• Title/Summary/Keyword: role of additives

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Solidification/Stabilization of Arsenic Contaminated Soil Using Cement-Based Synthesized Materials (시멘트계 합성물질을 이용한 비소 오염 토양의 고형화/안정화)

  • Kim, Ran;YHong, Seong Hyeok;Jung, Bahng Mi;Chae, Hee Hun;Park, Joo Yang
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.2
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    • pp.59-65
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    • 2012
  • Solidification/Stabilization(S/S) is one of the remediation technologies that have been applied for treating inorganic hazardous wastes. This study investigated the reduction of arsenic concentration of arsenic-contaminated soil using by S/S. The binder plays a role in controlling the mobility and solubility of the contaminants in S/S process, so it is important to determine the optimum binder content. Therefore, this study evaluated the effectiveness of S/S using four different binders(cement, zero valent iron, and monosulfate and ettringite(cement-based synthesized materials) at the binder content ranged between 5%(wt.) and 20%(wt.). The leachability of arsenic in 1 N HCl was different depending on the types of binders: cement(71.41%) > monosulfate(47.45%) > ettringite(46.36%) > ZVI(33.08%) at the binder content of 20%. Additionally, three kinds of a mixture binder were prepared using cement and additives(monosulfate, ettringite, calcium sulfoaluminate(CSA)) and tested for arsenic reduction. The highest arsenic removal capacity was found at the mass ratio of cement to the additive, 4:1 in all experiments using a mixture binder, regardless of the additives types. A mixture binder(cement and additives) resulted in higher arsenic removal relative to the arsenic removal when cement was used alone.

The Anticancer Role of Capsaicin in Experimentally-induced Lung Carcinogenesis

  • Anandakumar, Pandi;Kamaraj, Sattu;Jagan, Sundaram;Ramakrishnan, Gopalakrishnan;Asokkumar, Selvamani;Naveenkumar, Chandrashekar;Raghunandhakumar, Subramanian;Vanitha, Manickam Kalappan;Devaki, Thiruvengadam
    • Journal of Pharmacopuncture
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    • v.18 no.2
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    • pp.19-25
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    • 2015
  • Objectives: Capsaicin (CAP) is the chief pungent principle found in the hot red peppers and the chili peppers that have long been used as spices, food additives and drugs. This study investigated the anticancer potential of CAP through its ability to modify extracellular matrix components and proteases during mice lung carcinogenesis. Methods: Swiss albino mice were treated with benzo(a) pyrene (50 mg/kg body weight dissolved in olive oil) orally twice a week for four successive weeks to induce lung cancer at the end of $14^{th}$ week. CAP was administrated (10 mg/kg body weight dissolved in olive oil) intraperitoneally. Extracellular matrix components were assayed; Masson's trichome staining of lung tissues was performed. Western blot analyses of matrix metalloproteases 2 and 9 were also carried out. Results: In comparison with the control animals, animals in which benzo(a)pyrene had induced lung cancer showed significant increases in extracellular matrix components such as collagen (hydroxy proline), elastin, uronic acid and hexosamine and in glycosaminoglycans such as hyaluronate, chondroitin sulfate, keratan sulfate and dermatan sulfate. The above alterations in extracellular matrix components were effectively counteracted in benzo(a)pyrene along with CAP supplemented animals when compared to benzo(a) pyrene alone supplemented animals. The results of Masson's trichome staining for collagen and of, immunoblotting analyses of matrix metalloproteases 2 and 9 further supported the biochemical findings. Conclusion: The apparent potential of CAP in modulating extracellular matrix components and proteases suggests that CAP plays a chemomodulatory and anti-cancer role working against experimentally induced lung carcinogenesis.

