• Title/Summary/Keyword: safety properties

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Group Contribution Method and Support Vector Regression based Model for Predicting Physical Properties of Aromatic Compounds (Group Contribution Method 및 Support Vector Regression 기반 모델을 이용한 방향족 화합물 물성치 예측에 관한 연구)

  • Kang, Ha Yeong;Oh, Chang Bo;Won, Yong Sun;Liu, J. Jay;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.36 no.1
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    • pp.1-8
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    • 2021
  • To simulate a process model in the field of chemical engineering, it is very important to identify the physical properties of novel materials as well as existing materials. However, it is difficult to measure the physical properties throughout a set of experiments due to the potential risk and cost. To address this, this study aims to develop a property prediction model based on the group contribution method for aromatic chemical compounds including benzene rings. The benzene rings of aromatic materials have a significant impact on their physical properties. To establish the prediction model, 42 important functional groups that determine the physical properties are considered, and the total numbers of functional groups on 147 aromatic chemical compounds are counted to prepare a dataset. Support vector regression is employed to prepare a prediction model to handle sparse and high-dimensional data. To verify the efficacy of this study, the results of this study are compared with those of previous studies. Despite the different datasets in the previous studies, the comparison indicated the enhanced performance in this study. Moreover, there are few reports on predicting the physical properties of aromatic compounds. This study can provide an effective method to estimate the physical properties of unknown chemical compounds and contribute toward reducing the experimental efforts for measuring physical properties.

Effect of Thermal Aging on Microstructure and Mechanical Properties of China Low-Activation Martensitic Steel at 550℃

  • Wang, Wei;Liu, Shaojun;Xu, Gang;Zhang, Baoren;Huang, Qunying
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.518-524
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    • 2016
  • The thermal aging effects on mechanical properties and microstructures in China low-activation martensitic steel have been tested by aging at $550^{\circ}C$ for 2,000 hours, 4,000 hours, and 10,000 hours. The microstructure was analyzed by scanning and transmission electron microscopy. The results showed that the grain size and martensitic lath increased by about $4{\mu}m$ and $0.3{\mu}m$, respectively, after thermal exposure at $550^{\circ}C$ for 10,000 hours. MX type particles such as TaC precipitated on the matrix and Laves-phase was found on the martensitic lath boundary and grain boundary on aged specimens. The mechanical properties were investigated with tensile and Charpy impact tests. Tensile properties were not seriously affected by aging. Neither yield strength nor ultimate tensile strength changed significantly. However, the ductile-brittle transition temperature of China low-activation martensitic steel increased by $46^{\circ}C$ after aging for 10,000 hours due to precipitation and grain coarsening.

A Study on Enhancing Institutionalization of the Fire Proofing and the Safety Management for Architectural Buildings as Cultural Properties (문화재 건축물의 화재예방 및 안전관리 제도개선 방안 연구)

  • Yi, Waon-Ho;Park, Byung-Cheol;Kim, Hee-Kyu;Park, Sang-Hyun;Lee, Jung-Han
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.04a
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    • pp.325-328
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    • 2008
  • The fire ravage of Sungnyemun in 10th Feb 2008 gave an opportunity to overview an existing management system regarding cultural assets, which have been out of disaster and safety management. According to this consideration, we could provide enhanced plans of safety management policy with regard to cultural properties. The incident has taught us the important experiences in terms of the safety management in normal and the cultural assets; moreover, we should do our best through dispassionate reflection and consistent efforts to inherit priceless cultural assets to the next generation.

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Influence of water content on dynamic mechanical properties of coal

  • Gu, Helong;Tao, Ming;Wang, Jingxiao;Jiang, Haibo;Li, Qiyue;Wang, Wen
    • Geomechanics and Engineering
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    • v.16 no.1
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    • pp.85-95
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    • 2018
  • Water affects the mechanical properties of coal and stress wave propagation. To comprehensively investigate the effect of water content on the properties of coal, laboratory tests including X-Ray Diffraction (XRD) analysis, P-wave test, S-wave test, static and dynamic compression test with different water contents were conducted. The compressive strength, elastic modulus and failure strain and their mechanism of coal specimen under coupled static-dynamic load with the increased water content were observed. Meanwhile, energy transmission and dissipation characteristics of a stress wave in coal specimens with different water contents under dynamic load and its relation with the failure features, such as fragmentation and fractal dimension, of coal was analyzed. Furthermore, the dynamic interpretation of water infusion to prevent coal burst based on water infusion model of coal seam roadway was provided.

The Dielectric Properties of the Wire for Silicon Rubber (전선용 실리콘 고무의 유전특성)

  • Lee, Sung-Ill;Park, Seoung-Ho
    • Proceedings of the Safety Management and Science Conference
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    • 2012.11a
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    • pp.355-368
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    • 2012
  • This paper, the hardness of the silicone rubber wire for 50, 60 degrees, 70 degrees High Temperature Vulcanizing (HTV) method using specimens were fabricated. In this paper, in order to investigate the dielectric properties of silicone rubber for wire specimens, the temperature range of $30^{\circ}C{\sim}170^{\circ}C$, the frequency range from 100Hz~4.5MHz report surveyed about the frequency and temperature dependent properties.

