• 한국산업보건학회지
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• 제25권2호
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• pp.134-145
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• 2015

Objectives: An objective of this study was to perform a risk assessment and social cost-benefit analysis for revising permissible exposure limits for seven substances: Nickel(Insoluble inorganic compounds), benzene, carbon disulfide, formaldehyde, cadmium(as compounds), trichloroethylene, touluene-2,4-diisocyanate. Materials and Methods: The research methods were divided into risk and hazard assessment and cost-benefit analysis. The risk and hazard assessment for the seven substances consists of four steps: An overview of GHS MSDS(1st), review of document of ACGIH's TLVs (2nd), comparison between international occupational exposure limits and domestic permissible exposure limits(3rd), and analysis of excess workplace and excess rate for occupational exposure limits based on previous work environment measurement data(4th). Total cost was estimated using cost of local exhaust ventilation, number of excess workplace and penalties for exceeding a permissible exposure limit. On the other hand, total benefit was calculated using the reduction rate of occupational disease, number of workplaces treating each substance and industrial accident compensation. Finally, the net benefit was calculated by subtracting total cost from total benefit. Results: All the substances investigated in this study were classified by CMR(Carcinogens, Mutagens or Reproductive toxicants) and their international occupational exposure limits were stricter than the domestic permissible exposure limits. As a result of excess rate analysis, trichloroethylene was the highest at 11%, whereas nickel was the lowest at 0.5%. The excess rates of all substances except for trichloroethylene were observed at less than 10%. Among the seven substances, the total cost was highest for trichloroethylene and lowest for carbon disulfide. The benefits for the seven substances were higher than costs estimated based on strengthening current permissible exposure limits. Thus, revising the permissible exposure limits of the seven substances was determined to be acceptable from a social perspective. Conclusions: The final revised permissible exposure limits suggested for the seven substances are as follows: $0.2mg/m^3$ for nickel, 0.5 ppm(TWA) and 2.5 ppm(STEL) for benzene, 1 ppm(TWA) for carbon disulfide, $0.01mg/m^3$(TWA) for cadmium, 10 ppm(TWA) and 25 ppm(STEL) for trichloroethylene, 0.3 ppm(TWA) for formaldehyde, and 0.005 ppm(TWA) and 0.02 ppm(STEL) for toluene diisocynate(isomers).

• 한국안전학회지
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• 제14권1호
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• pp.93-100
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• 1999

By using literature data, the empirical equations have been derived which describe the interrelationships of explosion and other related properties of n-alcohols. The properties which have been correlated data are : lower and upper explosive limits, heats of combustion, carbon numbers. Also, the new equation for predicting the temperature dependence of lower explosive limits(LEL) of n-alcohols on the basis of explosive limits, heats of combustion, flame propagation theory and mathematical method is proposed. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given explosive properties. by using the proposed equations, it is possible to predict the other properties. It is hoped eventually that this method will permit the estimation of the explosive properties of alcohol with improved accuracy and the broader application for other compounds.

• 한국안전학회지
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• 제25권4호
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• pp.30-35
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• 2010

For the safe handling of acetone, the flash point, the explosion limit at $25^{\circ}C$ and the temperature dependence of the explosion limits were investigated. And the AIT for acetone were experimented. By using the literatures data, the lower and upper explosion limits of acetone recommended 2.5 vol% and 13.0 vol%, respectively. In this study, the lower flash points of acetone recommended $-20^{\circ}C$. This study was determined relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for acetone, and the experimental AIT of acetone was $565^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of acetone is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• 한국안전학회지
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• 제26권2호
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• pp.36-41
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• 2011

For the safe handling of n-hexane, the explosion limit at $25^{\circ}C$, the temperature dependence of the explosion limits and the lower flash point were investigated. And AITs(auto-ignition temperatures) by ignition delay time for n-hexane were experimented. By using the literatures data, the lower and upper explosion limits of n-hexane recommended 1.0 Vol% and 8.0 Vol%, respectively. In this study, the lower flash points of n-hexane recommended $-23^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for n-hexane, and the experimental AIT of n-hexane was $240^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of n-hexane is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• 한국산업보건학회지
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• 제26권4호
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• pp.445-453
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• 2016

Objectives: The objective of this study is to assess relative safety level of the decompression tables in Ministry of Employment and Labor Public Notice No. 2014-28 in comparison with overseas decompression tables. Methods: Decompression tables in the Public Notice No. 2014-28 were compared with examples from Japan, the USA, Canada, and France in terms of ascent rate, surface intervals after exceptional exposures, oxygen decompression and allowable partial pressure, depth limits in air diving, no-decompression limits, and decompression time and methods. Results: Public Notice No. 2014-28 does not include air diving depth limits, exceptional exposure limits, mandatory surface intervals after exceptional exposures, oxygen decompression, and surface decompression schedules. Its decompression time was found to be the shortest among the five decompression tables. Conclusions: Public Notice No. 2014-28 has the lowest safety level in comparison with overseas decompression tables. Deck decompression chambers are not applicable due to no regulations on surface interval and oxygen use in the chamber for decompression.

