• The Korean Journal of Rheology
• /
• v.3 no.2
• /
• pp.156-165
• /
• 1991

폴리비닐리덴플루오라이드 바이모프 외팔보(poly(vinylidene fluoride) bimorph cantilever beam)의 진동을 기술하는 수학적 모형을 세우고 실험으로 그모형의 타당성을 고 찰하였다. 여러 전압의 교류전류에 대해 여러 길이의 외팔보의 주파수응답을 측정하였고 여 러 전압의 직류전류에 대해 여러 길이의 외팔보의 처짐을 측정하였다. 실험으로부터 이 외 팔보의 진동은 점성감쇠보다는 구조감쇠로 기술하는 것이 더 타덩하고 외팔보가 전기장에 대해 damping factor가 일정해야 하나 각각의 normal mode에 대해 다른 damping factor로 수정하여 계산한이론치가 실험과 더 일치하였다. 공명주파수의 공명진폭을 예측할수 있고 넓은 입력주파수 영역에 대한 외팔보의 응답을 기술 할수 있으며 진동하는 외팔보는 모든위 치에서의 진폭을 기술할수 있다는 점에서 여기서의 모형은 Toda와 Smits의 모형들보다 우 수하다고 볼수 있다.

• The Korean Journal of Rheology
• /
• v.7 no.2
• /
• pp.139-149
• /
• 1995

실제 복합재료 제조공정에 널리 이용되는 등방성 탄소섬유직조와 에폭시수지에 대 해서 수지의 유동을 일방향으로 근사하여 비정상상태 투과계수와 모세관압을 측정하는 실험 을 수행하였고 적층된 섬유직조의 기공율, 금형 주입압력 그리고 섬유직조의 적층수에 따른 수지유동특성을 분석하였다. 또한 금형 충전과정에 대한 유동가시화 실험을 수행하여 유동 선단과 충전시간을 측정하였다. 전체 조업압력에 미치는 모세관압의 영향을 규명하기 위해 일정 유입압력에 따른 금형충전과정에 대하여 유한요소/관할부피 방법을 이용한 수치모사를 수행하였다. 함침공정의 수지유동에서 비정상상태 투과계수는 섬유직조의 기공율에 따라 급 격히 증가하였고 에폭시수의 표면장력에 기인한 모세관압은 기공율 감소에 따라 급격히 증 가하였다. 동일한 기공율에서 섬유직조의 적층수가 증가함에 따라 투과계수와 모세관압은 모두 증가하는 경향을 보였다. 또한실험에서 측정한 모세관압을 고려하여 유동선단과 금형 충전시간을 수치모사방법으로 예측ㄷ한 결과는 유동가시화 실험에의한 결과와 잘 일치함을 보였다. 이결과로부터 낮은 압력에서 조업하는 RTM공정에서 모세관압효과는 유동선단과 금형 충전시간을 예측하는데 기여함을 알수 있다.

• The Korean Journal of Rheology
• /
• v.7 no.3
• /
• pp.203-210
• /
• 1995

전기장 하에서 폴리아닐린/미네랄 오일 현탁액의 유변학적 특성에 관한 실험적인 연 구를 큐엣 셀 형태의 레오미터를 사용하여수행하였다. 폴리아닐린 현탁액은 전기장을 가해 줄 때 점도가 크게 상승하는 현상을 보였고 부피분율과 전기장의 3/2승에 비례하는 동적 항 복응력을 나타내었다. 작은 변형 진폭의 동적 상태 실험을 통하여 저장계수와 손실계수를 변형진폭, 변형의 구동 주파수 및 전기장의 함수로 나타내었다. 저장계수는 전기장을 증가시 킬 때 증가하나 손실계수(5wt%)는 약한 전기장 의존성을 보였다. 낮은 응력을 가해줄때의 크립과 회복곡선은 초기의 순간적인 변형 증가와 지연되는 변형 그리고 회복 불가능한 영구 적 변형으로 구성되어진다. 탄성 한계 항복응력은 전기장의 세기가 증가함에 따라 증가하였 다. 매우 작은 변형에서는 응력과 변형사이의 선형적 관계를 보여 고체와 유사한 거동을 나 타내었다.

