• Title/Summary/Keyword: rheometry

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Texture of Cooked Rice and Molecular Weight Distribution of Rice Amylose (밥의 텍스쳐와 쌀 아밀로오스의 분자량 분포에 관한 연구)

  • Rho, Eun-Sook;Ahn, Seung-Yo
    • Korean Journal of Food Science and Technology
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    • v.21 no.4
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    • pp.486-491
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    • 1989
  • The textural properties of cooked rice and the molecular weight distribution of amyloses of three rice cultivars different in cooking quality were investigated by the method involving rheometry and gel chromatography he tested rice cultivals were Chunmabyeo (short grain), Yongmunbyeo (medium grain) and Mahatma (long grain) The cooked rice prepared with Mahatma was higher in hardness and lower in adhesiveness than those prepared with the other two cultivars. The molecular wright distribution of amylose from Mahatma was found to be higher than those from the other cultivars.

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Simultaneous measurements of red blood cell aggregation and blood viscosity in a slit rheometry with light transmission analysis (광 투사법을 이용한 슬릿 점도계에서의 적혈구 응집성 및 점도 측정에 관한 연구)

  • Park, Myung-Su;Ku, Yun-Hee;Shin, Se-Hyun;Suh, Jang-Su
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1678-1681
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    • 2004
  • The light-transmission technique has been applied to a slit rheometer for measuring red blood cell aggregation as well as blood viscosity over a range of shear rates. For measurement of blood viscosity and aggregation, instantaneous pressure and transmit-light intensity are measured with time. Using a precision pressure measurement, one can determine the shear stress and shear rate. In addition, a transmitted light through a blood sample indicates degree of RBC aggregation. With abruptly flowing with high shear rate, RBCs rapidly disaggregate and the intensity of the transmitted light becomes low. When continuously flowing with decreasing shear rate, RBCs tend to re-aggregate and the corresponding transmit-intensity gradually increases with time. The light intensity as a degree of RBC aggregation is plotted against shear rate and compared with blood viscosity. The advantages of this design are dual measurement at a time, simplicity, i.e., ease of operation and no moving parts, low cost, short operating time, and the disposable kit which is contacted with blood sample.

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Oxidative Gelation of Dopamine-modified Polyaspartamides by NaIO4 (NaIO4를 사용한 도파민-수식 폴리아스팔트아미드의 산화적 젤화)

  • Jeon, Young Sil;Bui, Quang Tri;An, Jung Hyun;Chung, Dong June;Kim, Ji-Heung
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.108-112
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    • 2014
  • Novel adhesive polyaspartamides containing catechol and primary amine pendent groups were synthesized through successive ring-opening aminolysis reactions of dopamine (DOP) and ethylenediamine (EDA) with polysuccinimide (PSI). The oxidative gelation of aqueous dopamine-modified polyaspartamide was observed by adding $NaIO_4$ as the oxidizing reagent. FTIR, UV-vis and oscillatory rheometry was used to elucidate the oxidative cross-linking toward gel formation. The prepared gel was characterized by the swelling degree, thermogravimetric analysis (TGA), and by scanning electronic microscopy (SEM).

Rheological properties of some thermotropic liquid crystalline polymers

  • Fan, Yurun;Dai, Shaocong;Tanner, Roger I.
    • Korea-Australia Rheology Journal
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    • v.15 no.3
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    • pp.109-115
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    • 2003
  • Rheometry testing and the DSC measurement of five thermotropic liquid crystalline polymers (TLCP) have been carried out. The dynamic viscosities of the five TLCPs show a typical shear-thinning behaviour obeying the power-law with the power indices from 0.2 to 0.3. When these TLCPs are heated above the melting temperatures determined by the DSC measurements, the dynamic viscosities first rapidly decrease by 2~3 orders of magnitude then level off, finally increase gradually with the further increasing of temperature. The steady shearing exhibited the same behaviour as the dynamic shearing, but serious edge fracture of material slippage out of the plates occurred. The abnormal temperature dependence of the viscosities can be explained by the nematic-isotropic transition. By using the concept of activation energy, we propose a simple model which can fit the shear-thinning behaviour quite well and predict qualitatively correct temperature effects.

