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Study on Thermodynamic Properties of Sulfidization for Uranium and Rare Earth Oxides (우라늄 및 희토류(稀土流) 산화물(酸化物)의 황화반응(黃化反應)에 대한 열역학적(熱力學的) 고찰(考察))

  • Lee, Jung-Won;Lee, Jae-Won;Kang, Kweon-Ho;Park, Geun-Il
    • Resources Recycling
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    • v.21 no.1
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    • pp.66-74
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    • 2012
  • In order to evaluate the feasibility of selective sulfidization of uranium and rare-earth(RE) oxides, an analysis on thermodynamic data, such as $M-O_2-S_2$ phase stability diagram and changes of Gibbs free energy for sulfidization of uranium and rare-earth oxides were carried out. Comparing $RE-O_2-S_2$ with $U-O_2-S_2$ phase stability diagram at wide range of sulfur potential, $UO_2$ remains unreacted, while RE oxides are sulfidized. The Gibbs free energy change(${\Delta}G^{\circ}$) of sulfidization of RE oxides is lower than that of uranium oxides. Thus, the selective formation of RE sulfides is possible during sulfidization of RE and uranium oxides at lower temperature. $CS_2$ was selected as a sulfidizing agent, because it is a stronger sulfidizing agent than other agents and reacts at lower temperature.

Subcooled Burnout Heat Flux on a Heated Surface with Impinging Water Jet (충돌수분류(衝突水噴流)에 의한 서브쿨 Burnout열류속(熱流束)에 관한 연구)

  • Ohm, K.C.;Lee, J.S.;Park, S.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.527-536
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    • 1996
  • Convective nucleate boiling and burnout heat flux have been studied on a flat, downward facing, constant heat flux surface cooled by an impinging water jet. The tests are progressed from low, nonboiling power to high, burnout heat flux power. The jet velocity and the subcooling do not affect the nucleate boiling curve of $q{\sim}{\Delta}T_{sat}$ diagram, but the supplementary water height affects the curve. For the case of dimensionless height of supplementary water S/D=1, the boiling curve shift to the heigher heat flux than that of S/D=0 or S/D=2. Burnout heat flux is enhanced with increasing jet velocity and subcooling. Also. by using the supplementary water(S/D=1 or S/D=2), burnout heat flux is larger than that of the simple water jet(S/D=0). A generalized correlation for the burnout heat flux data in the present boiling system with an impinging water jet is successfully evolved.

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4-Channel 2.5-Gb/s/ch CMOS Optical Receiver Array for Active Optical HDMI Cables (액티브 광케이블용 4-채널 2.5-Gb/s/ch CMOS 광 수신기 어레이)

  • Lee, Jin-Ju;Shin, Ji-Hye;Park, Sung-Min
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.49 no.8
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    • pp.22-26
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    • 2012
  • This paper introduces a 2.5-Gb/s optical receiver implemented in a standard 1P4M 0.18um CMOS technology for the applications of active optical HDMI cables. The optical receiver consists of a differential transimpedance amplifier(TIA), a five-stage differential limiting amplifier(LA), and an output buffer. The TIA exploits the inverter input configuration with a resistive feedback for low noise and power consumption. It is cascaded by an additional differential amplifier and a DC-balanced buffer to facilitate the following LA design. The LA consists of five gain cells, an output buffer, and an offset cancellation circuit. The proposed optical receiver demonstrates $91dB{\Omega}$ transimpedance gain, 1.55 GHz bandwidth even with the large photodiode capacitance of 320 fF, 16 pA/sqrt(Hz) average noise current spectral density within the bandwidth (corresponding to the optical sensitivity of -21.6 dBm for $10^{-12}$ BER), and 40 mW power dissipation from a single 1.8-V supply. Test chips occupy the area of $1.35{\times}2.46mm^2$ including pads. The optically measured eye-diagrams confirms wide and clear eye-openings for 2.5-Gb/s operations.

