• Journal of the Korean Wood Science and Technology
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• 제42권4호
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• pp.420-427
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• 2014

The physical and mechanical properties of sawdust-rice husk mixed ceramic were investigated with rice husk mixing ratios. The mixed ceramic board was produced with carbonization and resin impregnated sawdust-rice husk board at high temperature. At the same percentage of resin impregnation condition, density and bending strength of the mixed ceramic board increased with increasing the mixing rates of rice husk, whereas weight loss of the ceramic boards decreased. At the same temperature condition for the carbonization of resin impregnated sawdust-rice husk board, the density and bending strength were the highest with 40% of rice husk mixing ratio.

• Journal of the Korean Wood Science and Technology
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• 제45권3호
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• pp.335-342
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• 2017

This study was carried out to explore a new application of the by-products sawdust, formed during sawing and mandarin peels which are agricultural by-products. The boards were manufactured by mixing the sawdust and mandarin peels at different mixing ratio and density. The boards were then converted to ceramics by various percentage of resin impregnation and at different carbonization temperatures. As the percentage of resin impregnation increased, the weight loss was decreased; on the other hand, density, linear shrinkage and thickness shrinkage increased. As the carbonization temperature increased, the weight loss was increased and linear thickness shrinkage increased to $1000^{\circ}C$ and the subsequent increase was insufficient. As the percentage of mandarin peels addition increased, the weight loss, linear shrinkage and thickness shrinkage was decreased.

• Carbon letters
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• 제16권1호
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• pp.25-33
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• 2015

The prime objective of this research was to study the influence of hot-pressing pressure and matrix-to-reinforcement ratio on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon-composite. Secondary objectives included determination of the physical and mechanical properties of the resulting composite. The 'hybrid carbon-fiber-reinforced mesophase-pitch-derived carbon-matrix' composite was fabricated by hot pressing. During hot pressing, pressure was varied from 5 to 20 MPa, and reinforcement wt% from 30 to 70. Densification of all the compacts was carried at low impregnation pressure with phenolic resin. The effect of the impregnation cycles was determined using measurements of microstructure and density. The results showed that effective densification strongly depended on the hot-pressing pressure and reinforcement wt%. Furthermore, results showed that compacts processed at lower hot-pressing pressure, and at higher reinforcement wt%, gained density gradually during three densification cycles and showed the symptoms of further gains with additional densification cycles. In contrast, samples that were hot-pressed at moderate pressure and at moderate reinforcement wt%, achieved maximum density within three densification cycles. Furthermore, examination of microstructure revealed the formation of cracks in samples processed at lower pressure and with low reinforcement wt%.

• Journal of Powder Materials
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• 제28권1호
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• pp.7-12
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• 2021

The change in the open porosity of bulk graphite as a function of the uniaxial molding pressure during manufacturing is studied using artificial graphite powder. Subsequently, the graphite is impregnated to determine the effect of the open porosity on the impregnation efficiency and to improve the density of the final bulk graphite. Bulk graphite is manufactured with different uniaxial molding pressures after mixing graphite powder, which is the by-product of processing the final graphite products and phenolic resin. The bulk density and open porosity are measured using the Archimedes method. The bulk density and open porosity of bulk graphite increase as the molding pressure increases. The open porosity of molded bulk graphite is 25.35% at 30 MPa and 29.84% at 300 MPa. It is confirmed that the impregnation efficiency increases when the impregnation process is performed on a specimen with large open porosity. In this study, the bulk density of bulk graphite molded at 300 MPa is 11.06% higher than that before impregnation, which is the highest reported increase. Therefore, it is expected that the higher the uniaxial pressure, the higher the density of bulk graphite.