• 한국안전학회지
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• 제16권4호
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• pp.103-108
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• 2001

Explosive limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limits are used to classify flammable liquids according to their relative flammability. Such a classification is important for the safe handling of flammable liquids which constitute the solvent mixtures. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this paper, Raoult,s law and van Laar equation(activity coefficient model) are shown to be applicable for the prediction of the explosive limits in the flammable ethylacetate-toluene system. The values calculated by the proposed equations were a good agreement with literature data within a given percent. From a given results, by the use of the proposed equations, it is possible to predict explosive limits of the other flammable mixtures. It is hoped eventually that this method will permit the estimation of the explosive Properties of flammable mixtures with improved accuracy and the broader application for other flammable stances.

• 한국안전학회지
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• 제24권5호
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• pp.28-33
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• 2009

The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosion limit, flash point, autoignition temperatures(AITs), minimum oxygen concentration(MOC), heat of combustion etc.. Also it is necessary to know explosion limit at high temperature and pressure. For the safe handling of benzene, lower explosion limit(LEL) at $25^{\circ}C$, the temperature dependence of the explosion limits and flash point were investigated. And the AITs for benzene were experimented. By using the literatures data, the lower and upper explosion limits of benzene recommended 1.3 vol% and 8.0 vol%, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for benzene, and the experimental AIT of benzene was $583^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of benzene is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• 한국안전학회지
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• 제23권3호
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• pp.36-41
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• 2008

For the safety design and operation of many chemical process, it is necessary to know certain explosion limit, flash point and autoignition temperature(AIT) of handling substances. Also it is necessary to know explosion limit at high temperature and pressure. For the safe handling of MEK(methyl ethyl ketone), explosion limit at $25^{\circ}C$ and the temperature dependence of the explosion limits were investigated. And flash point and AIT for MEK were experimented. By using the literatures data, the lower and upper explosion limits of MEK recommended 1.8 vol% and 11.0 vol%, respectively. In this study, measured the lower and upper flash points of MEK were $-5^{\circ}C$ and $22^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for MEK, and the experimental AIT of MEK was $507^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of MEK is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Nuclear Engineering and Technology
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• 제36권6호
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• pp.528-539
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• 2004

It is essential in commercial reactors that the safety limits imposed on the fuel pellets and fuel clad barriers, such as the linear power density (LPD) and the departure from nucleate boiling ratio (DNBR), are not violated during reactor operations. In order to accurately monitor the safety limits of current reactor states, a detailed three-dimensional (3D) core power distribution should be estimated from the in-core detector signals. In this paper, we propose a calculation methodology for detailed 3D core power distribution, using in-core detector signals and core monitoring constants such as the 3D Coupling Coefficients (3DCC), node power fraction, and pin-to-node factors. Also, the calculation method for several core safety parameters is introduced. The core monitoring constants for the real core state are promptly provided by the core design code and on-line MASTER (Multi-purpose Analyzer for Static and Transient Effects of Reactors), coupled with the core monitoring program. through the plant computer, core state variables, which include reactor thermal power, control rod bank position, boron concentration, inlet moderator temperature, and flow rate, are supplied as input data for MASTER. MASTER performs the core calculation based on the neutron balance equation and generates several core monitoring constants corresponding to the real core state in addition to the expected core power distribution. The accuracy of the developed method is verified through a comparison with the current CECOR method. Because in all the verification calculation cases the proposed method shows a more conservative value than the best estimated value and a less conservative one than the current CECOR and COLSS methods, it is also confirmed that this method secures a greater operating margin through the simulation of the YGN-3 Cycle-1 core from the viewpoint of the power peaking factor for the LPD and the pseudo hot pin axial power distribution for the DNBR calculation.

• 한국산업보건학회지
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• 제30권3호
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• pp.249-255
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• 2020

Objective: The purpose of this study was to provide technical information about the management of occupational exposure limits(OELs) for substances with completely revised ACGIH TLVs. Methods: The history of ACGIH TLVs for aluminum compounds, the reason for the complete revision of the related ACGIH TLV in 2008, and OELs for them in respective countries were reviewed. In addition, the results of a 2019 work environment assessment for aluminum compounds in Korea were reviewed. Results: In 1979, the ACGIH set up the TLVs for aluminum compounds considering types of compounds such as metal dust, pyro powders, welding fumes, soluble salts, alkyls, and aluminum oxide. However, in 2008 the ACGIH withdrew the TLVs for all types of aluminum and its compounds and adopted new TLVs for aluminum metal and insoluble compounds. This can cause confusion in many countries in the management of exposure to aluminum compounds because they adopt or refer to the ACGIH TLVs. Conclusion: Although Korea is setting occupational exposure limits by referring to the ACGIH's TLVs, it is necessary to sufficiently review whether it is necessary to accept the TLVs as they are if a TLV is completely changed, like took place with the revision of aluminum compounds in 2008.