Effect of Cellulose Concentration of Cellulose/[AMIM]Cl Solution on the Liquid Crystalline Spinning

  • Kim, Su-Jin;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.51-51
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    • 2012
  • Cellulose is extremely difficult to dissolve cellulose in water and most common organic solvents due to their stiff molecular structure, close chain packing and intermolecular hydrogen bonds. Recently, cellulose solutions using ionic liquids (ILs) as a green solvent have been known to form cholesteric liquid crystalline phase at high cellulose concentration. In this study, the phase transition and rheological behaviors of concentrated cellulose/[AMIM]Cl solution were investigated using polarized optical microscopy and rheometry. Studies were conducted to characterize the influence of cellulose concentration on the phase transition of the cellulose solution and the mechanical properties of the regenerated fibers spun from the anisotropic cellulose/[AMIM]Cl solutions.

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Migration of Nanoclay in Immiscible Polymer Blends

  • Kim, Yong-Kyoung;Ahn, Kyung-Hyun;Lee, Seung-Jong;Hong, Joung-Sook
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.366-366
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    • 2006
  • Five sandwiched multilayers consisting of PBT(Polybutyleneterephthalate), PS(Polystyrene) and clay were prepared to investigate the migration mechanism of clay in the polymer blend system. Rheometry (RMS800) was used to apply well-defined shear on the above multilayer samples in order to well understand dominant factors controlling the migration. Applied shear force was enough to move clay tactoids to the interface, if either long time or high shear was available, but it was not sufficient to separate into individual platelets of clay. The morphology evolution was subsequently studied in term of scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HR-TEM), respectively.

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Effect of added ionomer on morphology and properties of PP/clay nanocomposites

  • Liu, Hongzhi;Lim, Hyoung-Taek;Kim, Yong-Kyoung;Han, Nam-Kun;Ahn, Kyung-Hyun;Lee, Seoung-Jong
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.367-367
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    • 2006
  • With poly (ethylene-co-methacrylic acid) ionomer (i.e. Surlyn) as a compatibilizer, PP/organoclay (Cloisite(R)20A) nanocomposites were prepared via melt compounding in a co-rotating twin-screw extruder. For comparison, the widely used PP-g-MA was also used as a reference. The content of organoclay was fixed at 5phr based on the total weight of polymer resins. The structures of nanocomposites were characterized by XRD, rheometry in small amplitude oscillatory shear, SEM, and TEM, respectively. It was found that PP/Surlyn/OMMT nanocomposites displayed higher intercalation degree and better dispersion effect than the corresponding PP/PP-g-MA/OMMT counterpart. Additionally, their mechanical properties and wettability were measured.

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Effect of Metallocene-catalyzed Polyethylene on the Rheological and Mechanical Properties of Poly(phenylene sulfide)/Polyethylene Blends

  • Lee, Bo-Sun;Chun, Byoung-Chul;Chung, Yong-Chan
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.145-150
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    • 2004
  • Blends of poly(phenylene sulfide) (PPS) and polyethylene, either linear low density polyethylene (LLDPE) or metallocene-catalyzed polyethylene (MPE), that were prepared by melt blending, were investigated. From the rheological properties as determined by capillary rheometry, the melt viscosity of both PPS/LLDPE and PPS/MPE blends was low when PE was in dispersed phase, but high melt viscosity was observed for both blends with PPS in dispersed phase. Significant differences depending on the composition were found in the mechanical properties such as percent elongation at break and notched Izod impact strength. In addition, dispersed phase morphology of the blends was analyzed by a scanning electron microscope (SEM), together with brief discussion about the difference between them.