• Elastomers and Composites
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• v.49 no.3
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• pp.220-224
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• 2014

The tire tread is contacted with road surface directly. It gives significant effect on the breaking conditions, traction, noise and so on. The tread having grooves with complex geometry is molded by shaping process. The flow behavior of tread rubber in a mold affects the quality of the tread and it leads to the running performance of automobile. In this study, the flow behavior of rubber in shaping process has been investigated by computer simulation. The objective of flow simulation is the design of tread shape based on the contact of rubber on the mold surface and flow behavior of rubber. Different sequences of contact of rubber on the mold surface and flow behavior of rubber are observed according to the shape of tread on the mold surface. It was verified that the shape of tread gives significant effect on the flow behavior of rubber. Different flow behaviors of rubber and sequential contact of rubber to the mold surface were observed according to the shape of tread on the mold surface. Therefore, we have identified that the shape of tread give a change in the flow behavior of rubber.

• Bulletin of the Korean Chemical Society
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• v.21 no.1
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• pp.69-74
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• 2000

Applicability of Thermal field flow fractionation (ThFFF) was investigated for the analysis of masticated natural rubber (NR) adhesives produced bya hot melt mastication process. An optimum ThFFF condition for NR analysis was found by using tetrahydrofuran (THF) as a solvent/carrier and a field-programming. Low flowrate (0.3 mL/min) was used to avoid stopping the flow for the sample relaxation. Measured molecular weight distribution was used to monitor degradation of rubber during the mastication process. Rubber samples collected at three different stages of the mastication process and were analyzed by ThFFF. It was found that in an anaerobic process rubber degradation occurs at the resin-mixing (compounding) zone as well as in the initial break-down zone, while in an aerobic process most of degradation occurs at the initial breakdown zone. It was also found that E-beam radiation on NR causes a slight increase in the NR molecular weight due to the formation of a branched structure.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.320-325
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• 2015

Flow mark is a sort of surface defect on the composite that can arise during the filling stage of the injection molding process. The purpose of this study is to clarify a mechanism of the flow mark which appears on the surface of injection molded Polypropylene (PP) through the characterization of the surface structure. The materials used in this report are PP/rubber and PP/talc compounding, which are widely used in automobile part. The flow mark shows two different constitutions, such as a luster part and a cloud part on the surface of the injection molded PP. We have investigated the surface structure of PP/rubber and PP/talc composites by using scanning electron microscope (SEM), energy dispersive x-ray spectroscopy (EDAX) and optical microscopy (OM). As a result, the cloud part contains higher contents of the rubber and talc compare to the luster part.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2006.05a
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• pp.375-376
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• 2006

Thermoplastic elastomer(TPE) can be molded by conventional injection molding. Therefore TPE injection molding could be analyzed by commercial flow analysis software. However there are a little of gaps on CAE simulation results and practical molding. In this study, the properties of TPE were measured and applied to CAE simulation for comparing the simulation flow pattern and real flow pattern. The pattern that was controlled by injection time was match. The pattern that was controlled by injection stroke and rate was not match.

• Elastomers and Composites
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• v.51 no.4
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• pp.263-268
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• 2016

In the polymer shaping process that uses molds, the quality of the molded products is determined not only by the flow of the (molten) polymer but also by the air venting in the cavity. Inadequate air venting in the cavity can cause defects in the product, such as voids, short shot, or black streaks. As it is critical to consider the location and size of the vents for proper venting of the air in the cavity, a method that predicts the flow of air and material is required. The venting of air by the flow of rubber inside the cavity was simulated by using a multi-phase computational fluid dynamics method. Through computer simulation, the interface of rubber and air over time was predicted. Then, the velocity and pressure distribution of the venting air were observed. Our research proposes a fundamental method for analyzing the multi-phase flow of polymer materials and air inside the cavity of a mold.

• Elastomers and Composites
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• v.54 no.2
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• pp.156-160
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• 2019

The changes in the dispersion of carbon black in liquid polyisoprene under shear flow with time have been investigated by time-resolved ultra small-angle X-ray scattering (USAXS) method. The analyses of USAXS profile immediately after the start of shear flow clarified that the aggregates of carbon black with a mean radius of gyration of 14 nm and surface fractal dimension of 2.5 form the fractal network structure with mass-fractal dimension of 2.9. After the application of the shear flow, the scattering intensity increases with time at the observed whole entire q region, and then the a shoulder appears at $q=0.005nm^{-1}$, indicating that the agglomerate is broken and becomes smaller by shear flow. The analysis by the Unified Guinier/Power-law approach yielded several characteristic parameters, such as the sizes of aggregate and agglomerate, mass-fractal dimension of agglomerate, and surface fractal dimension of the primary particle. While the mean radius of gyration of the agglomerate decreases with time, the mean radius of gyration of the aggregate, mass fractal dimension, and surface fractal dimension don't change with time, indicating that the aggregates peel off the surface of the agglomerate.

