Also, FE-SEM and AFM analysis were performed for morphology measurement, and polyamide active layer formation and surface roughness were confirmed. In the case of water flux, the membrane fabricated by the surface modification had a value of 10 GFD or less. However, the boron rejection of the membranes synthesized with DGCA and DGCA-Na compounds were 94.38% and 94.64%, respectively, which were 12.03 %p and 12.29 %p larger than the Control polyamide membrane, respectively.

Penetration Properties of Airborne Chlorides on Concrete Exposed in Marine Environment (해안환경에 노출된 콘크리트의 비래염분 침투 특성)

  • Lee, Jong-Suk;An, Gi-Hong
    • Journal of the Korea Concrete Institute
    • /
    • v.24 no.5
    • /
    • pp.553-558
    • /
    • 2012
  • Airborne chlorides are transported to inland by sea wind to be attached to seashore concrete structure surface then penetrated into concrete structure members. Since the surface attached chloride amount are dependent on the amount of airborne chlorides, the prediction of distribution of airborne chlorides is important information in preventing chloride corrosion problems in seashore concrete structures. The prediction of surface chloride amount from airborne chlorides environment is extremely difficult than concrete directly in contact with seawater. In addition, their penetrating tendency is different from that of concrete immersed in seawater. In this study, properties of surface and penetrated chlorides under airborne chlorides environment are investigated. Concrete specimens were manufactured and exposed to marine environment for 3 years. The specimens were analyzed at the time durations of 1, 2, and 3 years to check surface chloride amount to penetrated chloride depth. The results revealed that there were certain differences according to surface roughness of concrete and with and without washing effect due to rainfalls. The evaluation results showed that penetrated chlorides depend on amount of airborne chlorides and duration of exposure. In addition, a notable tendency of having deeper chloride penetration and higher chloride content in concrete members under long-term exposure was observed.

A Study on Predicting the Range of Cooling Effect and the Diffusion of Water Particles that are Generated from a Fountain (분수에서 생성되는 물입자의 확산과 냉각효과의 범위 예측)

  • Lee, Sang-Deug
    • Journal of Environmental Science International
    • /
    • v.20 no.7
    • /
    • pp.819-828
    • /
    • 2011
  • This research was done to clarify the cooling effect of water particles generated from a fountain. This effect is a one way to control the heat island effect of big cities. The result of this research was drawn by setting the jets of water in a certain height, and then studying the diffusion of water particles, which is affected by the size of the particles and the wind speed, and the cooling effect caused by the diffusion. 1) When a diameter of a water drop was 500 ${\mu}m$ and the wind speed was 2.0 to 6.0 m/sec, the water drop diffused 75 to 190m, and the water vapor spread over 175 to 440 m. As a result, there was more than $0.5^{\circ}C$ of cooling effect on the temperature in the atmosphere 130 to 330m around the water fountain. 2) When a diameter of a water drop was 750 ${\mu}m$ and the wind speed was 2.0 to 6.0 m/sec, the water drop diffused 65 to 150 m, and the water vapor spread over 160 to 405 m. Moreover, there was more than $0.5^{\circ}C$ of cooling effect on the temperature in the atmosphere 110 to 275 m around the water fountain. 3) After studying on the relationship between the diameter of water drop and the wind speed, and the diffusion of water particles and the range of the atmosphere that was cooled, a result could be drawn from the research that the smaller the diameter of the water vapor gets and the faster the wind speed becomes, the wider the water particles diffuse and the cooler the atmosphere around the fountain becomes. 4) This research further extrapolates that when the ordinary water(tap water, water from river and stream) is used in a fountain, the cooling effect of the air near the fountain can be approached similarly. If the seawater is used in a fountain, there is to be more to concern not only on cooling effect on the air, but also on other effects on surrounding environment generated by the salt in seawater.