• Korea-Australia Rheology Journal
• /
• v.21 no.3
• /
• pp.149-153
• /
• 2009

Profile development of the melt spinning process of poly(ethylene terephthalate) (PET) was simulated by a numerical method under the consideration of two constitutive equations of Newtonian and upper convected Maxwell (UCM) models. The viscoelastic characteristics of the polymer were considered via UCM constitutive equation that considered relaxation time as a function of temperature and molecular weight. The UCM model predicted the diameter profile better than the Newtonian, while velocity development was slower than the Newtonian model. Viscoelasticity played an important role in accurately predicting diameter profile. However, even though neck-like deformation was observed in the UCM model, the exact position of the deformation under high speed spinning was not obtained.

• Korea-Australia Rheology Journal
• /
• v.17 no.2
• /
• pp.41-45
• /
• 2005

As an effort to explore the effective use of carbon nanotubes as a reinforcing material for advanced nano-composites with polymer matrices, multi-walled carbon nanotubes (MWNTs) were successfully incorporated into polystyrene (PS) via in-situ bulk polymerization. Various experimental techniques revealed that the covalent bonds formed between PS radicals and acid-treated carbon nanotubes are favorable resulting in an effective load transfer. The enhanced storage modulus of the nanocomposites suggests a strong possibility for the potential use in industrial applications.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2005.10a
• /
• pp.358-361
• /
• 2005

The rotational barrel type equipment has been designed for the new rheology fabrication process. During the continuous rotation of barrel with a constant temperature, the shear rate is controlled with the rotation speed and rotation time of barrel. The barrel surface can be controlled the temperature by the induction heating and cooling system. Many experiments were widely examined by using this system with controlling the rotation speed and the rotation time. The possibility for the rheoforming process was investigated with microstructural characteristics.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2016.05a
• /
• pp.205-206
• /
• 2016

This study examines the effect of binding material and alkali activator on the rheology characteristics of alkali active mortar quantitatively, and a result is as follows. In the 1/2 slump flow, the higher mixing ratio of the fly ash has been shown to increase the table flow. the reason is that fly ash ball bearing action. When viewed in the consistency curve, the higher mixing ratio of the blast furnace slag powder was higher shear stress.

• Elastomers and Composites
• /
• v.25 no.3
• /
• pp.203-210
• /
• 1990

The structure and properties of blends of ethylene-propylene-diene terpolymer(EPDM) and polyolefin blends have been investigated. The rheology and tensile properties of the EPDM/HDPE(high density polyethylene), EPDM/PP(polypropylene) binary and EPDM/PP/HDPE ternary blends were studied along with morphological analyses. Those properties were affected by preferential interaction of EPDM on HDPE, compared to that of EPDM on PP, for the binary blends. The preferetial interaction may stem from the molecular characteristics of EPDM to possess more ethylene units than propylene units in the elastomer. The EPDM played a role as compatibilizer for HDPE and PP in the EPDM/PP/HDPE ternary blends.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2005.10a
• /
• pp.645-648
• /
• 2005

The rotational barrel type equipment has been designed for the new rheology fabrication process. During the continuous rotation of barrel with a constant temperature, the shear rate is controlled with the rotation speed and rotation time of barrel. The barrel surface can be controlled the temperature by the induction heating and cooling system. Many experiments were widely examined by using this system with controlling the rotation speed and the rotation time. The possibility for the rheoforming process was investigated with microstructural characteristics.

• Korea-Australia Rheology Journal
• /
• v.20 no.2
• /
• pp.79-88
• /
• 2008

In this study, we focus on the improvement of the filling efficiency in injection molding by application of ultrasonic vibration. While studies about the filling efficiency of typical filling processes in the injection molding have been widely performed, there have been only few studies about the filling efficiency of an ultrasonic process. The effect of the ultrasonic vibration is an important process condition, which influences the flow characteristics of polymer melt. This new condition even affects well-known injection conditions such as cavity pressure, injection temperature and mold temperature. For this study, we carried out a numerical analysis by appropriate modeling and analysis of the ultrasonic process in the filling process. To verify this numerical analysis, we compared the numerical results with the experimental data. Also, we analyzed the filling process in a thin cavity using this numerical analysis. To understand the flow characteristics of polymer melt in the ultrasonic process, we substituted real and complex vibration conditions with simplified and classified conditions according to the position of vibrating cavity surfaces and the phase difference between two opposing cavity surfaces. We also introduced MFR (melt flow ratio) as a new index to estimate the filling efficiency in the ultrasonic process.