Role of Household Exposure, Dietary Habits and Glutathione S-Transferases M1, T1 Polymorphisms in Susceptibility to Lung Cancer among Women in Mizoram India

  • Phukan, Rup Kumar;Saikia, Bhaskar Jyoti;Borah, Prasanta Kumar;Zomawia, Eric;Sekhon, Gaganpreet Singh;Mahanta, Jagadish
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.7
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    • pp.3253-3260
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    • 2014
  • Background: A case-control study was conducted to evaluate the effect of household exposure, dietary habits, smoking and Glutathione S-Transferases M1, T1 polymorphisms on lung cancer among women in Mizoram, India. Materials and Methods: We selected 230 newly diagnosed primary lung cases and 460 controls from women in Mizoram. Multivariate logistic regression analysis was performed to estimate adjusted odds ratio (OR). Results: Exposure of cooking oil fumes (p<0.003), wood as heating source for cooking (p=0.004), kitchen inside living room (p=0.001), improper ventilated house (p=0.003), roasting of soda in kitchen (p=0.001), current smokers of tobacco (p=0.043), intake of smoked fish (p=0.006), smoked meat (p=0.001), Soda (p<0.001) and GSTM1 null genotype (p=0.003) were significantly associated with increased risk of lung cancer among women in Mizoram. Significantly protective effect was observed for intake of bamboo shoots (p=<0.001) and egg (p<0.001). A clear increase in dose response gradient was observed for total cooking dish years. Risk for lung cancer tends to increase with collegial effect of indoor environmental sources (p=0.022). Significant correlation was also observed for interaction of GST polymorphisms with some of dietary habits. Conclusions: We confirmed the important role of exposure of cooking oil emission and wood smoke, intake of smoked meat, smoked fish and soda (an alkali preparation used as food additives in Mizoram) and tobacco consumption for increase risk of lung cancer among Women in Mizoram.

Trends and Prospects of Microalgae used for Food (식품에 이용되는 미세조류와 이를 이용한 식품 연구개발 동향 및 전망)

  • Kwak, Ho Seok;Kim, Ji Soo;Lee, Ja Hyun;Sung, Dong Eun
    • Journal of the Korean Society of Food Culture
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    • v.36 no.1
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    • pp.66-75
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    • 2021
  • Microalgae are unicellular microorganisms inhabiting various ecosystems of the world, including marine and freshwater systems and extreme environments. Only a few species have been actively used as food. Microalgae are attracting attention as a means of biological CO2 reduction because they play an important role in absorbing atmospheric CO2 through their rapid growth by photosynthesis in water. Besides, microalgae are considered to be an eco-friendly energy source because they can rapidly produce biomass containing a large quantum of lipids that can be converted into biodiesel. Several microalgae, such as Chlorella spp., Spirulina spp. and Haematococcus spp. have already been commercialized as functional health supplements because they contain diverse nutrients including proteins, vitamins, minerals, and functional substances such as docosahexaenoic acid (DHA), β-glucan, phycocyanin, astaxanthin, etc. Moreover, they have the potential to be used as food materials that can address the protein-energy malnutrition (PEM) which may occur in the future due to population growth. They can be added to various foods in the form of powder or liquid extract for enhancing the quality characteristics of the foods. In this review, we analyzed several microalgae which can be used as food additives and summarized their characteristics and functions that suggest the possibility of a role for microalgae as future food.

Application of Mechanochemical Processing for Preparation of Si3N4-based Powder Mixtures

  • Sopicka-Lizer, Malgorzata;Pawlik, Tomasz
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.337-341
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    • 2012
  • Mechanochemical processing (MCP) involves several high-energy collisions of powder particles with the milling media and results in the increased reactivity/sinterability of powder. The present paper shows results of mechanochemical processing (MCP) of silicon nitride powder mixture with the relevant sintering additives. The effects of MCP were studied by structural changes of powder particles themselves as well as by the resulting sintering/densification ability. It has been found that MCP significantly enhances reactivity and sinterability of the resultant material: silicon nitride ceramics could be pressureless sintered at $1500^{\circ}C$. Nevertheless, a degree of a silicon nitride crystal lattice and powder particle destruction (amorphization) as detected by XRD studies, is limited by the specific threshold. If that value is crossed then particle's surface damage effects are prevailing thus severe evaporation overdominates mass transport at elevated temperature. It is discussed that the cross-solid interaction between particles of various chemical composition, triggered by many different factors during mechanochemical processing, including a short-range diffusion in silicon nitride particles after collisions with other types of particles plays more important role in enhanced reactivity of tested compositions than amorphization of the crystal lattice itself. Controlled deagglomeration of $Si_3N_4$ particles during the course of high-energy milling was also considered.