Dynamic Structural Response Characteristics of Stiffened Blast Wall under Explosion Loads (폭발 하중을 받는 보강된 방폭벽의 동적 구조 응답 특성에 관한 연구)

  • Kim, Sang Jin;Sohn, Jung Min;Lee, Jong Chan;Li, Chun Bao;Seong, Dong Jin;Paik, Jeom Kee
    • Journal of the Society of Naval Architects of Korea
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    • v.51 no.5
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    • pp.380-387
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    • 2014
  • Piper Alpha disaster drew attention to the damage likely to arise from explosions and fires on an offshore platform. And great concerns have been increased to prevent these hazards. Blast wall is one of the passive safety systems; it plays a key part of minimizing the consequences. However, a buckling due to explosion loads is a factor which can reduce the strength of blast wall. The buckling often occurs between web and flange at the center of blast wall. This study aims to find a solution for reinforcing its strength by installing a flat plate at the spot where the buckling occurs. First of all, ANSYS finite element method is adopted to numerically compute the structural resistance characteristic of blast wall by using a quasi-static approach. Sequentially, the impact response characteristics of blast wall are investigated the effect on thickness of flat plate by using ANSYS/LS-DYNA. Finally, pressure-impulse diagrams (P-I diagram) are presented to permit easy assessment of structural response characteristics of stiffened blast wall. In this study, effective use is made to increase structural intensity. of blast wall and acquired important insights have been documented.

Analysis of Abnormal Sea Surface Temperature in the Coastal Waters of the Yellow Sea Using Satellite Data for the Winter Season of 2004 (인공위성자료를 이용한 2004년 겨울철 황해 연안 해역 이상 수온 해석)

  • Moon, Jeong-Eon;Yang, Chan-Su
    • Korean Journal of Remote Sensing
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    • v.25 no.1
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    • pp.1-10
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    • 2009
  • We studied on the relationship between oceanic variation in the offshore and abnormal sea surface temperature rise in the coastal area of the Yellow Sea using a variety of satellite and in-situ data during winter 2004. In results of the satellite data, the average value of sea surface temperature in the Yellow Sea for 2003 was $10^{\circ}C$, and the average value of sea surface temperature for 2004 was $13^{\circ}C$. It was higher than those of the last year about $3^{\circ}C$. In results of the in-situ data, the average value of surface layer temperature in the Yellow Sea for 2003 was $9.85^{\circ}C$, and the average value of surface layer temperature for 2004 was $12.17^{\circ}C$. In the same satellite data, it was higher than those of the last year about $3^{\circ}C$. In results of the T-S diagram, we divided definitely into water mass of the Yellow Sea and the East China Sea in 2003. But we didn't divide definitely into water mass of the Yellow Sea and the East China Sea in 2004. The average values of air temperature and wind speed for 2003 were $5.23^{\circ}C$ and 4.81 m/s, respectively. And, the average values of air temperature and wind speed for 2004 were $5.61^{\circ}C$ and 4.52 m/s, respectively. So, These were similar. But the wind directions for 2003 were superior northwestern wind, and the wind directions for 2004 were various northern wind. The wind directions were different from each other. Therefore, the abnormal sea surface temperature rise in the coastal area of the Yellow Sea during winter 2004 were better related to oceanic variation in the offshore than influences of atmosphere. In the future, We will do in-depth study for these.

Experimental and Simulation Study of Barrier Properties in Schottky Barrier Thin-Film Transistors with Cr- and Ni- Source/Drain Contacts (Cr- 및 Ni- 소스/드레인 쇼트키 박막 트랜지스터의 장벽 특성에 대한 실험 및 모델링 연구)

  • Jung, Ji-Chul;Moon, Kyoung-Sook;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.10
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    • pp.763-766
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    • 2010
  • By improving the conducting process of metal source/drain (S/D) in direct contact with the channel, schottky barrier metal-oxide-semiconductor field effect transistors (SB MOSFETs) reveal low extrinsic parasitic resistances, offer easy processing and allow for well-defined device geometries down to the smallest dimensions. In this work, we investigated the arrhenius plots of the SB MOSFETs with different S/D schottky barrier (SB) heights between simulated and experimental current-voltage characteristics. We fabricated SB MOSFETs using difference S/D metals such as Cr (${\Phi}_{Cr}$ ~4.5 eV) and Ni (${\Phi}_{Ni}$~5.2 eV), respectively. Schottky barrier height (${\Phi}_B$) of the fabricated devices were measured to be 0.25~0.31 eV (Cr-S/D device) and 0.16~0.18 eV (Ni-S/D device), respectively in the temperature range of 300 K and 475 K. The experimental results have been compared with 2-dimensional simulations, which allowed bandgap diagram analysis.