• Composites Research
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• 제24권2호
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• pp.30-37
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• 2011

Analysis of wettability between epoxy resin and glass fabric was studied. The mixing ratios of epoxy resin and anhydride hardener were varied as 1:0.5, l:l and l:1.2. Catalyst content was fixed as 0.1wt% of the mixed resin. A curing analysis by differential scanning calorimeter(DSC) showed a possible impregnation of the mixed resin at the room temperature. An effective contact angle of the mixed epoxy resin drop onto the glass fabric being preset on a flat glass plate was measured as a function of time. The wet area of the epoxy resin drop was also measured. Behaviors of the contact angle, the droplet height, the neat wet area and the coefficient of wettability were used to evaluate the wettability of the epoxy resin onto the glass fabric. It was concluded that the equivalent ratio of 1: 1.2 was the most suitable for the wettability.

• Journal of the Korean Chemical Society
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• 제27권5호
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• pp.353-360
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• 1983

The adsorption behavior of 8-hydroxyquinoline (8HQ) on Amberlite XAD-4 and-7 resins was investigated by measuring its distribution coefficients under various experimental conditions, such as shaking time, pH and concentration of methanol in the medium. The application of 8HQ-impregnated-XAD resins for the absorption and separation of metal ions was studied. The maximum adsorption of 8HQ on XAD resins was observed in the 30% methanol solution having pH range from 6.0 to 9.0. The impregnation capacities of XAD resins for 8HQ were 3.81${\times}$10-2mmol, 8HQ/g, XAD-4 resins and 2.60${\times}$10-2mmol, 8HQ/g, XAD-7 resin, respectively. The 8HQ-impregnated-XAD resins were stable in pH range from 6.0 to 10.0 and the amount of 8HQ leached from XAD-4 resin by eluting with hydrochloric acid(above 5M) was negligible. The optimum pH range for the adsorption of metal ions on 8HQ-impregnated XAD resin was also 6.0 to 10.0, and the adsorption mole ratio of metal ion to 8HQ were 1 : 2 for Cu(II), Cd(II) and Ni(II), and 1 : 3 for Fe(III) at the above pH range. It was found that the absorbed metal ions on 8HQ-impregnated-XAD resins were recovered quantitatively with 5M HCl and 8HQ-impregnated-XAD-4 resin could be reusable over 5 times without decrease in its impregnation capacity.

• Journal of the Korean Chemical Society
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• 제28권6호
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• pp.403-411
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• 1984

Amberlite XAD-7 and XAD-4 resins impregnated with DXHQ (5,7-dihalo-8-hydroxyquinoline) were prepared for the adsorption, separation and recovery of heavy metal ions from aqueous solutions. The characteristics of the impregnated resins, DXHQ (X : Cl, Br, I)-XAD were studied to find out the proper pairs of resin and DXHQ for the adsorption of metal ions. The increasing order of the impregnated amount of DXHQ onto XAD-7 resin was as follows: DCHQ < DBHQ < DIHQ. It was observed from the plot of log $K_d$ vs. pH that the optimum pH range for the adsorption of DIHQ onto XAD-4 resin was from 3.0 to 7.0. The stabilities of the DXHQ-XAD resins were investigated by measuring the amount of DXHQ remained on the XAD resin after shaking the DXHQ-XAD resins in various solutions of pH ranging from 2 to 12 and hydrochloric acid solutions. The impregnated resins were considerably stable in both acidic and neutral solutions. The amount of DIHQ leached from DIHQ-XAD-4 resin by eluting with various HCl solutions (1 ∼ 5M) was negligible, but in the case of XAD-7 resin it increases as the concentration of HCl solution increases. The optimum pH ranges, absorption mole ratio (M : DXHQ) and adsorption capacities (mmol metal per gram of resin) for the adsorption of metal ions onto the DXHQ-XAD resins were determined respectively. The stability of metal ion absorbed by the DXHQ-XAD resins was observed as the following order: M-DCHQ-XAD-7 < M-DBHQ-XAD-7 < M-DIHQ-XAD-7. The adsorbed metal ions were quantitatively recovered by eluting with HCl (0.5 ∼ 5M) and DXHQ-XAD resins could be reused over 5 times without re-impregnation of DXHQ.