• Korean Journal of Food Science and Technology
• /
• v.33 no.6
• /
• pp.693-699
• /
• 2001

ChlorophyII destruction by irradiation in linoleic acid in methanol system was studied. ChlorophyII b standard (3 ppm) was added into methanol solution containing 1% of linoleic acid, and the sample was irradiated up to 20 kGy with or without nitrogen gas-bubbling. The content of chlorophyII b was analyzed by HPLC, and Hunter color value and UV-visible spectra were analyzed during 6 hr of photooxidation. The content of chlorophyll was reduced by irradiation and completely destroyed at 2.517 kGy. The model system with nitrogen gas-bubbling did not develop the lipid oxidation after irradiation or photooxidation at 20 kGy UV-visible spectra showed decreasing values of optical density by increase of irradiation doses, supporting the destruction of chlorophyII b. The results indicate that irradiation technology can be applied to reduce or eliminate the residual chlorophyII and to prolong the shelf-life of oil products.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.29 no.3
• /
• pp.369-385
• /
• 1996

The eco-hydrodynamic model was used to estimate the primary productivity of the oyster culture grounds in Kamak Bay. It is composed of the three-dimensional hydrodynamic model for the simulation of water flow and ecosystem model for the simulation of phytoplankton. The ecosystem model was applied to simulate phytoplankton biomass during culturing period in condition of no oyster culture grounds. The field surveys were conducted from May, 1994 to March, 1995 in Kamak bay. The results showed the concentration of chlorophyll $\alpha$ to be $1.00\~23.28\;{\mu}g/l$ in the surface layer, $1.27\~29.97\;{\mu}g/l$ in the middle layer and $1.23\~23.08\;{\mu}g/l$ the bottom layer. In monthly variations of chlorophyll $\alpha$ concentration, very high concentration were found in July, 1994 and very low concentrations in December, 1994. As the results of three-dimensional hydrodynamic simulation, the computed tidal currents ave mainly toward the inner part of bay through Yeosu Harbor and the southern mouth of a bay during the flood tide. The computed residual currents were dominated southward in Yeosu Harbor and eastward in the mouth of bay and also showed strong clockwise water circulation at the mouth of bay. The pattern between the simulated and observed tidal ellipses at three stations was very similar. The mean relative errors of all levels between the simulated and observed phytoplankton biomass at 14 stations in Kamak Bay were $13.81\%,\;9.31\%\;and\;17.84\%$, respectively. The results of phytoplankton biomass simulation showed that the biomass increased from June to September and rapidly decreased to December and then slowly increased to March. Primary productivity was estimated in the range of $0.99\~10.20gC/m^2/d$ with the average value of $4.43gC/m^2/d$ in condition of no oyster culture grounds. Primary productivity was rapidly increased from lune to August and rapidly decreased to December and then slowly increased from January to March in Kamak Bay.

• Journal of the Society of Naval Architects of Korea
• /
• v.30 no.2
• /
• pp.141-154
• /
• 1993

In this paper, a method to calculate the ultimate compressive strength of welded one-sided stiffened plates simply supported along all edges is proposed. At first initial imperfections such as distortions and residual stresses due to welding are predicted by using simplified methods. Then, the collapse modes of the stiffened plate are assumed and collapse loads for each mode are calculated. Among these loads, the lowest value is selected as the ultimate strength of the plate. Collapse modes are assumed as follows ; (1) Overall buckling of the stiffened plate$\rightarrow$Overall collapse due to stiffener bending (2) Local buckling of the plate part$\rightarrow$Local collapse of the plate part$\rightarrow$Overall collapse due to stiffener yielding (3) Local buckling of the plate part$\rightarrow$Overall collapse due to stiffener berthing (4) Local buckling of the plate part$\rightarrow$Local collapse of the plate part$\rightarrow$Overall collapse due to stiffener tripping. The elastic large deflection analysis based on the Rayleigh-Ritz method is carried out, and plastic analysis assuming hinge lines is also carried out. Collapse load is defined as the cross point of the two analysis curves. This method enables the utimate strength to be calculated with small computing time and a good accuracy. Using the present method, characteristics of the stiffener including torsional rigidity, bending and tripping can also be clarified.