A Leverage Strategy of the US-Korea Cost Sharing Program Based on Systems Thinking (시스템 사고를 이용한 주한미군 방위비 분담 정책 레버리지 전략)

  • Lee, Jung-Hwan;Cho, Yong-Gun;Moon, Seong-Am;Seo, Hyeok
    • Korean System Dynamics Review
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    • v.11 no.3
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    • pp.33-59
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    • 2010
  • South Korea has the defense burdensharing agreement with the United States in reference to the U.S. troops stationed in Korea since 1991, based on Special Measure Agreement(SMA). Due to the growth of Korea's economic power and the U.S. provision of the security environment on Korean penninsula, the U.S. government steadily demanded the rise of contributions to common defense from South Korea and South Korea accepted most of the U.S. requests without proper principles of negotiation concerning the cost sharing. This paper analyzes the systems of the Korea-U.S. cost sharing program through a systems thinking, that yields desirable results with a little effort. The three policy leverages are: 1) the development of negotiation principles; 2) the policy making closely linked with National Defense Reform Basic Plan; 3) the policy making with responsibility burdensharing than cost burdensharing. This paper findings will contribute to the developing the Korea-U.S. cost sharing program by providing policy-makers and policy-practitioners with systematic understanding and insight into the dynamics of the program. Also, this will enable the program to execute more effectively with a concrete formula.

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A Study on Dynamic Vibration Absorber Using Zener's Model (Zener 모델을 사용한 동흡진기 특성 연구)

  • Oh, Il-Kwon;Lim, Seung-Hyun
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.159-163
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    • 2005
  • A dynamic vibration absorber using the Zener's model has been taken into account with respect to frequency response characteristics. The concept of the tuned mass damper with a single degree of freedom has been well applied for many industrial fields, because many researchers have extensively studied various basic characteristics, performance and optimization methods for long time. The Zener's model has an additional spring, which is connected between a damper and a mass, while the tuned mass damper with a single degree of freedom consists of a mass, a spring and a damper connected in parallel. In previous works, the basic performance and characteristics of the Zoner's model as a dynamic vibration absorber have not been investigated. In this study, the frequency response characteristics according to the parameter change of the Zener's model have been described. In order to find the optimum value of several parameters, we use iterative scheme with three dimensional frequency response diagram by MATLAB programming. Present results shows the Zener's model can give more good damping performance than the simple tuned mass damper, and the numerical of optimization method should be developed for the efficient vibration absorbtion.

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The Studies on Urobilinogen Determination (Urobilinogen 측정에 관한 연구)

  • 조영주
    • Journal of Environmental Health Sciences
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    • v.7 no.1
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    • pp.59-62
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    • 1981
  • We have performed 324 specimens' urobilinogen determinations(Healthy normal 219 & out-or in-patients 105) for the purposs of defining accurate & precise methods in semi-quantitative techniques. As shown on Table 1 through 5 & Fig.1 to 3, normal person's titer is concentrated in 1:40, 1:80, 1:20 & 1:10 respectively and majority of patients' titer is 160. The concentration diagram on Fig. 2 is seen for the normal person and patient's titer is nearly normal distribution scattered from 0.475mg/dl of median throughout the whole area (0.225-0.625). From Fig. 5 I have found that semi-quantitative titer is much different from the true value by electrical measurements. I am proposing of taking photoelectric quantitative methods for semiquantitative methods.

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Requirements for Improvement in Transmission Performance for an Optical Delay Interferometer based Optical Duobinary Transmitters (광 간섭계를 이용한 광 듀오바이너리 송신기의 전송 성능 향상에 관한 조건 연구)

  • Lee, Dong-Soo
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.10 no.6
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    • pp.119-123
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    • 2010
  • The transmission performance of 10Gb/s optical duobinary transmitters implemented by using a Mach-Zehnder(MZ) modulator and an optical delay interferometer is presented. We investigated the theoretical impact of transmission systems by the modulator driving voltage ratio(=driving voltage/switching voltage) and the optical interferometer time delay to improve transmission distance using computer simulation. By reducing the driving voltage ratio and optimizing the partial bit time delay, the transmission performance has been improved greatly.