• Journal of the Semiconductor & Display Technology
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• v.12 no.2
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• pp.79-84
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• 2013

Nanoimprint lithography (NIL) is the next generation photolithography process in which the photoresist is dispensed onto the substrate in its liquid form and then imprinted and cured into a desired pattern instead of using traditional optical system. There have been considerable attentions on NIL due to its potential abilities that enable cost-effective and high-throughput nanofabrication to the display device and semiconductor industry. Although one of the current major research trends of NIL is large-area patterning, the technical difficulties to keep the uniformity of the residual layer become severer as the imprinting area increases more and more. In this paper, with the rolling type imprinting process, a mold, placed upon the $2^{nd}$ generation TFT-LCD glass sized substrate($370{\times}470mm^2$), is rolled by a rubber roller to achieve a uniform residual layer. The prediction of residual layer thickness of the photoresist by rolling of the rubber roller is crucial to design the rolling type imprinting process, determine the rubber roller operation conditions-mpressing force & feeding speed, operate smoothly the following etching process, and so forth. First, using the elasticity theory of contact problem and the empirical equation of rubber hardness, the contact length between rubber roller and mold is calculated with consideration of the shape and hardness of rubber roller and the pressing force to rubber roller. Next, using the squeeze flow theory to photoresist flow, the residual layer thickness of the photoresist is calculated with information of the viscosity and initial layer thickness of photoresist, the shape of mold pattern, feeding speed of rubber roller, and the contact length between rubber roller and mold previously calculated. Last, the effects of rubber roller operation conditions, impressing force & feeding speed, on the residual layer thickness are analyzed with consideration of the shape and hardness of rubber roller.

• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.490-498
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• 2010

The optimum mold design and the optimum process condition were constructed upon executing process simulation of rubber injection molding with the commercial CAE program of MOLDFLOW(Ver. 5.2) in order to solve the process-problems of K company relating to air-traps and short-shots. The former occurs at the cavity edge of torque-rod-bush and the latter takes place for the injection molding of dynamic dampers. As a result the process problem relating to air traps was solved by optimizing edge-angle and the number of gates to prevent the flow congestion of flow-front and to make the flow-front movement unaffected by congestion. For dynamic dampers of K company the unmolded flaw caused by their unfilled cavity was corrected by installing the air-vent at the confronting locations of both upstream and downstream of flow-front where air traps frequently occur. Besides the unmolded flaws were rectified by altering the position of gate from the upper to the middle or by increasing the number of gates. Thus the process problems of K company relating to air-traps and short-shots of torque-rod-bush and dynamic dampers, respectively, were solved by proper altering of mold design with process simulation of rubber injection molding.

• Elastomers and Composites
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• v.49 no.4
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• pp.275-283
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• 2014

Butyl rubber is used as an adhesive and it is mainly used in the form of sheets. The goal of this study is to design an extrusion die for the butyl rubber sheets using computer simulation. The extrusion die for the butylrubber sheets consists of manifold area and land area. In the manifold area, flows are spread from the entrance of the extrusion die to the land area. In the land area, flows become stable to the flow direction and uniform sheet can be obtained. Island area is being installed in the land area to get uniform flow. Four parameters, angle of manifold, length of manifold, length of land and island, were examined in the computer simulation. The optimum geometry of the extrusion die is derived which has a uniform flow in the width direction of the die.

• Elastomers and Composites
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• v.51 no.4
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• pp.280-285
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• 2016

The purpose of this study is to get optimum design and operation conditions of the heating rubber roller for laminating process. The cause of performance degradation of heating rubber roller is delamination of rubber on metal tube, rubber aging due to high temperature. We measured the material properties of thermal expansion, thermal conductivity, specific heat and density and analyzed thermal distributions of rubber layer using finite element method. As a result of heat/flow analysis, the density distribution of heating coil must shorten the stabilization time by reducing the temperature deviation on the length direction at the temperature rising section after increasing the density of the area contacting with the laminate film at the center part which is an opposite of the current composition while enabling to maintain the temperature of heater to be consistent while maintaining the temperature deviation to be low when heat loss is created. Finally, we determined optimum heating method of heating rubber roller.