• The Journal of Korean Academy of Prosthodontics
• /
• v.29 no.1
• /
• pp.111-137
• /
• 1991

Although a number of studies have been performed to assure that residual stress caused by a mismatch of alloy porcelain thermal expansion can contribute to clinical failure of a ceramometal restoratoin, the interactive influence of cooling rate on the magnitude of thermal expansion difference and on bond strength between them have not been extensively analyzed. The objective of this study was to determine the influence of cooling rate and the number of firing cycles on the expansion mismatch and the flexural failure resistance of metal porcelain strip. Tested alloys included one Pd-Ag alloy, one Ni-Cr-Be alloy with two kinds of porcelain, Vita and Ceramco. Metal specimens were cast into rods with a height of 13mm and a diameter of 5mm. Subsequently, the castings were subjected to scheduled firing cycles without porcelain. And the porcelain specimens after being fired were trimmed into a bar with a final dimension of 5 x 5 x 25mm. Thermal expansions of the alloys and porcelains were measured by using a push rod or a differential dialometer respectively. Porcelain glass transition temperatures and expansion values were derived alloy- porcelain pairs were assessed by comparing expansion values of the components at a porcelain glass transition temperature. Calculations were made using combinations of a Ni-Cr alloy or Pd-Ag alloy with each of two porcelain products. Metal- porcelain strip specimens were subjected to four point loading in an Instron testing machine until crack occured at the metal-cramic interface at the time of sharp decrease of load on recorder. On the basis of this study, the following conclusions may be stated : 1. Regardless of the kinds of ceramometal combinations, both of calculated and experimental data revealed that the double fired specimens exhibited a significantly lower flexural strength. 2. By the rise of the amount of mismatch, bond strength were decreased. 3. Thermal expansion value of Pd-Ag alloys were higher than of Ni-Cr alloys. 4. Expansion curves of metal were proportional to the increase of temperature and were not affected by the experimental conditions, however porcelains did not show the same magnitude of metal, and a shift of the glass transition temperature to higher temperatures was observed when cooled rapidly. 5. Alloy- porcelain thermal compatibility appeared more dependent on the porcelain than the alloy.

• Journal of the Korean GEO-environmental Society
• /
• v.6 no.4
• /
• pp.47-58
• /
• 2005

Development of underground space is conducted for various useful facility and underground structures and deep excavation technology for reclaimed area has been researched and developed. The seepage flow and behavior of phreatic line in reclaimed area was predominated by transient flow caused by tidal action. Also the soil-water characteristic relation is most important factor for transient flow analysis, therefore the research about the soil-water characteristic is strongly required. In this paper, laboratory tests (pressure cell, desiccator, and tensiometer test) and theoretical analysis were performed to investigate the soil-water characteristic such as air-entry value, metric suction, and residual water content. And the feasibility of prediction method for soil-water characteristic are presented by transient seepage analysis and comparison between analysis results and in-situ measured seepage flux in LNG TK-00 storage tank. Based on the result of laboratory and theoretical analysis, Fredlund and Xing's method provide to work out well for reclaimed ground soils. Also, the transient analysis result is more reasonable and effective for design of deep excavation work in coastal and reclaimed ground.

• Korean Chemical Engineering Research
• /
• v.55 no.2
• /
• pp.141-155
• /
• 2017

In the present paper, we investigated the development status of precipitated calcium carbonate (PCC) production using steel slag, which is one of mineral carbonation (MC) technologies, from the standpoint of $CO_2$ utilization. Principle, feature, and global and domestic development status of the mineral carbonation technology were discussed together with the overview of the production method and market of PCC. Mineral carbonation is known as stable and environmentally-friendly technology enabling economical treatment of industrials wastes. Typically, PCC is produced by the reaction of $CO_2$ with supernatant solution after Ca extraction from steel slag followed by the separation of solid and liquid. The development status of MC using steel slag is at the pilot stage (Slag2PCC at Aalto University), and there remains the process economics improvement for commercialization. Key technologies for the further development are efficient extraction of Ca ions from steel slag including impurities removal, valorization of PCC via shape and size control, usage development and value-addition of residual slag, and optimization of reaction conditions for continuous process setup, etc.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.38 no.3
• /
• pp.372-376
• /
• 2009

Physicochemical changes in persimmon were examined during natural organic acid fermentation. Major organic acids in raw persimmon juices were lactic acid (980 mg%) and acetic acid (245 mg%). The content of acetic acid was continuously increased during the whole period of fermentation up to 3 years. Glucose was the dominant free sugar, but the content was decreased after 20 days of fermentation. Most of the glucose was converted to ethanol until 40 days after initiation of acid fermentation. L- and a values of Hunter's color in fermented persimmon juice, which was naturally exuded from persimmon fruit as fermentation continued, increased gradually, while b value decreased. Acetic acid (1584 mg%) was the most abundant organic acid followed by lactic acid (712 mg%) and citric acid (48 mg%) in a persimmon fruit juice after completion of 3 year fermentation. A minute amount of residual free sugars, mainly glucose, even after 3 years of fermentation may cause changes in quality characteristics while storage for edible use.

