• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.330-335
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• 1998

This research was conducted to evaluate the adhesion in tension of the polymer mortars for cement concrete repair. Various polymer types, binder ratios, and wet/dry conditions of the surface were considered in this study. Styrene-butadiene rubber (SBR) and ethylen vinyl acetate (EVA) used for polymer cement mortars. Epoxy resin (EP), and unsaturated polyester resin (UP) were used for polymer mertars. Adhesion in tension for the dry condition of the substrate surface was higher than that for the wet condition of the substrate surface under the same binder ratio. Therefore, in repairing concrete, the dry surface condition was effective on adhesion.

• Elastomers and Composites
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• 제47권1호
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• pp.54-64
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• 2012

본 연구에서는 polar 한 silica 와 non-polar 한 고무사이의 친화력을 증대시키기 위하여 SBR 분자 주쇄에 acrylonitrile 을 도입시킨 acrylonitirle functionalized emulsion SBR 의 물성에 관하여 연구하였다. Acrylonitrile의 nitrile group 은 silica 표면의 silanol group 과 H-bond 를 형성할 수 있음으로 polar 한 silica 표면에 흡착되는 가교촉진제를 줄이고 가황반응을 촉진시키는 것으로 판단된다. SBR 및 AN-SBR 에 PEG 를 적용한 컴파운드의 경우 PEG 와 silica 표면의 silanol group 과의 상용성이 높아 가교촉진제가 polar 한 silica 표면에 흡착됨을 줄여 가교시간이 단축된 것으로 판단된다. 기계적 물성에서 AN-SBR 컴파운드는 SBR 1721 컴파운드 대비 100%, 300%에서 높은 모듈러스 값을 나타내었다. 이러한 결과는 AN-SBR 의 높은 분자량 및 nitrile group 의 도입에 따른 가교도의 상승에 의한 결과로 판단된다. 동적점탄특성 결과에서 AN-SBR 컴파운드는 SBR 1721 컴파운드 대비 $60^{\circ}C$ 에서 낮은 tan ${\delta}$ 값을 나타내었으며, 이는 nitrile group 과 silica 사이의 친화력에 따른 filler-rubber interaction의 향상에 의해 반복변형에 의한 energy dissipation 이 낮은 것으로 판단된다.

• Elastomers and Composites
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• 제35권2호
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• pp.98-105
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• 2000

화학적 표면처리에 따른 카본블랙의 표면 관능기와 표면 자유에너지를 FT-IR과 접촉각 측정법을 이용하여 각각 관찰하였다. 산성과 염기성 용액으로 표면 처리한 카본블랙을 분석한 결과, 표면 관능기가 표면 자유에너지의 극성요소에 크게 영향을 미치는 것을 확인하였다. 반면에 무극성 용액으로 표면처리한 NCB와 염기성 용액으로 처리한 BCB의 경우 표면 자유에너지의 London 비극성 요소의 증가를 보이며 이에 따라 카본블랙/고무 복합재료의 경도, 파단신율, 그리고 인장강도와 같은 기계적 물성이 증가하는 것을 볼 수 있었다. 특히, 접촉각 측정을 통해 얻은 표면 자유에너지의 London 비극성 요소가 복합재료의 인장강도와 상관관계가 있음을 확인할 수 있었다. 이는 카본블랙의 London 비극성 요소가 카본블랙/고무 복합재료의 기본적인 기계적 물성에 크게 기여한다고 사료된다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 춘계학술대회
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• pp.223-226
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• 2005

For $CO_2-free$ hydrogen production and better utilization of the produced carbon, catalytic decomposition of methane over rubber-grade carbon blacks manufactured from coal tar was carried out. The catalytic activities of several domestic carbon blacks were compared. A pelletized carbon black exhibited considerably lower activity and activation energy than the fluffy( loose) carbon black of the same grade. This difference is considered due to the binder that was added during pelletization. For pelletized carbon blacks, a tendency was observed that the activity per unit mass of catalyst increased with the specific surface area of the carbon black. Another tendency was also observed that the activation energy increased with the primary particle size or decrease of the specific surface area.