Study of Cam and Follower Contacts with the Mixed Concepts of EHL and Boundary Lubrication (EHL과 경계 윤활의 혼합 개념에 의한 캠과 종동물의 접촉 현상에 대한 연구)

  • 장시열
    • Tribology and Lubricants
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    • v.15 no.4
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    • pp.343-353
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    • 1999
  • The role of viscosity index improver's(Ⅶ) additives for modem engine lubrication is complex. Under the condition of atmosphere or low shear rate, the characteristics of Ⅶ added lubricant is verified and quoted frequently for mathematical model of lubricant behavior. However, recent research shows that added lubricant has the characteristics of shear thinning at high shear rate condition although it performs well enough over the whole range of working temperature. At high shear rate, they show significant decrease of apparent viscosity irrespective of temperature. Many experimental researches verify that Ⅶ added lubricant shows boundary film layer formation on the solid surface as well as shear thinning effect by its polymeric molecular characteristics. The intend of our research is to verify the effects of Ⅶ from the viewpoint of continuum mechanics, because conventional Reynolds'equation with only pressure-viscosity relation cannot fully predict the lubricant behavior under the Ⅶ added condition. In these aspects, Reynolds'equation of Newtonian fluid model lacks the reflection of real fluid behavior and there is no way to explain the non-linear characteristics of Ⅶ added lubricant. In this research, we mathematically modeled the Ⅶ added lubricant behaviors which are the characteristics of non-Newtonian fluid behavior at high shear rate and boundary film formation on the solid surface. The consideration of elastic deformation in the contact region is also included in our computation and finally the converged film pressure and the film thickness with elastic deformation are obtained. The results are compared with those of Newtonian fluid model.

The Observation of Nucleation & Growth during Water Vapor Induced Phase Inversion of Chlorinated Poly(vinyl chloride) Solution using SALS

  • Jang, Jae Young;Lee, Young Moo;Kang, Jong Seok
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.61-69
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    • 2004
  • Small angle light scattering (SALS) and field emission scanning electron microscope (FE-SEM) have been used to investigate the effects of alcohol on phase separation of chlorinated poly(vinyl chloride) (CPVC)/tetrahydrofuran (THF)/alcohol (9/61/30 wt%) solution during water vapor induced phase separation. A typical scattering pattern of nucleation & growth (NG) was observed for all casting solutions of CPVC/THF/alcohol. In the case of the phase separation of CPVC dope solution containing 30 wt% ethanol or n-propanol, the demixing with NG was observed to be heterogeneous. Meanwhile, the phase separation of CPVC dope solution with 30 wt% n-butanol was found to be predominantly homogeneous NG. Although the different phase separation behavior of NG was observed with types of alcohol additives, the resultant surface morphology had no remarkable differences. That is, even though the NG process by water vapor is either homogeneous or heterogeneous, this difference does not play a main role on the final surface morphology. However, it was estimated from the result of hydraulic flux that the phase separation by homogeneous NG provided the membrane geometry with lower resistance in comparison with that by heterogeneous one.