• Spatial Information Research
• /
• v.9 no.2
• /
• pp.239-261
• /
• 2001

A large suite of official statistical data sets has been compiled for geographical units under the national directives, and it is the quantitative regional analysis procedures that could add values to them. This paper reports our attempts at prototyping a statistical GIS which is capable of serving over the Web a variety of regional analysis routines as well as value-added statistics and maps. A pilot database of some major statistical data was ingested for the city of Seoul. The baseline subset of regional analysis methods of practical usage was selected and accommodated into the business logic of the target system, which ranges from descriptive statistics, regional structure/inequality measures, spatial ANOVA, spatial (auto) correlation to regression and residual analysis. The leading-edge information technologies including the application server were adopted in the system design and implementation so that the database, analysis modules and analytic mapping components may cooperate seamlessly behind the Web front-end. The prototyped system supports tables, maps, and files of downloadable format for input and output of the analyses. One of the most salient features of out proposed system is that both the database and analysis modules are extensible via the bi-directional interface for end users; The system provides users with operators and parsers for algebraic formulae such that the stored statistical variables may be transformed and combined into the newly-derived set of variables. This functionality eventually leads to on-the-fly fabrication of user-defined regional analysis algorithms. The stored dataset may also be temporarily augmented by user-uploaded dataset; The extension of this form, in essence, results in a virtual database which awaits for users commands as usual. An initial evaluation of the proposed system confirms that the issues involving the usage and dissemination of information can be addressed with success.

• Elastomers and Composites
• /
• v.37 no.1
• /
• pp.7-13
• /
• 2002

In this study, mechanical properties of PVC complexes containing the gypsum (Namhae Chemical Co.) which contains phosphte, CaO, etc., Pb-species stabilizer, and $CaCO_3$ were investigated as a function or the content. As a result, mechanical properties increased when the gypsum was mixed with PVC at the extent of 8.46wt%. From this result, it is suggested that the gypsum containing phosphate and CaO is compatible with PVC. Thermogravimetric analysis(TGA) showed that pyrolysis started about at $275^{\circ}C$, and residual weight(%) increased with the amount of the gypsum, and differential scanning calorimetry (DSC) showed that $T_m,\;T_g$ had the maximum and minimum value respectively when the gypsum was mixed with PVC at the extent of 8.46wt%. Comparing all the results, both mechanical and thermal properties of PVC complex were improved. The X-ray diffraction measurement also showed their blonds and structures.

• Journal of Environmental Science International
• /
• v.2 no.1
• /
• pp.43-49
• /
• 1993

Concentrations of sulfate and 6-values of sulfate, $({\delta}^{34}SO_4_){pw}$, dissolved In pore waters were measured from the sediment cores of the two different marine environments : deep northeast Pacific (57-1) and coastal Kyunggi Bay of Yellow Sea (57-2) . Sulfate concentration in pore waters decreases with depth at both cores, reflecting sulfate reduction in the sediment columns. However, much higher gradient of pore water sulfate at 57-2 than 57-1 indicates more rapid sulfate reduction at 57-2, because of high sedimentation rate at the coastal area compared to the deep-sea. The measured 6-values, $({\delta}^{34}SO_4_){pw}$, follow extremely well the predicted trend of the Rayleigh fractionation equation. The range of 26.756 to 61.35% at the coastal core 57-2 is not so great as that of 32.4$\textperthousand$ to 97.8$\textperthousand$ at the deep-sea core 57-1. Despite greater graclient of pore water sulfate at 57-2, the 6-values become lower than those of the deep- sea core 57-1. This inverse relation between the 6-values and the gradients of pore water sulfate could be explained by the combination of the two subsequent factors : the kinetic effect by which the residual pore water sulfate becomes progressively enriched with respect to the heavy isotope of $^{34}S$ as sulfate reduction proceeds, and the intrinsic formulation effect of the Rayleigh fractionation equation in which the greater becomes the fractionation factor, the more diminished values of $({\delta}^{34}SO_4_){pw}$ are predicted.