• 소성∙가공
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• 제13권2호
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• pp.129-136
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• 2004

Recently, instead of a matched die forming method requiring a high cost and long delivery term, a multi-point dieless forming method using a pair of matrix type punch array as flexible dies has been developed. Since the conventional multi-point dieless forming method has some disadvantages of difficulty in precise punch control and high-cost of equipment, a new concept of multi-point dieless forming method combined with an elasto-forming method has been suggested in this study. For optimal selection of elastomers, compression tests of rubbers, polyethylene and foams were carried out together with FEM analysis of the deformation behavior during sheet forming process using a rigid punch and elastomers. Compressive strain was concentrated on the upper central area of the elastomer under the punch, and the rubber exhibited higher concentration of the compressive strain than foams. Two-dimensional curved surface was formed successfully by the multi-point elasto-dieless forming method using an optimal combination of rubber and foam materials.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 제4회 박판성형 심포지엄
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• pp.21-28
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• 2003

Recently, instead of a matched die forming method requiring a high cost and long deliverly ten a multi-point dieless forming method using a pair of matrix type punch array as flexible dies has been developed. As this multi-point dieless forming method has some disadvantage of difficulty in precise punch control and high-cost of equipment, a new concept of multi-point dieless forming method combined with elastomer forming was suggested in this study. For optimal selection of elastomers, compression tests of rubbers, polyethylene and foams were carried out together with FEM analysis of the deformation behavior during sheet forming process using a rigid punch and elastomers. Compressive strain was concentrated on the upper central area of the elastomer under the punch, and the rubber exhibited higher concentration of the compressive strain than foams. Two-dimensional curved surface was formed successfully by the multi-point elasto-dieless forming method using an optimal combination of a rubber and foam.

• E2M - 전기 전자와 첨단 소재
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• 제9권4호
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• pp.344-350
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• 1996

Tracking is one of the biggist problems to be overcome in polymeric materials for outdoor insulators. But It can be decreased with the addition of filler such as alumina trihydrate (ATH). In this paper, the tracking of surface and evaluation of insulating ability at silicone rubber is investigated, using the salt fog test. At initial state, the peak leakage current and numbers by dry band arcing is increasing with increasing the filler level, but at aged state decreasing at high concentration filler samples. This is because the roughness of the surface may contribute to the increase in peak leakage cur-rent and numbers. As increasing the filler level, the insulating ability of materials is higher and weight loss is decreased. The mechanism of insulating failure is occurred by the erosion than the tracking and the erosion caused weight loss of 2 g.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 E
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• pp.2364-2367
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• 1999

Polymer insulating materials are widely used in power distribution and transmission systems for their good dielectric properties, light weight, low cost, and good contamination performance. Tracking is one of the biggest problems to be overcome in polymer insulating materials. The alumina trihydrate(ATH) is widely used as a filler for improve the tracking performance of silicone rubber. In this paper, we have investigated the influence of surface treatment of fillers on the tracking performance of silicone insulator using the IEC 587 tracking test method.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.25-28
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• 1998

In this study, we investigated the electrical characteristics of silicone rubber that being used outdoor insulating material, which had been immersed in salt water. After immersed the sample in salt water, we measured surface hydrophobicity, weight loss and microscopic surface appearance, and then compared with these of the original. And we tested the electrical characteristics of the aged sample by the water under salt-fog. These electrical characteristics are described by the average of leakage current, peak pulse number, which are recorded by data acquisition system The experimental results show that the resistance against tracking and erosion is decreased significantly by water penetration.

• Elastomers and Composites
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• 제18권3호
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• pp.87-98
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• 1983

Fundamental properties and surface treatment effects of domestic kaolin calcined at higher temperature were studied to develop reinforcing fillers for rubbers. The results obtained are as follows: (i) X-ray diffraction and scanning electron microscopy studies revealed kaolinite as a major constituent of the raw kaolin used in this study. (ii) Physical properties of natural rubber vulcanizates compounded with the calcined kaolin fillers treated with poly(maleic anhydride) and sodium polyphosphate are favorably improved. Particularly, the kaolin filler treated with sodium polyphosphate(designated as PT series) shows excellent physical properties compared with hydrated silica.