A Quantitative Analysis on Feature of Hydrate Affecting Early-Age Strength (콘크리트 초기강도에 영향을 미치는 수화물의 정량분석에 관한 연구)

  • Song Tae Hyeob;Lee Mun Hwan;Lee Sea Hyun;Park Dong Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.583-586
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    • 2005
  • Strength of concrete is very important factor in design and quality management and may represent overall quality of concrete. Such strength of concrete may differ depending on amount of cement mixed, water and fine aggregate ratio. Classic concrete products have been produced mainly with ordinary portland cement(hereinafter 'cement'), water and fine aggregate as shown above, but various additives and mixture materials have been used for concrete manufacturing, along with development of high functional concrete and diversification of structures. Various kinds of chemical mixtures agents and mixture materials have been used as it requires concretes with other features which cannot be solved with existing materials only, such as high strength, high flexibility and no-separation in the water. Such addition of various mixture agents may cause change in cement hydrate, affecting strength. Hydration of cement is the process of producing potassium hydroxide, C-S-H, C-A-H and Ettringite, while causing heat generation reaction after it is mixed with water, and generation amounts of such hydrates play lots of roles in condensation and hardening. This study aims to analyze its strength and features with hydrates by making specimen according to curing temperature, types of mixture agent, mixing ratio and ages and by analyzing such hydrates in order to analyze role of cement hydrate on early strength of concrete.

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Role of Charges of the Surface-grafted Polymer Chains for Aqueous Lubrication at a Nonpolar Interface

  • Ron, Troels;Madsen, Jan Busk;Nikorgeorgos, Nikolaos;Lee, Seunghwan
    • Tribology and Lubricants
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    • v.30 no.5
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    • pp.247-255
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    • 2014
  • Charged polymer chains, i.e., polyelectrolytes, are known to show superior aqueous lubricating properties compared to those of neutral polymer chains, especially in brush conformation. This is primarily because of the incorporation of a large amount of counterions within the polymer layers and the consequently increased osmotic pressure. However, this effect is active only when the polymer chains remain immobilized even under tribostress, which is not realistic for high-contact pressure tribological applications, especially when they are irreversibly immobilized on tribopair surfaces. In contrast, with free polymers, which can be included as surface-active additives in the base lubricant (water), long-term lubricating performance based on "self-healing" properties is readily expected. In order to assess whether the superior aqueous lubricating properties of polyelectrolyte chains are valid for free polymers too, this study reviews recent studies on the tribological properties of many charged biopolymer and synthetic copolymers at a nonpolar, hydrophobic interface. In contrast to the irreversibly immobilized polyelectrolyte chains, free polyelectrolyte chains show inferior aqueous lubricating properties compared to their neutral counterparts owing to charge accumulation and the consequently impeded surface adsorption on the nonpolar surface. Nevertheless, bovine submaxillary mucin (BSM), a representative biopolymer, shows a sufficiently effective surface adsorption and aqueous lubricating capabilities even at neutral pH without losing the polyanionic characteristics.

Strategies for reducing noxious gas emissions in pig production: a comprehensive review on the role of feed additives

  • Md Mortuza Hossain;Sung Bo Cho;In Ho Kim
    • Journal of Animal Science and Technology
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    • v.66 no.2
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    • pp.237-250
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    • 2024
  • The emission of noxious gases is a significant problem in pig production, as it can lead to poor production, welfare concerns, and environmental pollution. The noxious gases are the gasses emitted from the pig manure that contribute to air pollution. The increased concentration of various harmful gasses can pose health risks to both animals and humans. The major gases produced in the pig farm include methane, hydrogen sulfide, carbon dioxide, ammonia, sulfur dioxide and volatile fatty acids, which are mainly derived from the fermentation of undigested or poorly digested nutrients. Nowadays research has focused on more holistic approaches to obtain a healthy farm environment that helps animal production. The use of probiotics, prebiotics, dietary enzymes, and medicinal plants in animal diets has been explored as a means of reducing harmful gas emissions. This review paper focuses on the harmful gas emissions from pig farm, the mechanisms of gas production, and strategies for reducing these emissions. Additionally, various methods for reducing gas in pigs, including probiotic interventions; prebiotic interventions, dietary enzymes supplementation, and use of medicinal plants and organic acids are discussed. Overall, this paper provides a comprehensive review of the current state of knowledge on reducing noxious gas in pigs and offers valuable insights for pig producers, nutritionists, and researchers working in this area.