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The Flame Retardant and Mechanical Properties of Wood Flour-High Density Polyethylene Composites (목분-HDPE 복합체의 난연성 및 기계적 성질)

  • Shin, Baeg-Woo;Bang, Dae-Suk;Song, Young-Ho;Chung, Kook-Sam
    • Journal of the Korean Society of Safety
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    • v.27 no.1
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    • pp.26-31
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    • 2012
  • Wood-plastic composites represents a growing class of materials used by the residential construction industry and furniture industry. In this study, the effect of flame retardants on the flammability and mechanical properties of wood flour-high density polyethylene(HDPE) composites were studied. we were manufactured wood flour-HDPE composites by modular intermeshing co-rotating twin screw extruder with L/D ratio of 42. The flame retardant properties were used limiting oxygen index(LOI) and mechanical properties were measured by universal testing machine(UTM). The Morphological analysis of composites were analyzed by Scanning electron microscope(SEM). It was found that Ammonium polyphosphate can effectively reduce the flammability of the wood flour-HDPE composites. Marginal reduction in the mechanical properties of the composites was found with addition of flame retardants. SEM images showed that the coupling agent improved wood flour-HDPE interfacial bonding.

Sensitivity of SNF transport cask response to uncertainty in properties of wood inside the impact limiter under drop accident conditions

  • Lee, Eun-ho;Ra, ChiWoong;Roh, Hyungyu;Lee, Sang-Jeong;Park, No-Choel
    • Nuclear Engineering and Technology
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    • v.54 no.10
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    • pp.3766-3777
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    • 2022
  • It is essential to ensure the safety of spent nuclear fuel (SNF) transport cask in drop situation that is included in transport accident scenarios. The safety of the drop situation is affected by the impact absorption performance of impact limiters. Therefore, when designing an impact limiter, the uncertainty in the material properties that affect the impact absorption performance must be considered. In this study, the material properties of the wood inside the impact limiter were selected as the variables for a parametric study. The sensitivity analysis of the drop response of the SNF transport cask with impact limiter was performed. The minimum wood strength required to prevent a direct collision between the cask and floor was derived from the analysis results. In addition, the plastic strain response was analyzed and strain-based evaluation was performed. Based on this result, the critical values of wood properties that change the impact dynamic characteristics were investigated. Finally, the optimal material properties of wood were obtained to secure the structural safety of the SNF transport cask. The results of this study can contribute to the development of SNF transport cask, thereby ensuring safety in transport accident conditions.

A Study of the Evaluation of Combustion Properties of Tetralin (테트랄린의 연소특성치 평가에 관한 연구)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.33 no.4
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    • pp.8-14
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    • 2018
  • In the industrial chemical process involving combustible materials, reliable safety data are required for design prevention, protection and mitigation measures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. The combustion parameters necessary for process safety are lower flash point, upper flash point, fire point, lower explosion limit(LEL), upper explosion limit(UEL)and autoignition temperature(AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. In the chemical industries, tetralin which is widely used as a raw material of intermediate products, coating substances and rubber chemicals was selected. For safe handling of tetralin, the lower and flash point, the fire point, and the AIT were measured. The LEL and UEL of tetralin were calculated using the lower and upper flash point obtained in the experiment. The flash points of tetralin by using the Setaflash and Pensky-Martens closed-cup testers measured $70^{\circ}C$ and $76^{\circ}C$, respectively. The flash points of tetralin using the Tag and Cleveland open cup testers are measured $78^{\circ}C$ and $81^{\circ}C$, respectively. The AIT of the measured tetralin by the ASTM E659 apparatus was measured at $380^{\circ}C$. The LEL and UEL of tetralin measured by Setaflash closed-cup tester at $70^{\circ}C$ and $109^{\circ}C$ were calculated to be 1.02 vol% and 5.03 vol%, respectively. In this study, it was possible to predict the LEL and the UEL by using the lower and upper flash point of tetralin measured by Setasflash closed-cup tester. A new prediction method for the ignition delay time by the ignition temperature has been developed. It is possible to predict the ignition delay time at different ignition temperatures by the proposed model.

On Relationship between Safety and Liveness of Election Problem in Asynchronous Distributed Systems

  • Park, Sung-Hoon
    • International Journal of Contents
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    • v.7 no.4
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    • pp.30-34
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    • 2011
  • A Leader is a Coordinator that supports a set of processes to cooperate a given task. This concept is used in several domains such as distributed systems, parallelism and cooperative support for cooperative work. In completely asynchronous systems, there is no solution for the election problem satisfying both of safety and liveness properties in asynchronous distributed systems. Therefore, to solve the election problem in those systems, one property should be weaker than the other property. If an election algorithm strengthens the safety property in sacrifice of liveness property, it would not nearly progress. But on the contrary, an election algorithm strengthening the liveness property in sacrifice of the safety property would have the high probability of violating the safety property. In this paper, we presents a safety strengthened Leader Election protocol with an unreliable failure detector and analyses it in terms of safety and liveness properties in asynchronous distributed systems.

Study on the Development of Standard Reference Materials for Safety Control of Construction Materials (건설재료의 안전적 제어를 위한 표준물질 (Standard Reference Materials) 도출)

  • Lee, Dong Kyu;Lee, Keon Woo;Choi, Myoung Sung
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.54-61
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    • 2017
  • The purpose of this study is to develop standard reference materials for safety control of construction materials considering the required performance of standard materials including flow performance incorporating particles. The flow characteristics of concrete are very complicated depending on mixing proportions of constituent materials, admixtures, amount of mixing, type of mixer, time of mixing, temperature and so forth. Uncertainties and multidimensional properties of concrete have been evaluated through various studies but there are few researches for the development of standard reference material. In this study, based on the rheological concept, the flow performance of construction materials was evaluated to understand the properties of standard reference materials and was finally obtained representing materials which simulate the standard reference materials.