• Journal of the Korean Chemical Society
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• v.48 no.3
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• pp.261-265
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• 2004

We investigated the order of local movement of functional groups (-C(=O)O) in a liquid crystalline (LC) oligomer (12-4) using 2D Raman correlation spectroscopy. The results suggest that the free carbonyl near the ethyl terminal group moved first, followed by the hydrogen-bonded group. The free carbonyl group between the biphenyl groups rarely moved. Interestingly, 2D sample-to-sample correlation spectroscopy (2D STSCS) revealed that some of the carbonyl modes started to move at far below (50$^{\circ}C$) the LC temperature (135$^{\circ}C$), countering conventional beliefs.

• Journal of Drive and Control
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• v.14 no.4
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• pp.45-50
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• 2017

The gas spring is a hydropneumatic adjusting element, consisting of a pressure tube, a piston rod, a piston and a connection fitting. The gas spring is filled with compressed nitrogen within the cylinder. The filling pressure acts on both sides of the piston and because of area difference it produces an extension force. Therefore, a gas spring is similar in function compare to mechanical coil spring. Conversely, optimization is a process of finding the best set of parameters to reach a goal while not violating certain constraints. The AMESim software provides NLPQL (Nonlinear Programming by Quadratic Lagrangian) and GA (genetic algorithm) for optimization. The NLPQL method builds a quadratic approximation to the Lagrange function and linear approximations to all output constraints at each iteration, starting with the identity matrix for the Hessian of the Lagrangian, and gradually updating it using the BFGS method. On each iteration, a quadratic programming problem is solved to find an improved design until the final convergence to the optimum design. In this study, we conducted optimization design of the gas spring reaction force with NLPQL.

• Proceedings of the Korean Society of Applied Pharmacology
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• 1995.10a
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• pp.107-113
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• 1995

Basement membrane laminin is a multidomain glycoprotein that interacts with itself, heparin and cells. The distal long arm plays major cell and heparin interactive roles. The long arm consists of three subunits (A, B1, B2) joined in a coiled-coil rod attached to a terminal A chain globule (G). The globule is in turn subdivided into five subdomains (Gl-5). In order to analyze the functions of this region, recombinant G domains (rG, rAiG, rG5, rGΔ2980-3028) were expressed in Sf9 insect cells using a baculovirus expression vector. A hybrid molecule (B-rAiG), consisting of recombinant A chain(rAiG) and the authentic B chains (E8-B)was assembled in vitro. The intercalation of rAiG into E8-B chains suppressed a heparin binding activity identified in subdomain Gl-2. By the peptide napping and ligand blotting, the relative affinity of each subeomain to heparin was assigned as Gl> G2= G4> G5> G3, such that G1 bound strongly and G3 not at all. The active heparin binding site of G domain in intact laminin appears to be located in G4 and proximal G5. Cell binding was examined using fibrosarcoma Cells. Cells adhered to E8, B-rAiG, rAiG and rG, did not bind on denatured substrates, poorly bound to the mixture of E8-B and rG. Anti-${\alpha}$6 and anti-${\beta}$1 integrin subunit separately blocked cell adhesion on E8 and B-rAiG, but not on rAiG. Heparin inhibited cell adhesion on rAiG, partially on B-rAiG, and not on E8. In conclusion, 1) There are active and cryptic cell and heparin binding activities in G domain. 2) Triple-helix assembly inactivates cell and heparin binding activities and restores u6131 dependent cell binding activities.

• Proceedings of the KIEE Conference
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• 1995.07b
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• pp.761-765
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• 1995

The old Timing Controller for Control Element Drive Mechanism (CEDM) is designed as an open loop control system because it is difficult to mount sensors within the Control Element Drive Mechanism(CEDM) which is operating under the pressure boundary of the reactor vessel. In this work new method which can be used to detect the CEDM operational conditions without mounting sensors within the CEDM housing is developed in order to resolve problems of the old Timing Controller. By using the developed new method, the new Timing Controller for the CEDM is designed as a closed loop controller which has features of the control rod drop prevention, fine position control and the coil life time extension. The algorithm developed under closed loop control concept resolves most problems occurred in the old Timing Controller and improves the performance and reliability of the system. During designing and testing of the Timing Controller algorithm, the real time CEDM simulator developed here was used. And all functions of the developed algorithm were verified using CEDM simulator with the real data collected from the site. The results show that the Timing Controller performs its intended functions properly.